Pilot-scale treatment of hypersaline coal chemical wastewater with zero liquid discharge

The exponentially multiplying population of the world demands increasing freshwater resources. Thelimited resources comprising less than 3% of the earth’s water resources are getting polluted at an alarming rate. To deal with this situation, seawater reverse osmosis is being carried out at large scales across the globe. The concentrate generated in return is two times more concentrated in terms of total dissolved solids when compared to the feed. The adverse effects of the concentrate stream on the marine ecosystem and further pollution of water cause an immediate need to treat the concentrate. In this review, the harm caused by the direct discharge of concentrate stream has been discussed and therefore volume minimization using treatment methods has been addressed. The treatment methods are mainly classified into four types; membrane-based, thermal-based, electricity-based, and chemical-based methods. Integrated methods, which have been mainly tested on a pilot scale for zero liquid discharge, have also been discussed. The treatment methods that are probable for seawater concentrate treatment falling under the above categories for other concentrate sources have also been attended to. Finally, the disposal methods employed for the discharge of the leftover concentrate have been addressed. Thermal methods are well established but require a lot of energy compared to other methods whereas chemical methods can be economic due to the profit obtained from recovered chemicals, but they are mostly employed for pretreatment. Electricity-based and membrane-based methods are emerging technologies. It was also found that seawater reverse osmosis concentrate is usually discharged directly and therefore integrated methods based on zero liquid discharge are to be implemented. To compensate for the intensive research required for zero liquid discharge to become a reality, innovative and environmentally-friendly disposal methods are available to cut the resultant footprint.

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Approaching zero liquid discharge concept using high-rate integrated pilot-scale bioreactor in the palm oil mill effluent (POME) treatment

10.1016/b978-0-12-823031-2.00003-3 ◽

2021 ◽

pp. 641-667

Author(s):

Cheau Chin Yap ◽

Yi Jing Chan

Keyword(s):

Palm Oil ◽

Pilot Scale ◽

High Rate ◽

Palm Oil Mill Effluent ◽

Liquid Discharge ◽

Palm Oil Mill

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Advances in seawater membrane distillation (SWMD) towards stand-alone zero liquid discharge (ZLD) desalination

Reviews in Chemical Engineering ◽

10.1515/revce-2020-0073 ◽

2021 ◽

Vol 0 (0) ◽

Author(s):

Helen Julian ◽

Novesa Nurgirisia ◽

Putu Doddy Sutrisna ◽

I. Gede Wenten

Keyword(s):

Sea Water ◽

Low Cost ◽

Detailed Comparison ◽

Pilot Scale ◽

Membrane Distillation ◽

Water Recovery ◽

Feed Concentration ◽

Liquid Discharge ◽

Salt Recovery ◽

Push Forward

Abstract Seawater membrane distillation (SWMD) is a promising separation technology due to its ability to operate as a stand-alone desalination unit operation. This paper reviews approaches to improve laboratory-to-pilot-scale MD performance, which comprise operational strategies, module design, and specifically tailored membranes. A detailed comparison of SWMD and sea water reverse osmosis is presented to further analyze the critical shortcomings of SWMD. The unique features of SWMD, namely the ability to operate with extremely high salt rejection and at extreme feed concentration, highlight the SWMD potential to be operated under zero liquid discharge (ZLD) conditions, which results in the production of high-purity water and simultaneous salt recovery, as well as the elimination of the brine disposal cost. However, technical challenges, such as thermal energy requirements, inefficient heat transfer and integration, low water recovery factors, and lack of studies on real-case valuable-salt recovery, are impeding the commercialization of ZLD SWMD. This review highlights the possibility of applying selected strategies to push forward ZLD SWMD commercialization. Suggestions are projected to include intermittent removal of valuable salts, in-depth study on the robustness of novel membranes, module and configuration, utilization of a low-cost heat exchanger, and capital cost reduction in a renewable-energy-integrated SWMD plant.

