Novel Ti3C2/Bi@BiOI nanosheewets with gradient oxygen vacancies for the enhancement of spatial charge separation and photocatalytic performance: The roles of reactive oxygen and iodine species

2021 ◽  
pp. 130764
Author(s):  
Peng Gao ◽  
Zijing Zhang ◽  
Li Feng ◽  
Yongze Liu ◽  
Ziwen Du ◽  
...  
Catalysts ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 1294
Author(s):  
Sopheak Meng ◽  
Takaya Ogawa ◽  
Hideyuki Okumura ◽  
Keiichi N. Ishihara

Heterojunction photocatalysts have attracted a significant amount of attention due to their advantages over a single photocatalyst and, particularly, their superior spatial charge separation. Herein, the BiVO4/Bi2S3/SnS2 heterojunction was synthesized via solvothermal synthesis with different ratios of BiVO4 to SnS2. The photodegradation rate of the 0.03 BiVO4/SnS2 sample for rhodamine B removal is 2.3 times or 2.9 times greater than that of a single SnS2 or BiVO4, respectively. The chemical bond between photocatalysts is confirmed by X-ray photoelectron spectroscopy (XPS), and the synchronized shift observed in binding energies strongly indicates the electron screening effect at the heterojunction. A Z-scheme model is proposed to explain charge transfer pathway in the system, in which the formation of Bi2S3 plays a crucial role in the enhanced photocatalytic performance of the heterojunction.


Author(s):  
Cheng Hu ◽  
Na Tian ◽  
Yihe Zhang ◽  
Hongwei Huang

Facet-selective charge separation in semiconductors has been considered one of the most vital factors to improve their photocatalytic performance and selectivity for solar energy conversion due to the spatial charge...


RSC Advances ◽  
2019 ◽  
Vol 9 (25) ◽  
pp. 14286-14295 ◽  
Author(s):  
Wenhui He ◽  
Yawen Wang ◽  
Caimei Fan ◽  
Yunfang Wang ◽  
Xiaochao Zhang ◽  
...  

h-BN/OV-BiOCl composites were prepared to improve the visible-light photocatalytic activity of OV-BiOCl.


2020 ◽  
Vol 124 (31) ◽  
pp. 16961-16974 ◽  
Author(s):  
Ton Nu Quynh Trang ◽  
Nguyen Dang Nam ◽  
Le Thi Ngoc Tu ◽  
Hau Pham Quoc ◽  
Tran Van Man ◽  
...  

2020 ◽  
Vol 507 ◽  
pp. 145133 ◽  
Author(s):  
Juan-Juan Li ◽  
Meng Zhang ◽  
Bo Weng ◽  
Xi Chen ◽  
Jing Chen ◽  
...  

2021 ◽  
Vol 11 (18) ◽  
pp. 6080-6088
Author(s):  
Yongqian Cui ◽  
Zipeng Xing ◽  
Meijun Guo ◽  
Yalu Qiu ◽  
Bin Fang ◽  
...  

Core–shell carbon colloid sphere@phosphotungstic acid/CdS exhibits excellent visible-light-driven photocatalytic performance, which is due to the Z-scheme heterojunction favoring the charge transfer and spatial charge separation and the photothermal effect.


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