Enhanced H2+ and D2+ production from water isotopologues: Dependence on laser’s wavelength

2020 ◽  
Vol 756 ◽  
pp. 137835
Author(s):  
Emmanouil Kechaoglou ◽  
Constantine Kosmidis
Keyword(s):  
Author(s):  
Jacob Willem Kooi ◽  
Darren Hayton ◽  
Paul Goldsmith ◽  
Dariusz Lis ◽  
Jonathan Kawamura ◽  
...  

2015 ◽  
Vol 120 (13) ◽  
pp. 6712-6729 ◽  
Author(s):  
S. J. Sutanto ◽  
G. Hoffmann ◽  
J. Worden ◽  
R. A. Scheepmaker ◽  
I. Aben ◽  
...  

2015 ◽  
Vol 15 (10) ◽  
pp. 5537-5555 ◽  
Author(s):  
R. Eichinger ◽  
P. Jöckel ◽  
S. Brinkop ◽  
M. Werner ◽  
S. Lossow

Abstract. This modelling study aims at an improved understanding of the processes that determine the water vapour budget in the stratosphere by means of the investigation of water isotope ratios. An additional (and separate from the actual) hydrological cycle has been introduced into the chemistry–climate model EMAC, including the water isotopologues HDO and H218O and their physical fractionation processes. Additionally an explicit computation of the contribution of methane oxidation to H2O and HDO has been incorporated. The model expansions allow detailed analyses of water vapour and its isotope ratio with respect to deuterium throughout the stratosphere and in the transition region to the troposphere. In order to assure the correct representation of the water isotopologues in the model's hydrological cycle, the expanded system has been evaluated in several steps. The physical fractionation effects have been evaluated by comparison of the simulated isotopic composition of precipitation with measurements from a ground-based network (GNIP) and with the results from the isotopologue-enabled general circulation model ECHAM5-wiso. The model's representation of the chemical HDO precursor CH3D in the stratosphere has been confirmed by a comparison with chemical transport models (1-D, CHEM2D) and measurements from radiosonde flights. Finally, the simulated stratospheric HDO and the isotopic composition of water vapour have been evaluated, with respect to retrievals from three different satellite instruments (MIPAS, ACE-FTS, SMR). Discrepancies in stratospheric water vapour isotope ratios between two of the three satellite retrievals can now partly be explained.


2018 ◽  
Vol 10 (2) ◽  
pp. 166 ◽  
Author(s):  
Tongmei Wang ◽  
Qiong Zhang ◽  
Stefan Lossow ◽  
Léon Chafik ◽  
Camille Risi ◽  
...  
Keyword(s):  

2021 ◽  
Author(s):  
Janica C. Bühler ◽  
Josefine M. Axelsson ◽  
Franziska A. Lechleitner ◽  
Jens Fohlmeister ◽  
Allegra N. LeGrande ◽  
...  

Abstract. The incorporation of water isotopologues into the hydrology of general circulation models (GCMs) facilitates the comparison between modelled and measured proxy data in paleoclimate archives. However, the variability and drivers of measured and modelled water isotopologues, and indeed the diversity of their representation in different models are not well constrained. Improving our understanding of this variability in past and present climates will help to better constrain future climate change projections and decrease their range of uncertainty. Speleothems are a precisely datable paleoclimate archive and provide well preserved (semi-)continuous multivariate isotope time series in the lower and mid-latitudes, and are, therefore, well suited to assess climate and isotope variability on decadal and longer timescales. However, the relationship between speleothem oxygen and carbon isotopes to climate variables also depends on site-specific parameters, and their comparison to GCMs is not always straightforward. Here we compare speleothem oxygen and carbon isotopic signatures from the Speleothem Isotopes Synthesis and AnaLysis database version 2 (SISALv2) to the output of five different water-isotope-enabled GCMs (ECHAM5-wiso, GISS-E2-R, iCESM, iHadCM3, and isoGSM) over the last millennium (850–1850 common era, CE). We systematically evaluate differences and commonalities between the standardized model simulation outputs. The goal is to distinguish climatic drivers of variability for both modelled and measured isotopes. We find strong regional differences in the oxygen isotope signatures between models that can partly be attributed to differences in modelled temperatures. At low latitudes, precipitation amount is the dominant driver for water isotope variability, however, at cave locations the agreement between modelled temperature variability is higher than for precipitation variability. While modelled isotopic signatures at cave locations exhibited extreme events coinciding with changes in volcanic and solar forcing, such fingerprints are not apparent in the speleothem isotopes, and may be attributed to the lower temporal resolution of speleothem records compared to the events that are to be detected. Using spectral analysis, we can show that all models underestimate decadal and longer variability compared to speleothems, although to varying extent. We found that no model excels in all analyzed comparisons, although some perform better than the others in either mean or variability. Therefore, we advise a multi-model approach, whenever comparing proxy data to modelled data. Considering karst and cave internal processes through e.g. isotope-enabled karst models may alter the variability in speleothem isotopes and play an important role in determining the most appropriate model. By exploring new ways of analyzing the relationship between the oxygen and carbon isotopes, their variability, and co-variability across timescales, we provide methods that may serve as a baseline for future studies with different models using e.g. different isotopes, different climate archives, or time periods.


