Magneto-tunnelling transport of chiral charge carriers

<p>We study magneto-tunnelling between two parallel two-dimensional electron gases theoretically, where the electrons have a pseudo-spin-½ degree of freedom that is coupled to their momentum. The two-dimensional electron gases focused on in this work are single layer graphene, bilayer graphene, and single layer molybdenum disulphide. The results are derived using a linear response theory formalism in the weak tunnelling regime, and it is assumed that the electron gases are at zero temperature, with no interactions or disorder. The linear magneto-tunnelling conductance characteristics for an applied in-plane and tilted magnetic field are found to strongly depend on the pseudo-spin structure of the tunnelling matrix and the pseudo-spin's dependence on momentum. For instance, resonances in the linear magneto-tunnelling conductance are sensitive to the pseudo-spin tunnel-coupling across the barrier and how the pseudo-spin eigenstates are coupled to momentum. We discuss how measurements of the magneto-tunnelling conductance can be applied as a spectroscopic tool. We explain how to measure the pseudo-spin tunnel-coupling through least squares parameter fitting of the magneto-tunnelling conductance. We show that the parameters are interdependent, one can use the interdependency to test the consistency between theory and experiment. It is expected that measurements of pseudo-spin tunnel-coupling will be a function of the lattice structure of the double layer system, which suggests these measurements can be used as a spectroscopic tool. Additionally, we investigate in-plane electric fields in single layer graphene to see if their effects can be observed in magneto-tunnelling transport. Then, we perturbatively include the effects of electron-electron interactions in single layer graphene, and find it should dampen the linear tunnelling conductance. We investigate tunnel-coupled , parallel , single layer and bilayer graphene systems. We find that using an in-plane magnetic field, one can generate a valley polarized tunnelling current. This method is unique because it does not require manipulation of the single and bilayer graphene samples through nano-structuring, coupling to electromagnetic fields, application of mechanical strain, or the presence of defects. In particular, the valley polarization is dependent on the pseudo-spin tunnel-coupling between the single and bilayer graphene systems, and the strength of an applied in-plane magnetic field. We explicitly show through analytic derivations how an understanding of linear magneto-tunnelling transport (zero bias limit) can be used to understand non-linear magneto-tunnelling transport (finite bias).</p>

Magneto-tunnelling transport of chiral charge carriers

<p>We study magneto-tunnelling between two parallel two-dimensional electron gases theoretically, where the electrons have a pseudo-spin-½ degree of freedom that is coupled to their momentum. The two-dimensional electron gases focused on in this work are single layer graphene, bilayer graphene, and single layer molybdenum disulphide. The results are derived using a linear response theory formalism in the weak tunnelling regime, and it is assumed that the electron gases are at zero temperature, with no interactions or disorder. The linear magneto-tunnelling conductance characteristics for an applied in-plane and tilted magnetic field are found to strongly depend on the pseudo-spin structure of the tunnelling matrix and the pseudo-spin's dependence on momentum. For instance, resonances in the linear magneto-tunnelling conductance are sensitive to the pseudo-spin tunnel-coupling across the barrier and how the pseudo-spin eigenstates are coupled to momentum. We discuss how measurements of the magneto-tunnelling conductance can be applied as a spectroscopic tool. We explain how to measure the pseudo-spin tunnel-coupling through least squares parameter fitting of the magneto-tunnelling conductance. We show that the parameters are interdependent, one can use the interdependency to test the consistency between theory and experiment. It is expected that measurements of pseudo-spin tunnel-coupling will be a function of the lattice structure of the double layer system, which suggests these measurements can be used as a spectroscopic tool. Additionally, we investigate in-plane electric fields in single layer graphene to see if their effects can be observed in magneto-tunnelling transport. Then, we perturbatively include the effects of electron-electron interactions in single layer graphene, and find it should dampen the linear tunnelling conductance. We investigate tunnel-coupled , parallel , single layer and bilayer graphene systems. We find that using an in-plane magnetic field, one can generate a valley polarized tunnelling current. This method is unique because it does not require manipulation of the single and bilayer graphene samples through nano-structuring, coupling to electromagnetic fields, application of mechanical strain, or the presence of defects. In particular, the valley polarization is dependent on the pseudo-spin tunnel-coupling between the single and bilayer graphene systems, and the strength of an applied in-plane magnetic field. We explicitly show through analytic derivations how an understanding of linear magneto-tunnelling transport (zero bias limit) can be used to understand non-linear magneto-tunnelling transport (finite bias).</p>

