Intensification of biodiesel production from vegetable oils using ultrasonic-assisted process: Optimization and kinetic

Author(s):  
Babak Salamatinia ◽  
Hamed Mootabadi ◽  
Iman Hashemizadeh ◽  
Ahmad Zuhairi Abdullah
2014 ◽  
Vol 44 (1) ◽  
pp. 47-56
Author(s):  
M. O. FERREIRA ◽  
L. CARDOZO-FILHO ◽  
C. SILVA ◽  
E.M. B.D. SOUSA

Growing environmental concerns, along with the search for renewable energies that emit less CO2, put biodiesel in a favorable position. Biodiesel is commonly produced by the transesterification reaction between vegetable oils and methanol or ethanol, in the presence of a catalyst. With government incentives for biodiesel production in Brazil, there was an exaggerated increase in their production and hence the concern about the disposal of surplus glycerol. Therefore research is being developed with respect to the use of the surplus of glycerol. In this context, emerged as the alternative use of fuel additives, from glycerin to contribute to the development of new applications for innovative and environmentally-friendly processes. The bibliographic review presented here starts with describing the different glycerol production processes, characterization and analysis methods. Next, Glycerol-based processing methods are described, evaluating the main reaction parameters that interfere in process optimization.


2018 ◽  
Vol 35 (1) ◽  
pp. 47
Author(s):  
Fernando Carvalho Silva ◽  
Kiany Sirley Brandão Cavalcante ◽  
Hilton Costa Louzeiro ◽  
Katia Regina Marques Moura ◽  
Adeilton Pereira Maciel ◽  
...  

Maranhão state in Brazil presents a big potential for the cultivation of several oleaginous species, such as babassu, soybean, castor oil plant, etc... These vegetable oils can be transformed into biodiesel by the transesterification reaction in an alkaline medium, using methanol or ethanol. The biodiesel production from a blend of these alcohols is a way of adding the technical and economical advantages of methanol to the environmental advantages of ethanol. The optimized alcohol blend was observed to be a methanol/ethanol volume ratio of 80 % MeOH: 20 % EtOH. The ester content was of 98.70 %, a value higher than the target of the ANP, 96.5 % (m/m), and the biodiesel mass yield was of 95.32 %. This biodiesel fulfills the specifications of moisture, specific gravity, kinematic viscosity and percentages of free alcohols (methanol plus ethanol) and free glycerin.


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