Dummy molecularly imprinted mesoporous silica prepared by hybrid imprinting method for solid-phase extraction of bisphenol A

2015 ◽  
Vol 1396 ◽  
pp. 17-24 ◽  
Author(s):  
Dan Yu ◽  
Xiaolei Hu ◽  
Shoutai Wei ◽  
Qiang Wang ◽  
Chiyang He ◽  
...  
2017 ◽  
Vol 1067 ◽  
pp. 25-33 ◽  
Author(s):  
Tamires Amabile Valim Brigante ◽  
Luis Felippe Cabral Miranda ◽  
Israel Donizeti de Souza ◽  
Vinicius Ricardo Acquaro Junior ◽  
Maria Eugênia Costa Queiroz

2015 ◽  
Vol 7 (15) ◽  
pp. 6299-6306 ◽  
Author(s):  
Tayyebeh Madrakian ◽  
Abbas Afkhami ◽  
Ehsan Vanaei ◽  
Mazaher Ahmadi

Solid phase extraction of leached bisphenol A from some polycarbonate products using surface molecularly imprinted nanospheres.


2016 ◽  
Vol 23 (4) ◽  
pp. 651-664 ◽  
Author(s):  
Anna Poliwoda ◽  
Małgorzata Mościpan ◽  
Piotr P. Wieczorek

Abstract Selective molecularly imprinted polymers (MIPs) with bisphenol A as template were synthesized using the non-covalent imprinting approach. MIPs were prepared using thermally initiated polymerization with 1,1’-azobis(cyclohexanecarbonitryle) (ACHN) as initiator and ethylene glycol dimethacrylate (EDMA) as a cross-linking agent. The tested functional monomers included methacrylic acid, acrylamide, and 4-vinylpyridine. The selectivity of the BPA-MIP for the solid phase extraction of bisphenol A was tested in samples containing other related alkylphenols. The polymers prepared in acetonitrile using methacrylic acid or acrylamide as monomer showed the highest selectivity towards target analyte (the selectivity ratio 8:1, respectively for MIP and NIP). The proposed procedure has been proven to be an effective for selective extraction of bisphenol A in aqueous samples (recoveries over 85%) enabling detection and quantification limits of 25 and 70 μg/dm3, respectively based on 10 cm3 of sample volume, with relative standard deviations (RSD) lower than 6%. The obtained molecularly imprinted material showed interesting properties for selective extraction and preconcentration of studied analyte from large volumes of aqueous samples without any problems of cartridge clogging.


2010 ◽  
Vol 397 (2) ◽  
pp. 815-822 ◽  
Author(s):  
Claudio Baggiani ◽  
Patrizia Baravalle ◽  
Cristina Giovannoli ◽  
Laura Anfossi ◽  
Gianfranco Giraudi

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