A number of distinct or non-isomorphic kinematic chains exist for a specified number of links and joints. For example, sixteen distinct chains can be obtained with eight links and two hundred and thirty chains with ten links having a single degree of freedom. Similarly, many space mechanisms can be formed with four links and joints having different degrees of freedom. So far no measure is available to know which of these possesses greater mobility or flexibility. Flexibility is not to be confused with the degree of freedom. Intuitively one feels that a six-link chain has greater flexibility than a four-bar chain both having the same degrees of freedom. Though the mobility of a chain increases with the number of links one is not sure how the structural arrangement, type of links and joints, their numbers and sequence etc. influence the same. Combining graph theory with the concepts of probability, simple formulae are developed to investigate the relative merits of spatial and planar kinematic chains. The greater the flexibility or mobility of the chain, the higher is the ability to meet the motion requirements, i.e., a chain having greater entropy can be expected, say, to reproduce a given function more accurately.