Validation of microscopic magnetochiral dichroism theory

Magnetochiral dichroism (MChD), a fascinating manifestation of the light-matter interaction characteristic for chiral systems under magnetic fields, has become a well-established optical phenomenon reported for many different materials. However, its interpretation remains essentially phenomenological and qualitative, because the existing microscopic theory has not been quantitatively confirmed by confronting calculations based on this theory with experimental data. Here, we report the experimental low-temperature MChD spectra of two archetypal chiral paramagnetic crystals taken as model systems, tris(1,2-diaminoethane)nickel(II) and cobalt(II) nitrate, for light propagating parallel or perpendicular to the c axis of the crystals, and the calculation of the MChD spectra for the Ni(II) derivative by state-of-the-art quantum chemical calculations. By incorporating vibronic coupling, we find good agreement between experiment and theory, which opens the way for MChD to develop into a powerful chiral spectroscopic tool and provide fundamental insights for the chemical design of new magnetochiral materials for technological applications.

Seeking a Fast Screening Method of the Varietal Origin of Olive Oil: The Usefulness of an NMR-Based Approach

This work encompasses the use of 1D multinuclear NMR spectroscopy, namely, 1H NMR and 13C NMR DEPT 45, combined with a multivariate statistical analysis to characterize olive oils produced from nine different varieties: Galega Vulgar, Cobrançosa, Cordovil de Serpa, Blanqueta, Madural, Verdeal Alentejana, Arbequina, Picual and Carrasquenha. Thus, the suitability of an NMR-based spectroscopic tool to discriminate olive oils according to their varietal origin is addressed. The results obtained show that the model based on 13C NMR DEPT 45 data has a stronger performance than the model based on 1H NMR data, proving to be promising in the discrimination of the olive oils under study based on their varietal origin, being particularly relevant for olive oils of the Galega Vulgar variety.

Improving Resolution of Dual-Comb Gas Detection Using Periodic Spectrum Alignment Method

Dual-comb spectroscopy has been an infusive spectroscopic tool for gas detection due to its high resolution, high sensitivity, and fast acquisition speed over a broad spectral range without any mechanical scanning components. However, the complexity and cost of high-performance dual-comb spectroscopy are still high for field-deployed applications. To solve this problem, we propose a simple frequency domain post-processing method by extracting the accurate position of a specific absorption line frame by frame. After aligning real-time spectra and averaging for one second, the absorbance spectrum of H13C14N gas in the near-infrared is obtained over 1.1 THz spectral range. By using this method, the standard deviation of residual error is only ~0.002, showing great agreement with the conventional correction method. In addition, the spectral resolution is improved from 13.4 GHz to 4.3 GHz compared to direct spectrum averaging. Our method does not require a specially designed common-mode suppression comb, rigorous frequency control system, or complicated computational algorithm, providing a cost-effective scheme for field-deployed Doppler-limited spectroscopy applications.

ATR-FTIR spectroscopy for virus identification: A powerful alternative

In pandemic times, like the one we are witnessing for COVID-19, the discussion about new efficient and rapid techniques for diagnosis of diseases is more evident. In this mini-review, we present to the virological scientific community the potential of attenuated total reflection Fourier-transform infrared (ATR-FTIR) spectroscopy as a diagnosis technique. Herein, we explain the operation of this technique, as well as its advantages over standard methods. In addition, we also present the multivariate analysis tools that can be used to extract useful information from the data towards classification purposes. Tools such as Principal Component Analysis (PCA), Successive Projections Algorithm (SPA), Genetic Algorithm (GA) and Linear and Quadratic Discriminant Analysis (LDA and QDA) are covered, including examples of published studies. Finally, the advantages and disadvantages of ATR-FTIR spectroscopy are emphasized, as well as future prospects in this field of study that is only growing. One of the main aims of this paper is to encourage the scientific community to explore the potential of this spectroscopic tool to detect changes in biological samples such as those caused by the presence of viruses.

Using the Emission of Muonic X-rays as a Spectroscopic Tool for the Investigation of the Local Chemistry of Elements

There are several techniques providing quantitative elemental analysis, but very few capable of identifying both the concentration and chemical state of elements. This study presents a systematic investigation of the properties of the X-rays emitted after the atomic capture of negatively charged muons. The probability rates of the muonic transitions possess sensitivity to the electronic structure of materials, thus making the muonic X-ray Emission Spectroscopy complementary to the X-ray Absorption and Emission techniques for the study of the chemistry of elements, and able of unparalleled analysis in case of elements bearing low atomic numbers. This qualitative method is applied to the characterization of light elements-based, energy-relevant materials involved in the reaction of hydrogen desorption from the reactive hydride composite Ca(BH4)2-Mg2NiH4. The origin of the influence of the band-structure on the muonic atom is discussed and the observed effects are attributed to the contribution of the electronic structure to the screening and to the momentum distribution in the muon cascade.