A Raman spectroscopic tool to estimate chemical composition of natural volcanic glasses

Whilst some atention has in the past been devoted to the question of the properties of natural glasses, very little has been done to indicate the interrelations of the properties determined. In the case of tile natural volcanic glasses, this is unfortullately only too evident from a study of the standard text-books. A determination of such properties as density, refractivity, ttud chemical composition, and the interrelations of these for particular glasses, is rarely to be found in the literature. The chief contribution to this subject is due to Stark, who has examined the refringence of a large number of volcanic glasses. Unfortunately, there is no record of the density of these rocks, and the interrelation of these remained unknown.

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Raman spectroscopic study of four Spanish shocked ordinary chondrites: Cañellas, Olmedilla de Alarcón, Reliegos and Olivenza

Philosophical Transactions of The Royal Society A Mathematical Physical and Engineering Sciences ◽

10.1098/rsta.2010.0104 ◽

2010 ◽

Vol 368 (1922) ◽

pp. 3153-3166 ◽

Cited By ~ 13

Author(s):

F. Rull ◽

M. J. Muñoz-Espadas ◽

R. Lunar ◽

J. Martínez-Frías

Keyword(s):

Raman Spectroscopy ◽

Chemical Composition ◽

Spectral Band ◽

Shock Metamorphism ◽

Structural Deformation ◽

Ordinary Chondrites ◽

Raman Spectroscopic ◽

Raman Spectroscopic Study ◽

Vibrational Characteristics ◽

The Impact

Shock metamorphism in chondritic parent bodies produces typical textures, visible under the microscope, which are a consequence of structural deformation of the crystals. Such deformations can be studied with Raman spectroscopy. The vibrational characteristics of olivines and pyroxenes, structurally deformed by weak-to-moderate shock metamorphism, have been determined on four Spanish ordinary chondrites (Cañellas, Olmedilla de Alarcón, Reliegos and Olivenza). Such deformations would affect, in principle, the band positions and widths of the Raman spectra peaks. The measured band positions and relative intensities are consistent with chemical composition for olivines and pyroxenes, but show little influence on the degree of shock. However, the full spectral band width of the silicate internal modes shows some dependence on the impact grade, which could be attributed to inhomogeneous effects produced by the impacts.

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Long-Term Structural Modification of Water under Microwave Irradiation: Low-Frequency Raman Spectroscopic Measurements

Advances in Optical Technologies ◽

10.1155/2017/5260912 ◽

2017 ◽

Vol 2017 ◽

pp. 1-5 ◽

Cited By ~ 1

Author(s):

A. V. Yakunov ◽

M. M. Biliy ◽

A. P. Naumenko

Keyword(s):

Chemical Composition ◽

Water Samples ◽

Structural Changes ◽

Low Frequency ◽

Percolation Cluster ◽

Equilibrium Structure ◽

Sample Volume ◽

Raman Spectroscopic ◽

Network Of Hydrogen Bonds

Raman scattering has been used to study the influence of 2.45 GHz microwave on the structure of water. It has been shown that treatment of the distilled water samples by electromagnetic field leads to long-term changes in the vibrational density of states. It was established that the retention time of structural changes of the water samples depends on the sample volume. The experimental results have been interpreted on the basis of the percolation model. It has been suggested that the change in the chemical composition of the water treated by microwaves can lead to a change in the structure of the percolation cluster formed by the network of hydrogen bonds. The time of the equilibrium structure recovery of the percolation cluster after termination of the microwaves depends on the cluster size and is much slower than the recovery in the chemical composition of water.

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The Origin of the Moon

Symposium - International Astronomical Union ◽

10.1017/s0074180900178209 ◽

1962 ◽

Vol 14 ◽

pp. 149-155 ◽

Cited By ~ 1

Author(s):

E. L. Ruskol

Keyword(s):

Chemical Composition ◽

Solar System ◽

The Moon ◽

The Earth ◽

The Difference ◽

Origin Of The Moon

The difference between average densities of the Moon and Earth was interpreted in the preceding report by Professor H. Urey as indicating a difference in their chemical composition. Therefore, Urey assumes the Moon's formation to have taken place far away from the Earth, under conditions differing substantially from the conditions of Earth's formation. In such a case, the Earth should have captured the Moon. As is admitted by Professor Urey himself, such a capture is a very improbable event. In addition, an assumption that the “lunar” dimensions were representative of protoplanetary bodies in the entire solar system encounters great difficulties.

