Catalytic epoxidation of cyclooctene using molybdenum(VI) compounds and urea-hydrogen peroxide in the ionic liquid [bmim]PF6

2007 ◽  
Vol 8 (7) ◽  
pp. 987-990 ◽  
Author(s):  
Matthew Herbert ◽  
Agustín Galindo ◽  
Francisco Montilla
Keyword(s):  
Hydrogen Peroxide ◽  
Ionic Liquid ◽  
Catalytic Epoxidation ◽  
Urea Hydrogen Peroxide

Epoxidation of Olefins Catalyzed by Polyoxomolybdates Formed in-situ in Ionic Liquids

2013 ◽  
Vol 68 (10) ◽  
pp. 1138-1142 ◽  
Author(s):  
Lilian R. Graser ◽  
Sophie Jürgens ◽  
Michael E. Wilhelm ◽  
Mirza Cokoja ◽  
Wolfgang A. Herrmann ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Hydrogen Peroxide ◽  
Ionic Liquid ◽  
Catalyst Concentration ◽  
Sodium Molybdate ◽  
Significant Loss ◽  
Catalytic Epoxidation ◽  
Epoxidation Reaction ◽  
Epoxidation Of Olefins

Polyoxomolybdates were generated in situ by treating a carboxylic acid-functionalized ionic liquid with an aqueous solution of sodium molybdate. This reaction mixture was applied in the catalytic epoxidation of olefins using hydrogen peroxide as oxidant. The influence of acid and catalyst concentration as well as of the reaction temperature was investigated. The system showed a good performance for the epoxidation reaction and can be reused several times without a significant loss of activity. We present an easy, cheap and environmentally friendly catalytic system for the epoxidation of cis-cyclooctene.

An ionic liquid immobilized copper complex for catalytic epoxidation

RSC Advances ◽  
2015 ◽  
Vol 5 (81) ◽  
pp. 65870-65873 ◽  
Author(s):  
R. Dileep ◽  
B. J. Rudresha
Keyword(s):  
Hydrogen Peroxide ◽  
Ionic Liquid ◽  
Liquid Medium ◽  
Catalytic System ◽  
Copper Complex ◽  
Liquid Mixture ◽  
Catalytic Epoxidation ◽  
Epoxidation Of Olefins ◽  
Ionic Liquid Medium

A catalytic system consisting of copper complex and hydrogen peroxide in Emim ionic liquid medium was effective in the epoxidation of olefins and terpenes. The catalyst and the ionic liquid mixture was recycled and reused consistently.

scholarly journals One-Pot Tandem Catalytic Epoxidation—CO2 Insertion of Monounsaturated Methyl Oleate to the Corresponding Cyclic Organic Carbonate

Catalysts ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1477
Author(s):  
Roberto Calmanti ◽  
Nicola Sargentoni ◽  
Maurizio Selva ◽  
Alvise Perosa
Keyword(s):  
Hydrogen Peroxide ◽  
Fatty Acids ◽  
Ionic Liquid ◽  
Double Bond ◽  
Methyl Oleate ◽  
Unsaturated Fatty Acids ◽  
One Pot ◽  
Co Catalyst ◽  
Catalytic Epoxidation ◽  
Organic Carbonate

Conversion of unsaturated fatty acids, FAMEs or triglycerides into the corresponding cyclic organic carbonates involves two reaction steps—double-bond epoxidation and CO2 insertion into the epoxide—that are generally conducted separately. We describe an assisted-tandem catalytic protocol able to carry out carbonation of unsaturated methyl oleate in one-pot without isolating the epoxide intermediate. Methyl oleate carbonate was obtained in 99% yield and high retention of cis-configuration starting from methyl oleate using hydrogen peroxide and CO2 as green reagents, in a biphasic system and in the presence of an ammonium tungstate ionic liquid catalyst with KBr as co-catalyst.

Hydrogen Peroxide Biosensor Based on Cellulose Diacetate Ionic Liquid Film Immobilizing Myoglobin

2012 ◽  
Vol 39 (9) ◽  
pp. 1358-1362
Author(s):  
She-Ying DONG ◽  
Guang-Zhe GU ◽  
Zhu-Qing YU ◽  
Yuan-Zhen ZHOU ◽  
Hong-Sheng TANG ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Ionic Liquid ◽  
Liquid Film ◽  
Cellulose Diacetate ◽  
Hydrogen Peroxide Biosensor
Sign in / Sign up

Export Citation Format

Share Document