Mixed micellization of gemini and cationic surfactants: Physicochemical properties and solubilization of polycyclic aromatic hydrocarbons

2014 ◽  
Vol 451 ◽  
pp. 56-65 ◽  
Author(s):  
Jyotsna Lakra ◽  
Deepti Tikariha ◽  
Toshikee Yadav ◽  
Sibani Das ◽  
Soumen Ghosh ◽  
...  
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Physicochemical Properties ◽  
Aromatic Hydrocarbons ◽  
Cationic Surfactants ◽  
Mixed Micellization ◽  
Polycyclic Aromatic

scholarly journals Levels of Polycyclic Aromatic Hydrocarbons (PAHs) in Beers: Consumption and Public Health Concerns

2020 ◽  
pp. 47-59
Author(s):  
V. N. Okafor ◽  
U. B. Uche ◽  
R. C. Abailim
Keyword(s):  
Public Health ◽  
Polycyclic Aromatic Hydrocarbons ◽  
Specific Gravity ◽  
Physicochemical Properties ◽  
Aromatic Hydrocarbons ◽  
Alcohol Content ◽  
Marine Research ◽  
Health Concerns ◽  
Standard Methods ◽  
Polycyclic Aromatic

Aim: The aim is to investigate some physicochemical properties of beers and polycyclic aromatic hydrocarbons contaminants in beer brewed with isomerized hop extract and in comparison with beers brewed with extracts from four Nigerian potential hop substitutes. Study Design: Beers were brewed using isomerized hop extract and extracts from four Nigerian bitter vegetables. Analyses of physicochemical properties of the beers and for the presence of 16 specific target PAHs were carried out using their respective standard methods. Place and Duration of Study: Analysis of physicochemical properties of the beers was done at Nigerian Breweries PLC, Enugu while analysis for PAHs was conducted at Central Laboratory, Nigerian Institute for Oceanography and Marine Research, Lagos between July, 2018 and November, 2019. Methodology: Physicochemical properties of the beers (alcohol content, bitterness level, pH, specific gravity, colour) were determined using their respective standard methods. Gas chromatography/mass spectrometry was used in analyzing for PAHs [naphthalene, acenaphthylene, acenaphthene, phenanthrene, anthracene, fluoranthene, pyrene, benzo(a)anthracene, chrysene, benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(a)pyrene, dibenzo(a,h)anthracene, indeno(1,2,3-cd)pyrene and benzo(g,h,i)perylene]. Four isotopically labelled PAHs (acenaphthene-d10, phenanthrene-d10, chrysene-d12 and perylene-d12) were used as internal standards. Results: Alcohol content (%v//v) in the beer samples is A(5.20); B(4.28); C(4.40); D(4.43) and E(4.54), bitterness level in International Bitterness Units (IBU) is A(0.54); B(0.80); C(1.46); D(1.46) and E(0.08), pH is A(4.36); B(3.08); C(3.88); D(3.90) and E(3.87), specific gravity is A(10.06); B(10.00); C(10.00); D(10.06) and E(10.06), and beer colour is A(5.80); B(7.70); C(6.60); D(8.00) and E(7.40). All 16 EPA PAHs were not found in all the beer samples except pyrene which was detected in sample B at a concentration of 0.00402 mg/kg. Conclusion: It is concluded that extracts from the four Nigerian bitter vegetables could be used as substitutes for isomerized hop extract and that consumption of beer produced using extract from G. kola poses great public health concerns.

Physicochemical properties and health risk assessment of polycyclic aromatic hydrocarbons of fragrant rapeseed oils in China

2020 ◽  
Vol 100 (8) ◽  
pp. 3351-3359
Author(s):  
Youfeng Zhang ◽  
Yun Zhu ◽  
Longkai Shi ◽  
Yue Guo ◽  
Lai Wei ◽  
...  
Keyword(s):  
Risk Assessment ◽  
Polycyclic Aromatic Hydrocarbons ◽  
Health Risk ◽  
Physicochemical Properties ◽  
Health Risk Assessment ◽  
Aromatic Hydrocarbons ◽  
Polycyclic Aromatic

scholarly journals Two physicochemical properties of benzenoid chains: solvent accessible molecular volume and molar refraction

2019 ◽  
Vol 97 (5) ◽  
pp. 524-528
Author(s):  
Akbar Ali ◽  
Zafar Iqbal ◽  
Zaffar Iqbal
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Physicochemical Properties ◽  
Aromatic Hydrocarbons ◽  
Fixed Number ◽  
Molar Refraction ◽  
Molecular Structures ◽  
Molecular Volume ◽  
Randić Index ◽  
Randic Index ◽  
Polycyclic Aromatic

Predicting physicochemical properties of molecules is one of the fundamental tasks in chemical physics. Many predictive methods have been developed for correlating the molecular structures with their physicochemical properties. One of the simplest such methods involves topological indices. Edge connectivity index (or equivalently, reformulated Randić index), which is denoted as ε, seems to be a good topological index for predicting the solvent accessible molecular volume and molar refraction of polycyclic aromatic hydrocarbons. In this paper, a closed-form formula for calculating the reformulated Randić index ε of benzenoid hydrocarbon chains (or simply, benzenoid chains, which represent a type of polycyclic aromatic hydrocarbons) is derived. Benzenoid chains with maximum (and minimum) ε value are also determined from the collection of all benzenoid chains having fixed number of hexagonal rings. Moreover, an attempt is made to generalize the obtained results for reformulated bond incident degree indices.

EXPERIMENTAL AND NUMERICAL STUDY OF COMBUSTION OF AVIATION KEROSENE TS-1 SURROGATES

2020 ◽  
Author(s):  
D. V. Idrisov ◽  
◽  
S. S. Matveev ◽  
S. G. Matveev ◽  
N. I. Gurakov ◽  
...  
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Physicochemical Properties ◽  
Reference Values ◽  
Aromatic Hydrocarbons ◽  
Molar Mass ◽  
Numerical Study ◽  
Combustion Chambers ◽  
Aviation Kerosene ◽  
Cyclic Alkanes ◽  
Polycyclic Aromatic

The article analyzes two types of kerosene surrogates: six-component SU1 and four-component SU2. The characteristics of the both differ from the accepted reference values no more than by 1%. It is revealed that multicomponent surrogates are necessary for reproducing the physicochemical properties of the real aviation kerosene. In addition, various classes of hydrocarbons such as alkanes, cyclic alkanes, and aromatic hydrocarbons should be included in order to meet these properties. Other parameters such as density, H/C ratio, and molar mass impose additional and important constraints on the development of surrogates. Several methods for combined reactor prediction of the concentrations of carcinogenic polycyclic aromatic hydrocarbons (PAHs) in aircraft kerosene combustion chambers have been proposed and investigated.

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