scholarly journals How to give a renewed chance to natural gas as feed for the production of hydrogen: Electric MSR coupled with CO2 mineralization

2021 ◽  
Vol 5 ◽  
pp. 100280
Author(s):  
Gianluca Natrella ◽  
Alessia Borgogna ◽  
Annarita Salladini ◽  
Gaetano Iaquaniello
Green ◽  
2013 ◽  
Vol 3 (1) ◽  
Author(s):  
Raphael Winkler-Goldstein ◽  
Aline Rastetter

AbstractIn Germany more than 20% of the energy mix is made up of renewable energy and its share is rapidly increasing. The federal government expects renewables to account for 35% of Germany's electricity consumption by 2020, 50% by 2030 and 80% by 2050. According to the German Energy Agency, multi-billion euro investments in energy storage are expected by 2020 in order to reach these goals. The growth of this fluctuating energy supply has created demand for innovative storage options in Germany and it is accelerating the development of technologies in this field. Along with batteries and smart grids, hydrogen is expected to be one of the lead technologies. 2010 a commercialization roadmap for wind hydrogen was set up by the two northern federal states of Hamburg and Schleswig-Holstein with the goal of utilizing surplus wind power for the electrolytic production of hydrogen. With the creation of the “performing energy initiative”, 2011, Brandenburg and Lower Saxony joined this undertaking. The aim of this initiative is to set up demonstration projects in order to develop and optimize wind-hydrogen hybrid systems and prepare their commercialization for the time after 2020. Beside the conversion of hydrogen into electricity and fuel for cars, further markets like raw material for the chemical, petrochemical, metallurgy and food industry are going to be addressed. Considering the fact there are over 40 caves currently used for natural gas storage with a total volume of 23.5 billion cubic meters and 400 000 km gas grid available in Germany, the German Technical and Scientific Association for Gas and Water sees opportunities for hydrogen to be fed into the existing natural gas grid network. The name of this concept is power-to-gas. According to the current DVGW-Standards natural gas in Germany can contain up to 5% hydrogen. The GERG, European Group on the Gas Research sees potential to increase this amount up to 6% to 20%. Power-to-gas could serve both for fuel and for the storage of extra energy produced by renewable sources. The hydrogen produced via electrolysis could be drawn upon – directly or as synthetic natural gas (SNG) in a second additional methanation process step – to provide electricity by means of CCGT (combined cycle gas turbines) or CHP (combined heat and power) using for example fuel cells. It could also address the industrial and household heat market. DVGW is furthermore participating in the “Power-to-Gas Platform” that was set up in 2012 by the German Energy Agency, bringing together RnD institutes, renewable energy project developers and park operators, utilities, underground storage providers in order to create political support for this new technology. Demonstration projects will be completed by 2020 in order to develop business models (for storage, production and trade of “green gas”) and devices (electrolysers, turbines, smart gas metering, compressors, storage capacities amongst others) to enable the implementation of this concept on a broad scale. This means that a multitude of industrial players will be involved in the changes that will occur in the value chain: utilities (electricity, gas), power technology companies, car makers, heating device manufacturers, but also manufacturers of measurement, regulation and control devices, suppliers of the biogas and methanation industry. Germany is the pioneer in this field. This technology however increasingly interests its neighbours, with project developments in France, Italy, Spain, and UK but also in North America and North Africa. Germany can contribute its valuable experience (e.g. legal framework for power-to-gas) to the development of these industries. German participants in demonstration projects in these countries could for example be renewable energy park operators, RnD institutes and suppliers.


Catalysts ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1401
Author(s):  
Pawel Mierczynski ◽  
Magdalena Mosinska ◽  
Waldemar Maniukiewicz ◽  
Krasimir Vasilev ◽  
Malgorzata Iwona Szynkowska-Jozwik

This work presents, for the first time, the comparative physicochemical and reactivity studies of a range of bimetallic Pt-Ni, Pd-Ni, Ru-Ni, and Ag-Ni catalysts in the oxy-steam reforming (OSR) of liquefied natural gas (LNG) reaction towards hydrogen generation. In order to achieve the intended purpose of this work, a binary oxide CeO2·ZrO2 (1:2) support was prepared via a co-precipitation method. The catalysts’ physicochemical properties were studied using X-ray diffraction (XRD), BET, TPR-H2, TPD-NH3, SEM-EDS and XPS methods. The highest activity in the studied process was exhibited by the 1%Pt-5%Ni catalyst supported on CeO2·ZrO2 (1:2) system. The highest activity of this system is explained by the specific interactions occurring between the components of the active phase and between the components of the active phase and the carrier itself. The activity results showed that this catalytic system exhibited above 71% of the methane conversion at 600 °C and 60% yield of hydrogen formation. The results of this work demonstrate that the Pt-Ni and Ru-Ni catalytic systems hold promise to be applied in the production of hydrogen to power solid oxide fuel cells.


Author(s):  
Kas Hemmes ◽  
Anish Patil ◽  
Nico Woudstra

In the framework of the project Greening of Gas, in which the feasibility of mixing hydrogen into the natural gas network in the NL is studied, we are exploring alternative hydrogen production methods. Fuel cells are usually only seen as devices that convert hydrogen into power and heat. It is less well known that these electrochemical energy converters can produce hydrogen, or form an essential component in systems for co-production of hydrogen and power. Co-production of hydrogen and power from NG in an Internal reforming fuel cell (IR FC) is worked out by flow sheet calculations on an Internal reforming Solid Oxide fuel cell (IR-SOFC) system. It is shown that the system can operate in a wide range of fuel utilization values at least from 60% representing highest hydrogen production mode to 95% corresponding to ‘normal’ fuel cell operation mode. For the atmospheric pressure system studied here hydrogen and CO content increase up to 22.6 and 13.5 % respectively at a fuel utilization of 60%. Total system efficiency (power + H2/CO) is increasing significantly at lower fuel utilization and can reach 94 %. Our study confirms that the calculations of Vollmar et al1) on an IR-SOFC stack also hold for a complete FC system. Notably that paradoxically a system with the same fuel cell stack when switched to hydrogen production mode can yield more power in addition to the H2 and CO produced. This is because the hydrogen production mode allows for operation at high current and power densities. The same system can double its power output (e.g. from 1.26 MW to 2.5 MW) while simultaneously increasing the H2 /CO output to 3.1MW). Economics of these systems is greatly improved. These systems can also be considered for hydrogen production for the purpose of mixing it with natural gas in the natural gas grid in order to reduce CO2 emissions at the end users, because of the ability to adopt the system rapidly to fluctuations in natural gas/hydrogen demand.


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