Development and characterisation of a Y2Ti2O7-based glass-ceramic as a potential oxidation protective coating for titanium suboxide (TiOx)

Author(s):  
Fabiana D’Isanto ◽  
Federico Smeacetto ◽  
Hans-Peter Martin ◽  
Richard Sedlák ◽  
Maksym Lisnichuk ◽  
...  
2004 ◽  
Vol 85 (11) ◽  
pp. 2867-2869 ◽  
Author(s):  
Lianjun Wang ◽  
Changgong Meng ◽  
Changhou Liu ◽  
Liqiu Wang

Author(s):  
Y.I. Koltsova ◽  
◽  
V.I. Ovcharenko ◽  

This study was aimed at producing a porous layered glass ceramic material with a decorative-protective coating via one-stage firing. Waste products were used as gas-forming agents to fabricate a glass ceramic material, which partially solves a problem of their utilization; available natural raw materials were also used as gas-forming agents. A decorative-protective coating was applied simultaneously with the formation of the main layers of the material. It consisted of glass cullet and various amounts of coloring oxide. Firing of the samples was carried out at the temperature of 7500С. The coating containing 99.9 wt.% of glass cullet and 0.1 wt.% of Cr2O3 with the thickness of 425 m and having a greenish color was stated to be the coating of the highest quality. As a result of the research, a three-layer porous glass ceramic material was obtained with a low coefficient of thermal conductivity (0.056 W m–1 K–1). The presence of a fourth front decorative-protective layer will allow using this material in construction as a heat-insulating and structural material without additional cladding.


Author(s):  
T.R. Dinger ◽  
G. Thomas

The use of Si3N4, alloys for high temperature, high stress structural applications has prompted numerous studies of the oxynitride glasses which exist as intergranular phases in their microstructures. Oxynitride glasses have been investigated recently in their bulk form in order to understand their crystallization behavior for subsequent Si3N4 applications and to investigate their worth as glass-ceramic precursors. This research investigates the crystallization sequence of a glass having a normalized composition of Y26Si30Al11 ON11 and lying in the A1N-Y2O3-SiO2 section of the Y-Si-Al-O-N system. Such glasses exist as intergranular phases in the technologically important Y2O3/Al2O3-fluxed Si3N4 alloys.


The choice of cost-effective method of anticorrosive protection of steel structures is an urgent and time consuming task, considering the significant number of protection ways, differing from each other in the complex of technological, physical, chemical and economic characteristics. To reduce the complexity of solving this problem, the author proposes a computational tool that can be considered as a subsystem of computer-aided design and used at the stage of variant and detailed design of steel structures. As a criterion of the effectiveness of the anti-corrosion protection method, the cost of the protective coating during the service life is accepted. The analysis of existing methods of steel protection against corrosion is performed, the possibility of their use for the protection of the most common steel structures is established, as well as the estimated period of effective operation of the coating. The developed computational tool makes it possible to choose the best method of protection of steel structures against corrosion, taking into account the operating conditions of the protected structure and the possibility of using a protective coating.


2008 ◽  
Author(s):  
Xiaomei Guo ◽  
Kewen Kevin. Li ◽  
Xuesheng Chen ◽  
Yingyin Kevin. Zou ◽  
Hua Jiang

2020 ◽  
Vol 56 (1) ◽  
pp. 57-69
Author(s):  
S. P. Rogalskiy ◽  
I. A. Morozovskaya ◽  
M. A. Boretskaya ◽  
T. V. Cherniavskaya ◽  
O. P. Tarasiuk ◽  
...  
Keyword(s):  

2019 ◽  
Vol 85 (12) ◽  
pp. 43-50
Author(s):  
D. A. Movenko ◽  
L. V. Morozova ◽  
S. V. Shurtakov

The results of studying operational destruction of a high-loaded cardan shaft of the propeller engine made of steel 38KhN3MFA are presented to elucidate the cause of damage and develop a set of recommendations and measures aimed at elimination of adverse factors. Methods of scanning electron and optical microscopy, as well as X-ray spectral microanalysis are used to determine the mechanical properties, chemical composition, microstructure, and fracture pattern of cardan shaft fragments. It is shown that the mechanical properties and chemical composition of the material correspond to the requirements of the regulatory documentation, defects of metallurgical origin both in the shaft metal and in the fractures are absent. The microstructure of the studied shaft fragments is tempered martensite. Fractographic analysis revealed that the destruction of cardan shaft occurred by a static mechanism. The fracture surface is coated with corrosion products. The revealed cracks developed by the mechanism of corrosion cracking due to violation of the protective coating on the shaft. The results of the study showed that the destruction of the cardan shaft of a propeller engine made of steel 38Kh3MFA occurred due to formation and development of spiral cracks by the mechanism of stress corrosion cracking under loads below the yield point of steel. The reason for «neck» formation upon destruction of the shaft fragment is attributed to the yield point of steel attained during operation. Regular preventive inspections are recommended to assess the safety of the protective coating on the shaft surface to exclude formation and development of corrosion cracks.


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