2012 ◽  
Vol 86 (5) ◽  
Author(s):  
Antonio Castrillo ◽  
Hemanth Dinesan ◽  
Giovanni Casa ◽  
Gianluca Galzerano ◽  
Paolo Laporta ◽  
...  

2014 ◽  
Vol 7 (9) ◽  
pp. 9095-9135 ◽  
Author(s):  
S. J. Sutanto ◽  
G. Hoffmann ◽  
R. A. Scheepmaker ◽  
J. Worden ◽  
S. Houweling ◽  
...  

Abstract. Over the last-decade, global scale datasets of atmospheric water vapor isotopologues (HDO) have become available from different remote-sensing instruments. Due to the observational geometry and the spectral ranges that are used, only few satellites sample water isotopologues in the lower troposphere, where the bulk of hydrological processes within the atmosphere take place. Here, we compare three satellite HDO datasets, two from the Tropospheric Emission Spectrometer (TES retrieval version 4 and 5) and one from SCIAMACHY (SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY), with results from the atmospheric global circulation model ECHAM4 (European Center HAMburg 4). We examine a list of known isotopologue effects to qualitatively benchmark the various observational datasets. TES version 5 (TESV5), TES version 4 (TESV4), SCIAMACHY, ECHAM, and ECHAM convoluted with averaging kernel of TES version 5 (ECHAMAK5) successfully reproduced a number of established isotopologue effects such as the latitude effect, the amount effect, and the continental effect, but to different extent. The improvement of TES version 5 over version 4 was confirmed by the steeper latitudinal gradient at higher latitudes in agreement with SCIAMACHY. Other features of the water isotopologue cycle such as the seasonally varying signal in the tropics due to the movement of the Inter Tropical Convergence Zone (ICTZ) are captured in TESV5 and SCIAMACHY. We suggest that the qualitative and quantitative tests carried out in this study could become benchmark tests for evaluation of future satellite isotopologue datasets.


2017 ◽  
Author(s):  
Johannes Eckstein ◽  
Roland Ruhnke ◽  
Stephan Pfahl ◽  
Emanuel Christner ◽  
Christoph Dyroff ◽  
...  

Abstract. We present the new isotope enabled model ICON-ART-Iso. The physics of the global ICOsahedral Nonhydrostatic (ICON) modelling framework have been extended to simulate passive moisture tracers and the stable isotopologues HDO and H218O. The extension builds on the infrastructure provided by ICON-ART, which allows a high flexibility with respect to the number of related water tracers that are simulated. The physics of isotopologue fractionation follow the model COSMOiso. First, we present a detailed description of the physics of fractionation that have been implemented in the model. The model is then evaluated by comparing with measurements in precipitation and vapor representing a range of temporal scales. A multi annual simulation is compared to observations of the isotopologues in precipitation taken from the station network GNIP (Global Network for Isotopes in Precipitation). ICON-ART-Iso is able to reasonably simulate the seasonal cycles in δD and δ18O as observed at the GNIP stations. In a comparison with IASI satellite retrievals, the seasonal and daily cycles in the isotopologue content of vapor are examined for different regions in the free troposphere. On a small spatial and temporal scale, ICON-ART-Iso is used to simulate the period of two flights of the IAGOS-CARIBIC aircraft in September 2010, which sampled air in the tropopause level influenced by Hurricane Igor. The general features of this sample as well as all of tropical data available from IAGOS-CARIBIC are captured by the model. The study demonstrates that ICON-ART-Iso is a flexible tool to analyze the water cycle of ICON. It is capable of simulating tagged water as well as the isotopologues HDO and H218O.


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