AFM study of conducting polymer polypyrrole nanoparticles formed by redox enzyme – glucose oxidase – initiated polymerisation

2006 ◽  
Vol 48 (2) ◽  
pp. 159-166 ◽  
Author(s):  
Almira Ramanaviciene ◽  
Wolfgang Schuhmann ◽  
Arunas Ramanavicius
2018 ◽  
Vol 122 (17) ◽  
pp. 9491-9498 ◽  
Author(s):  
Urte Bubniene ◽  
Raminta Mazetyte ◽  
Almira Ramanaviciene ◽  
Vidmantas Gulbinas ◽  
Arunas Ramanavicius ◽  
...  

2014 ◽  
Vol 16 (33) ◽  
pp. 17426-17436 ◽  
Author(s):  
Marccus V. A. Martins ◽  
Andressa R. Pereira ◽  
Roberto A. S. Luz ◽  
Rodrigo M. Iost ◽  
Frank N. Crespilho

Graphene oxide sheets provide short-range electron transfer from the glucose oxidase enzyme to the electrode surface.


Polymers ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 2173
Author(s):  
Natalija German ◽  
Almira Ramanaviciene ◽  
Arunas Ramanavicius

Biosensors for the determination of glucose concentration have a great significance in clinical diagnosis, and in the food and pharmaceutics industries. In this research, short-chain polyaniline (PANI) and polypyrrole (Ppy)-based nanocomposites with glucose oxidase (GOx) and 6 nm diameter AuNPs (AuNPs(6 nm)) were deposited on the graphite rod (GR) electrode followed by the immobilization of GOx. Optimal conditions for the modification of GR electrodes by conducting polymer-based nanocomposites and GOx were elaborated. The electrodes were investigated by cyclic voltammetry and constant potential amperometry in the presence of the redox mediator phenazine methosulfate (PMS). The improved enzymatic biosensors based on GR/PANI-AuNPs(6 nm)-GOx/GOx and GR/Ppy-AuNPs(6 nm)-GOx/GOx electrodes were characterized by high sensitivity (65.4 and 55.4 μA mM−1 cm−2), low limit of detection (0.070 and 0.071 mmol L−1), wide linear range (up to 16.5 mmol L−1), good repeatability (RSD 4.67 and 5.89%), and appropriate stability (half-life period (τ1/2) was 22 and 17 days, respectively). The excellent anti-interference ability to ascorbic and uric acids and successful practical application for glucose determination in serum samples was presented for GR/PANI-AuNPs(6 nm)-GOx/GOx electrode.


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