scholarly journals Structural disorganization of cereal, tuber and bean starches in aqueous ionic liquid at room temperature: Role of starch granule surface structure

2021 ◽  
Vol 258 ◽  
pp. 117677
Author(s):  
Ke Zan ◽  
Jinwei Wang ◽  
Fei Ren ◽  
Jinglin Yu ◽  
Shuo Wang ◽  
...  
2019 ◽  
Vol 18 (6) ◽  
pp. 1359-1372 ◽  
Author(s):  
Rupam Dutta ◽  
Gourhari Jana ◽  
Dipankar Mondal ◽  
Arghajit Pyne ◽  
Sourav Sil ◽  
...  

Literature reports provide ample evidence of the dynamical studies of various fluorophores in different room-temperature ionic liquid (RTIL)–cosolvent mixtures.


2011 ◽  
Vol 287-290 ◽  
pp. 424-427 ◽  
Author(s):  
Norazlin Zainal ◽  
Razali Idris ◽  
Mohamed Nor Sabirin

Ionic liquid based on imidazolium cation; 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide (EMITFSI) has been incorporated with epoxidized natural rubber-50 (ENR-50) and lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) to obtain electrolyte material. Fourier transform infrared spectroscopy (FTIR) spectra showed evidence of complexation between ENR-50, EMITFSI and LiTFSI. Glass transition temperature, Tg displayed an increasing trend with increase in salt concentration. The incorporation of EMITFSI resulted in an increase in ionic conductivity. The increase in ionic conductivity was attributed to the role of ionic liquid which reduced Tg, thus, facilitated ion conduction in the system. The highest ionic conductivity at room temperature was 5.72 ´ 10-4 S cm-1 for sample containing 20 wt% of EMITFSI and 50 wt% of LiTFSI.


Lubricants ◽  
2019 ◽  
Vol 7 (3) ◽  
pp. 27 ◽  
Author(s):  
Luigi Urtis ◽  
Andrea Arcifa ◽  
Peng Zhang ◽  
Junxiao Du ◽  
Marzia Fantauzzi ◽  
...  

This work aims to elucidate the role of environmental humidity on the tribological behavior of steel surfaces lubricated with an ionic liquid comprised of a fluorinated phosphonium cation—tributyl-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octyl-phosphonium—and a dicyanamide anion (i.e. N(CN)2−). Ball-on-disk tribotests were carried out at room temperature and at various levels of relative humidity (RH). Water was found to be required to promote the formation of a tribofilm over the contact area. The reaction layer exhibited a patchy morphology, which resembles that observed formed with conventional antiwear additives such as ZnDTP. A surface-chemical analysis of the tribofilm indicated that the tribofilm is composed of fluorides, oxides, and phosphates, pointing to a stress-induced degradation of the ions and corrosion of the sliding counterparts, which is enabled by the presence of water at the sliding interface.


2019 ◽  
Vol 54 (9) ◽  
pp. 1443-1452 ◽  
Author(s):  
Rajesh B. Gujar ◽  
Seraj A. Ansari ◽  
Dibakar Goswami ◽  
Prasanta K. Mohapatra

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