Hollow Fe2O3/Co3O4 microcubes derived from metal-organic framework for enhanced sensing performance towards acetone

2021 ◽  
Author(s):  
Ruixue Mo ◽  
Dongqiang Han ◽  
Zeng Ren ◽  
Dazhuang Yang ◽  
Fei Wang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Metal Organic ◽  
Sensing Performance ◽  
Organic Framework

A highly stable 8-hydroxyquinolinate-based metal–organic framework as a selective fluorescence sensor for Fe3+, Cr2O72− and nitroaromatic explosives

2020 ◽  
Vol 7 (22) ◽  
pp. 4387-4395
Author(s):  
Quan Sun ◽  
Kun Yang ◽  
Wenna Ma ◽  
Liyan Zhang ◽  
Guozan Yuan
Keyword(s):  
Metal Organic Framework ◽  
Fluorescence Sensor ◽  
Nitroaromatic Explosives ◽  
Metal Organic ◽  
Sensing Performance ◽  
Organic Framework

A novel 8-hydroxyquinolinate-based metal–organic framework exhibits excellent sensing performance toward Fe3+, Cr2O72− and nitroaromatic explosives.

Coating a DNA self-assembled monolayer with a metal organic framework-based exoskeleton for improved sensing performance

The Analyst ◽  
2019 ◽  
Vol 144 (11) ◽  
pp. 3539-3545 ◽  
Author(s):  
Jiehua Ma ◽  
Wenxin Chai ◽  
Jianyang Lu ◽  
Tian Tian ◽  
Shuai Wu ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Self Assembled Monolayers ◽  
Self Assembled Monolayer ◽  
New Strategy ◽  
Assembled Monolayers ◽  
Metal Organic ◽  
Self Assembled ◽  
Poor Stability ◽  
Sensing Performance ◽  
Organic Framework

The relatively poor stability of DNA self-assembled monolayers (SAMs) greatly limits their use in real applications. A new strategy is reported to protect the DNA SAMs by using a metal organic framework (MOF)-based exoskeleton.

Metal–Organic Framework-Assisted Construction of TiO2/Co3O4 Highly Ordered Necklace-like Heterostructures for Enhanced Ethanol Vapor Sensing Performance

Langmuir ◽  
2018 ◽  
Vol 34 (48) ◽  
pp. 14577-14585 ◽  
Author(s):  
Tian Zhang ◽  
Xing Tang ◽  
Jian Zhang ◽  
Tingting Zhou ◽  
Hao Wang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Ethanol Vapor ◽  
Vapor Sensing ◽  
Metal Organic ◽  
Sensing Performance ◽  
Organic Framework

An efficient strategy for improving the luminescent sensing performance of a terbium(iii) metal–organic framework towards multiple substances

2018 ◽  
Vol 54 (94) ◽  
pp. 13271-13274 ◽  
Author(s):  
Xiaoning Wang ◽  
Jia-Luo Li ◽  
Chenggang Jiang ◽  
Peng Hu ◽  
Bao Li ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Hydrolytic Stability ◽  
Efficient Strategy ◽  
Metal Organic ◽  
Sensing Performance ◽  
Luminescent Sensing ◽  
Organic Framework

A new luminescent Ln-MOF-based sensor with hydrolytic stability has been successfully prepared.

Multifunctional metal–organic framework heterostructures for enhanced cancer therapy

2021 ◽  
Author(s):  
Jintong Liu ◽  
Jing Huang ◽  
Lei Zhang ◽  
Jianping Lei
Keyword(s):  
Cancer Therapy ◽  
General Principle ◽  
Biomedical Applications ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Functional Modulation ◽  
Organic Framework

We review the general principle of the design and functional modulation of nanoscaled MOF heterostructures, and biomedical applications in enhanced therapy.

Magnetic Ordering via Itinerant Ferromagnetism in a Metal-Organic Framework

2020 ◽  
Author(s):  
Jesse Park ◽  
Brianna Collins ◽  
Lucy Darago ◽  
Tomce Runcevski ◽  
Michael Aubrey ◽  
...  
Keyword(s):  
Charge Transport ◽  
Magnetic Order ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Magnetic Ordering ◽  
Double Exchange ◽  
Itinerant Ferromagnetism ◽  
Organic Solids ◽  
Metal Organic ◽  
Organic Framework

<b>Materials that combine magnetic order with other desirable physical attributes offer to revolutionize our energy landscape. Indeed, such materials could find transformative applications in spintronics, quantum sensing, low-density magnets, and gas separations. As a result, efforts to design multifunctional magnetic materials have recently moved beyond traditional solid-state materials to metal–organic solids. Among these, metal–organic frameworks in particular bear structures that offer intrinsic porosity, vast chemical and structural programmability, and tunability of electronic properties. Nevertheless, magnetic order within metal–organic frameworks has generally been limited to low temperatures, owing largely to challenges in creating strong magnetic exchange in extended metal–organic solids. Here, we employ the phenomenon of itinerant ferromagnetism to realize magnetic ordering at <i>T</i><sub>C</sub> = 225 K in a mixed-valence chromium(II/III) triazolate compound, representing the highest ferromagnetic ordering temperature yet observed in a metal–organic framework. The itinerant ferromagnetism is shown to proceed via a double-exchange mechanism, the first such observation in any metal–organic material. Critically, this mechanism results in variable-temperature conductivity with barrierless charge transport below <i>T</i><sub>C</sub> and a large negative magnetoresistance of 23% at 5 K. These observations suggest applications for double-exchange-based coordination solids in the emergent fields of magnetoelectrics and spintronics. Taken together, the insights gleaned from these results are expected to provide a blueprint for the design and synthesis of porous materials with synergistic high-temperature magnetic and charge transport properties. </b>

Solvent-Free Powder Synthesis and MOF-CVD Thin Films of the Mesoporous Metal-Organic Framework MAF-6

2019 ◽  
Author(s):  
Timothée Stassin ◽  
Ivo Stassen ◽  
Joao Marreiros ◽  
Alexander John Cruz ◽  
Rhea Verbeke ◽  
...  
Keyword(s):  
Vapor Phase ◽  
Metal Organic Framework ◽  
Chemical Vapor ◽  
Uptake Capacity ◽  
Powder Synthesis ◽  
Crystalline Films ◽  
Metal Organic ◽  
Mesoporous Metal ◽  
First Time ◽  
Organic Framework

A simple solvent- and catalyst-free method is presented for the synthesis of the mesoporous metal-organic framework (MOF) MAF-6 (RHO-Zn(eIm)2) based on the reaction of ZnO with 2-ethylimidazole vapor at temperatures ≤ 100 °C. By translating this method to a chemical vapor deposition (CVD) protocol, mesoporous crystalline films could be deposited for the first time entirely from the vapor phase. A combination of PALS and Kr physisorption measurements confirmed the porosity of these MOF-CVD films and the size of the MAF-6 supercages (diam. ~2 nm), in close agreement with powder data and calculations. MAF-6 powders and films were further characterized by XRD, TGA, SEM, FTIR, PDF and EXAFS. The exceptional uptake capacity of the mesoporous MAF-6 in comparison to the microporous ZIF-8 is demonstrated by vapor-phase loading of a molecule larger than the ZIF-8 windows.

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