Nickel silicate beta zeolite prepared by interzeolite transformation: A highly active and stable catalyst for dry reforming of methane

2021 ◽  
pp. 133364
Author(s):  
Sungjoon Kweon ◽  
Young Woo Kim ◽  
Chae-Ho Shin ◽  
Min Bum Park ◽  
Hyung-Ki Min
Keyword(s):  
Dry Reforming ◽  
Dry Reforming Of Methane ◽  
Beta Zeolite ◽  
Highly Active ◽  
Nickel Silicate ◽  
Stable Catalyst

scholarly journals Atomically dispersed nickel as coke-resistant active sites for methane dry reforming

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Mohcin Akri ◽  
Shu Zhao ◽  
Xiaoyu Li ◽  
Ketao Zang ◽  
Adam F. Lee ◽  
...  
Keyword(s):  
Active Sites ◽  
Large Scale ◽  
Low Cost ◽  
Coke Formation ◽  
Dry Reforming ◽  
Dry Reforming Of Methane ◽  
Highly Active ◽  
Catalytic Sites ◽  
Earth Abundant ◽  
Poor Stability

AbstractDry reforming of methane (DRM) is an attractive route to utilize CO2 as a chemical feedstock with which to convert CH4 into valuable syngas and simultaneously mitigate both greenhouse gases. Ni-based DRM catalysts are promising due to their high activity and low cost, but suffer from poor stability due to coke formation which has hindered their commercialization. Herein, we report that atomically dispersed Ni single atoms, stabilized by interaction with Ce-doped hydroxyapatite, are highly active and coke-resistant catalytic sites for DRM. Experimental and computational studies reveal that isolated Ni atoms are intrinsically coke-resistant due to their unique ability to only activate the first C-H bond in CH4, thus avoiding methane deep decomposition into carbon. This discovery offers new opportunities to develop large-scale DRM processes using earth abundant catalysts.

scholarly journals Highly active and stable Ni dispersed on mesoporous CeO2-Al2O3 catalysts for production of syngas by dry reforming of methane

2021 ◽  
Vol 281 ◽  
pp. 119459 ◽  
Author(s):  
André L.A. Marinho ◽  
Fabio S. Toniolo ◽  
Fabio B. Noronha ◽  
Florence Epron ◽  
Daniel Duprez ◽  
...  
Keyword(s):  
Dry Reforming ◽  
Dry Reforming Of Methane ◽  
Highly Active ◽  
Mesoporous Ceo2

scholarly journals Embedded Ni nanoparticles in CeZrO2 as stable catalyst for dry reforming of methane

2020 ◽  
Vol 268 ◽  
pp. 118387 ◽  
Author(s):  
André L.A. Marinho ◽  
Raimundo C. Rabelo-Neto ◽  
Florence Epron ◽  
Nicolas Bion ◽  
Fabio S. Toniolo ◽  
...  
Keyword(s):  
Dry Reforming ◽  
Dry Reforming Of Methane ◽  
Ni Nanoparticles ◽  
Stable Catalyst

scholarly journals Highly Active Ceria-Supported Ru Catalyst for the Dry Reforming of Methane: In Situ Identification of Ruδ+–Ce3+ Interactions for Enhanced Conversion

ACS Catalysis ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 3349-3359 ◽  
Author(s):  
Zongyuan Liu ◽  
Feng Zhang ◽  
Ning Rui ◽  
Xing Li ◽  
Lili Lin ◽  
...  
Keyword(s):  
Dry Reforming ◽  
Dry Reforming Of Methane ◽  
Ru Catalyst ◽  
Highly Active

scholarly journals Dry Reforming of Methane on a Highly-Active Ni-CeO2 Catalyst: Effects of Metal-Support Interactions on C−H Bond Breaking

2016 ◽  
Vol 128 (26) ◽  
pp. 7581-7585 ◽  
Author(s):  
Zongyuan Liu ◽  
David C. Grinter ◽  
Pablo G. Lustemberg ◽  
Thuy-Duong Nguyen-Phan ◽  
Yinghui Zhou ◽  
...  
Keyword(s):  
Dry Reforming ◽  
Dry Reforming Of Methane ◽  
Bond Breaking ◽  
Highly Active ◽  
Metal Support ◽  
Metal Support Interactions

scholarly journals Dry Reforming of Methane on a Highly-Active Ni-CeO2 Catalyst: Effects of Metal-Support Interactions on C−H Bond Breaking

2016 ◽  
Vol 55 (26) ◽  
pp. 7455-7459 ◽  
Author(s):  
Zongyuan Liu ◽  
David C. Grinter ◽  
Pablo G. Lustemberg ◽  
Thuy-Duong Nguyen-Phan ◽  
Yinghui Zhou ◽  
...  
Keyword(s):  
Dry Reforming ◽  
Dry Reforming Of Methane ◽  
Bond Breaking ◽  
Highly Active ◽  
Metal Support ◽  
Metal Support Interactions

One-Step Synthesis of Highly Active and Stable Ni–ZrOx for Dry Reforming of Methane

2020 ◽  
Vol 59 (25) ◽  
pp. 11441-11452 ◽  
Author(s):  
Ye Wang ◽  
Qing Zhao ◽  
Yannan Wang ◽  
Changwei Hu ◽  
Patrick Da Costa
Keyword(s):  
Dry Reforming ◽  
Dry Reforming Of Methane ◽  
Highly Active ◽  
One Step

scholarly journals Design of an active and stable catalyst for dry reforming of methane via molecular layer deposition

2021 ◽  
Vol 362 ◽  
pp. 47-54 ◽  
Author(s):  
Piyush Ingale ◽  
Chengyue Guan ◽  
Ralph Kraehnert ◽  
Raoul Naumann d’Alnoncourt ◽  
Arne Thomas ◽  
...  
Keyword(s):  
Molecular Layer ◽  
Dry Reforming ◽  
Dry Reforming Of Methane ◽  
Molecular Layer Deposition ◽  
Stable Catalyst ◽  
Layer Deposition
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