In situ analysis of major and trace elements of anhydrous minerals by LA-ICP-MS without applying an internal standard

2008 ◽  
Vol 257 (1-2) ◽  
pp. 34-43 ◽  
Author(s):  
Yongsheng Liu ◽  
Zhaochu Hu ◽  
Shan Gao ◽  
Detlef Günther ◽  
Juan Xu ◽  
...  
2000 ◽  
Vol 12 (5) ◽  
pp. 1015-1024 ◽  
Author(s):  
Xian-Hua Li ◽  
Xirong Liang ◽  
Min Sun ◽  
Ying Liu ◽  
Xianglin Tu

2018 ◽  
Vol 1044 ◽  
pp. 200-202
Author(s):  
Maria Luisa Astolfi ◽  
Elisabetta Marconi ◽  
Carmela Protano ◽  
Matteo Vitali ◽  
Elisa Schiavi ◽  
...  

Author(s):  
John D. Greenough ◽  
Alejandro Velasquez ◽  
Mohamed Shaheen ◽  
Joel Gagnon ◽  
Brian J. Fryer ◽  
...  

Trace elements in native gold provide a “fingerprint” that tends to be unique to individual gold deposits. Fingerprinting can distinguish gold sources and potentially yield insights into geochemical processes operating during gold deposit formation. Native gold grains come from three historical gold ore deposits; Hollinger, McIntyre (quartz-vein ore), and Aunor near Timmins, Ontario, at the western end of the Porcupine gold camp and the south-western part of the Abitibi greenstone belt. Laser-ablation, inductively-coupled plasma mass spectrometry (LA ICP MS) trace element concentrations were determined on 20 to 25 µm wide, 300 µm long rastor trails in ~ 60 native gold grains. Analyses used Ag as an internal standard with Ag and Au determined by a scanning electron microscope with an energy dispersive spectrometer. The London Bullion Market AuRM2 reference material served as the external standard for 21 trace element analytes (Al, As, Bi, Ca, Cr, Cu, Fe, Mg, Mn, Ni, Pb, Pd, Pt, Rh, Sb, Se, Si, Sn, Te, Ti, Zn; Se generally below detection in samples). Trace elements in native gold associate according to Goldschmidt’s classification of elements strongly suggesting that element behavior in native Au is not random. Such element behavior suggests that samples from each Timmins deposit formed under similar but slightly variable geochemical conditions. Chalcophile and siderophile elements provide the most compelling fingerprints of the three ore deposits and appear to be mostly in solid solution in Au. Lithophile elements are not very useful for distinguishing these deposits and element ABSTRACT CUT OFF BY SOFTWARE


2019 ◽  
Vol 2019 (1) ◽  
pp. 1-5
Author(s):  
Xuejing Gong ◽  
Qingtian Lü ◽  
Guixiang Meng ◽  
Jiayong Yan ◽  
Jinhua Zhao

1980 ◽  
Vol 17 (9) ◽  
pp. 1246-1258 ◽  
Author(s):  
J. B. Whalen

The Ackley City batholith of southeast Newfoundland is an oval-shaped granitoid of approximately 5400 km2 which intruded Ordovician and Precambrian rocks of the Gander and Avalon tectonic zones, respectively, about 345 Ma ago. It is a composite body, consisting mainly of K-feldspar megacrystic granite and alaskite. Spatially related to the southeast contact of the alaskite are younger aplites and pegmatites within which are six separate molybdenite showings. The showings vary in their type of host rocks and in features of mineralization and alteration, but can all be classed as being of aplite–pegmatite type.This notably felsic (SiO2 > 71.8%) pluton has alkaline affinities and features indicative of derivation from an igneous source (I-type). Some major and trace elements exhibit considerable variations. These variations and other geological features indicate that aplites and pegmatites formed by in situ fractional crystallization of the alaskite at shallow depths (1.8 to 3.7 km) to produce a roof-zone complex. Mo is localized in these rocks, which formed from the final residual melt and coexisting vapour phase, and is considered to be closely genetically related to them.


2016 ◽  
Vol 31 (4) ◽  
pp. 1012-1022 ◽  
Author(s):  
Bao Zhian ◽  
Yuan Honglin ◽  
Zong Chunlei ◽  
Liu Ye ◽  
Chen Kaiyun ◽  
...  

A new glass-making method was developed to allow the in situ analysis of trace elements and lead isotopes in rock samples.


2015 ◽  
Vol 22 (4) ◽  
pp. 489-498 ◽  
Author(s):  
Jacques Bezuidenhout ◽  
Nicole Dames ◽  
Alfred Botha ◽  
Marina V. Frontasyeva ◽  
Zoya I. Goryainova ◽  
...  

Abstract Invasive bivalve molluscs, Mediterranean mussels (Mytilus galloprovincialis) were used as sentinel biomonitors of pollution by inorganic contaminants in Saldanha Bay and the Langebaan Lagoon area of South Africa. Two complementary analytical techniques, ICP-MS and NAA, allowed for determination of concentrations of 31 major and trace elements including heavy metals and arsenic in the soft tissues of the mussels. Distinct seasonal patterns were found in the dynamics of these concentrations, with the mussels accumulating much more trace elements in winter than in the summer. In general, the mussels that grew naturally also demonstrated higher concentrations of As, Cd, Fe, Hg and Zn than those that were farmed. Fe showed the highest levels with a maximum concentration of 444 mg/kg followed by Zn with a maximum of 228 mg/kg. The concentrations of Mn and Pb were significantly higher in the Port of Saldanha close to the jetty where ores containing these metals are loaded in comparison with the other sampling sites. It was concluded that bivalve molluscs present themselves as effective biomonitors when assessing marine aquatic pollution by inorganic contaminants in the Saldanha Bay region.


Sign in / Sign up

Export Citation Format

Share Document