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On the Inhomogeneity of Chemical Composition over the Surface of 21 Per

International Astronomical Union Colloquium ◽

10.1017/s0252921100080659 ◽

1976 ◽

Vol 32 ◽

pp. 343-349

Author(s):

Yu.V. Glagolevsky ◽

K.I. Kozlova ◽

V.S. Lebedev ◽

N.S. Polosukhina

Keyword(s):

Chemical Composition ◽

Spectral Line ◽

Variable Star ◽

Radial Velocities ◽

Crimean Astrophysical Observatory ◽

Line Intensities ◽

Magnetic Variable

SummaryThe magnetic variable star 21 Per has been studied from 4 and 8 Å/mm spectra obtained with the 2.6 - meter reflector of the Crimean Astrophysical Observatory. Spectral line intensities (Wλ) and radial velocities (Vr) have been measured.

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Structural Studies on Mitotic Spindle Fibres

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100070345 ◽

1978 ◽

Vol 36 (3) ◽

pp. 615-626

Author(s):

J.R. Mcintosh

Keyword(s):

Chemical Composition ◽

Mitotic Spindle ◽

Structural Studies ◽

Mitotic Apparatus ◽

Chemical Studies ◽

Medical Interest ◽

Spindle Fibres

The mitotic apparatus is a structure of obvious biological and medical interest, but it has proved to be a difficult cellular machine to understand. The chemical composition of the spindle is only slightly elucidated, largely because of the difficulties in preparing useful isolates of the structure. Chemical studies of the mitotic spindle have been reviewed elsewhere (Mcintosh, 1977), and will not be discussed further here. One would think that structural studies on the mitotic apparatus (MA) in situ would be straightforward, but even with this approach there is some disagreement in the results obtained with various methods and by different investigators. In this paper I will review briefly the approaches which have been used in structural studies of the MA, pointing out the strengths and problems of each approach. I will summarize the principal findings of the different methods, and identify what seem to be fruitful avenues for further work.

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Effects of 5-5'-Diphenyl-2-thiohydantoin (DPTH) and Thyroxine on the Ultrastructure and Chemical Composition of Rat Liver

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100066917 ◽

1971 ◽

Vol 29 ◽

pp. 570-571

Author(s):

E. A. Elfont ◽

R. B. Tobin ◽

D. G. Colton ◽

M. A. Mehlman

Keyword(s):

Chemical Composition ◽

Rat Liver ◽

Future Study ◽

Mode Of Action ◽

Liver Mitochondria ◽

Rat Liver Mitochondria ◽

Effective Inhibitor ◽

Biochemical Effects ◽

Glycerophosphate Dehydrogenase ◽

Stimulation Of

Summary5,-5'-diphenyl-2-thiohydantoin (DPTH) is an effective inhibitor of thyroxine (T4) stimulation of α-glycerophosphate dehydrogenase in rat liver mitochondria. Because this finding indicated a possible tool for future study of the mode of action of thyroxine, the ultrastructural and biochemical effects of DPTH and/or thyroxine on rat liver mere investigated.Rats were fed either standard or DPTH (0.06%) diet for 30 days before T4 (250 ug/kg/day) was injected. Injection of T4 occurred daily for 10 days prior to sacrifice. After removal of the liver and kidneys, part of the tissue was frozen at -50°C for later biocheailcal analyses, while the rest was prefixed in buffered 3.5X glutaraldehyde (390 mOs) and post-fixed in buffered 1Z OsO4 (376 mOs). Tissues were embedded in Araldlte 502 and the sections examined in a Zeiss EM 9S.Hepatocytes from hyperthyroid rats (Fig. 2) demonstrated enlarged and more numerous mitochondria than those of controls (Fig. 1). Glycogen was almost totally absent from the cytoplasm of the T4-treated rats.

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Applications of Photoelectron Microscopy

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100092499 ◽

1976 ◽

Vol 34 ◽

pp. 506-507

Author(s):

William J. Baxter

Keyword(s):

Electron Microscopy ◽

Thermal Decomposition ◽

Chemical Composition ◽

Ultraviolet Radiation ◽

Thin Layer ◽

Edge Effects ◽

Electron Optics ◽

Surface Layers ◽

Crystalline Orientation ◽

Fluorescent Screen

In this form of electron microscopy, photoelectrons emitted from a metal by ultraviolet radiation are accelerated and imaged onto a fluorescent screen by conventional electron optics. image contrast is determined by spatial variations in the intensity of the photoemission. The dominant source of contrast is due to changes in the photoelectric work function, between surfaces of different crystalline orientation, or different chemical composition. Topographical variations produce a relatively weak contrast due to shadowing and edge effects.Since the photoelectrons originate from the surface layers (e.g. ∼5-10 nm for metals), photoelectron microscopy is surface sensitive. Thus to see the microstructure of a metal the thin layer (∼3 nm) of surface oxide must be removed, either by ion bombardment or by thermal decomposition in the vacuum of the microscope.

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