Ultrafine metal species confined in metal–organic frameworks: Fabrication, characterization and photocatalytic applications

2021 ◽  
Vol 439 ◽  
pp. 213924
Author(s):  
Jiao Cao ◽  
Zhaohui Yang ◽  
Weiping Xiong ◽  
Yaoyu Zhou ◽  
You Wu ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Metal Species ◽  
Ultrafine Metal ◽  
Metal Organic ◽  
Photocatalytic Applications

A series of multifunctional lanthanide metal-organic frameworks for luminescent sensing and photocatalytic applications

2019 ◽  
Vol 206 ◽  
pp. 192-198 ◽  
Author(s):  
Fengqin Wang ◽  
Yanyan Pu ◽  
Xuemei Zhang ◽  
Fengxiao Zhang ◽  
Honglin Cheng ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Photocatalytic Applications ◽  
Luminescent Sensing

scholarly journals Porous ZnO/Carbon nanocomposites derived from metal organic frameworks for highly efficient photocatalytic applications: A correlational study

Carbon ◽  
2019 ◽  
Vol 146 ◽  
pp. 348-363 ◽  
Author(s):  
Mian Zahid Hussain ◽  
Govinder Singh Pawar ◽  
Zheng Huang ◽  
Asif Ali Tahir ◽  
Roland A. Fischer ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Correlational Study ◽  
Carbon Nanocomposites ◽  
Highly Efficient ◽  
Metal Organic ◽  
Photocatalytic Applications

scholarly journals Metal Organic Frameworks as Heterogeneous Catalysts in Olefin Epoxidation and Carbon Dioxide Cycloaddition

Inorganics ◽  
2021 ◽  
Vol 9 (11) ◽  
pp. 81
Author(s):  
Alessia Tombesi ◽  
Claudio Pettinari
Keyword(s):  
Carbon Dioxide ◽  
Coordination Polymers ◽  
Heterogeneous Catalysts ◽  
Metal Organic Frameworks ◽  
Metal Species ◽  
Olefin Epoxidation ◽  
Crystalline Materials ◽  
Recent Developments ◽  
Metal Organic ◽  
New Research

Metal–organic frameworks (MOFs) are a family of porous crystalline materials that serve in some cases as versatile platforms for catalysis. In this review, we overview the recent developments about the use of these species as heterogeneous catalysts in olefin epoxidation and carbon dioxide cycloaddition. We report the most important results obtained in this field relating them to the presence of specific organic linkers, metal nodes or clusters and mixed-metal species. Recent advances obtained with MOF nanocomposites were also described. Finally we compare the results and summarize the major insights in specific Tables, outlining the major challenges for this emerging field. This work could promote new research aimed at producing coordination polymers and MOFs able to catalyse a broader range of CO2 consuming reactions.

Coordination distortion induced water adsorption in hydrophobic flexible metal–organic frameworks

2020 ◽  
Vol 56 (64) ◽  
pp. 9106-9109
Author(s):  
Yoshinobu Kamakura ◽  
Arata Hikawa ◽  
Hirofumi Yoshikawa ◽  
Wataru Kosaka ◽  
Hitoshi Miyasaka ◽  
...  
Keyword(s):  
Metal Ions ◽  
Water Adsorption ◽  
Metal Organic Frameworks ◽  
Adsorption Properties ◽  
Metal Species ◽  
Metal Organic ◽  
Flexible Metal

The water-adsorption properties of four isostructural hydrophobic metal-organic frameworks are dependent on the metal species, which was revealed to be caused by coordination distortion around the metal ions.

scholarly journals Transition Metal Oxodiperoxo Complex Modified Metal-Organic Frameworks as Catalysts for the Selective Oxidation of Cyclohexane

Materials ◽  
2020 ◽  
Vol 13 (4) ◽  
pp. 829 ◽  
Author(s):  
Yuechao Hong ◽  
Jie Peng ◽  
Zhichao Sun ◽  
Zhiquan Yu ◽  
Anjie Wang ◽  
...  
Keyword(s):  
Transition Metal ◽  
Photoelectron Spectroscopy ◽  
Inductively Coupled Plasma ◽  
Metal Organic Frameworks ◽  
Atomic Emission ◽  
Cyclohexane Oxidation ◽  
Metal Species ◽  
Emission Spectrometry ◽  
Plasma Atomic Emission Spectrometry ◽  
Metal Organic

In this work, a series of modified metal-organic frameworks (MOFs) have been prepared by pre- and post-treatment with transition metal oxodiperoxo complexes (MoO(O2)2, WO(O2)2, and KVO(O2)2). The obtained materials are characterized by XRD, FTIR, SEM, TEM, inductively coupled plasma atomic emission spectrometry (ICP-AES), and X-ray photoelectron spectroscopy (XPS), as well as by N2 adsorption/desorption measurement. The characterization results show that transition metal oxodiperoxo complexes are uniformly incorporated into the MOF materials without changing the basic structures. The performance of cyclohexane oxidation on metal oxodiperoxo complex modified MOFs are evaluated. UiO-67-KVO(O2)2 shows the best performance for cyclohexane oxidation, with 78% selectivity to KA oil (KA oil refers to a cyclohexanol and cyclohexanone mixture) at 9.4% conversion. The KA selectivity is found to depend on reaction time, while hot-filtration experiments indicates that the catalytic process is heterogeneous with no leaching of metal species.

scholarly journals Titanium-based metal–organic frameworks for photocatalytic applications

2018 ◽  
Vol 359 ◽  
pp. 80-101 ◽  
Author(s):  
Jianjun Zhu ◽  
Pei-Zhou Li ◽  
Wenhan Guo ◽  
Yanli Zhao ◽  
Ruqiang Zou
Keyword(s):  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Photocatalytic Applications

Fe-Co-Ni trimetallic organic framework chrysanthemum-like nanoflowers: efficient and durable oxygen evolution electrocatalysts

2022 ◽  
Author(s):  
Ziliang Li ◽  
Shangkun Deng ◽  
Zhuangzhuang Yin ◽  
Shihan Qi ◽  
Hai Yu ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Nickel Foam ◽  
Metal Organic Frameworks ◽  
Metal Species ◽  
Metal Organic ◽  
Organic Framework

By mixing Fe, Co, and Ni metal species (FCN) in equimolar ratios, multivariate metal-organic frameworks (MOFs) with unique chrysanthemum nanoflower structures were successfully fabricated on a nickel foam (NF) via...

Titanium-based metal-organic frameworks for photocatalytic applications

2021 ◽  
pp. 37-63
Author(s):  
A. Ratnamala ◽  
G. Deepthi Reddy ◽  
M. Noorjahaan ◽  
H. Manjunatha ◽  
S. Janardan ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Photocatalytic Applications
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