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Upscaling of foam forming technology for pilot scale

TAPPI Journal ◽

10.32964/tj18.8.461 ◽

2019 ◽

Vol 18 (8) ◽

Cited By ~ 1

Author(s):

JANI LEHMONEN ◽

TIMO RANTANEN ◽

KARITA KINNUNEN-RAUDASKOSKI

Keyword(s):

Production Efficiency ◽

Strength Loss ◽

Pilot Scale ◽

Foam Density ◽

Forming Process ◽

Production Scale ◽

Forming Technology ◽

Wet Pressing ◽

Foam Forming ◽

Board Industry

The need for production cost savings and changes in the global paper and board industry during recent years have been constants. Changes in the global paper and board industry during past years have increased the need for more cost-efficient processes and production technologies. It is known that in paper and board production, foam typically leads to problems in the process rather than improvements in production efficiency. Foam forming technology, where foam is used as a carrier phase and a flowing medium, exploits the properties of dispersive foam. In this study, the possibility of applying foam forming technology to paper applications was investigated using a pilot scale paper forming environment modified for foam forming from conventional water forming. According to the results, the shape of jet-to-wire ratios was the same in both forming methods, but in the case of foam forming, the achieved scale of jet-to-wire ratio and MD/CD-ratio were wider and not behaving sensitively to shear changes in the forming section as a water forming process would. This kind of behavior would be beneficial when upscaling foam technology to the production scale. The dryness results after the forming section indicated the improvement in dewatering, especially when foam density was at the lowest level (i.e., air content was at the highest level). In addition, the dryness results after the pressing section indicated a faster increase in the dryness level as a function of foam density, with all density levels compared to the corresponding water formed sheets. According to the study, the bonding level of water- and foam-laid structures were at the same level when the highest wet pressing value was applied. The results of the study show that the strength loss often associated with foam forming can be compensated for successfully through wet pressing.

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Application of a Pilot-Scale Pulsed Electrocoagulation system to OCC-Based Paper Mill Effluent

TAPPI Journal ◽

10.32964/tj8.3.14 ◽

2009 ◽

Vol 8 (3) ◽

pp. 14-20 ◽

Cited By ~ 2

Author(s):

YUAN-SHING PERNG ◽

EUGENE I-CHEN WANG ◽

SHIH-TSUNG YU ◽

AN-YI CHANG

Keyword(s):

Water Quality ◽

Quality Indicators ◽

Paper Mill ◽

Pilot Scale ◽

Operating Conditions ◽

Optimal Dosage ◽

Water Quality Indicators ◽

Paper Mill Effluent ◽

Treated Effluent ◽

True Color

Trends toward closure of white water recirculation loops in papermaking often lead to a need for system modifications. We conducted a pilot-scale study using pulsed electrocoagulation technology to treat the effluent of an old corrugated containerboard (OCC)-based paper mill in order to evaluate its treatment performance. The operating variables were a current density of 0–240 A/m2, a hydraulic retention time (HRT) of 8–16 min, and a coagulant (anionic polyacrylamide) dosage of 0–22 mg/L. Water quality indicators investigated were electrical con-ductivity, suspended solids (SS), chemical oxygen demand (COD), and true color. The results were encouraging. Under the operating conditions without coagulant addition, the highest removals for conductivity, SS, COD, and true color were 39.8%, 85.7%, 70.5%, and 97.1%, respectively (with an HRT of 16 min). The use of a coagulant enhanced the removal of both conductivity and COD. With an optimal dosage of 20 mg/L and a shortened HRT of 10 min, the highest removal achieved for the four water quality indicators were 37.7%, 88.7%, 74.2%, and 91.7%, respectively. The water qualities thus attained should be adequate to allow reuse of a substantial portion of the treated effluent as process water makeup in papermaking.

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Pilot-scale combustion studies with kraft lignin in a powder burner and a CFB boiler

TAPPI Journal ◽

10.32964/tj9.6.24 ◽

2010 ◽

Vol 9 (6) ◽

pp. 24-30 ◽

Cited By ~ 2

Author(s):

NIKLAS BERGLIN ◽

PER TOMANI ◽

HASSAN SALMAN ◽

SOLVIE HERSTAD SVÄRD ◽

LARS-ERIK ÅMAND

Keyword(s):

Circulating Fluidized Bed ◽

Black Liquor ◽

Chloride Content ◽

Pilot Scale ◽

High Energy ◽

Kraft Lignin ◽

High Energy Density ◽

Alkali Chloride ◽

Cfb Boiler ◽

Solid Biofuel

Processes have been developed to produce a solid biofuel with high energy density and low ash content from kraft lignin precipitated from black liquor. Pilot-scale tests of the lignin biofuel were carried out with a 150 kW powder burner and a 12 MW circulating fluidized bed (CFB) boiler. Lignin powder could be fired in a powder burner with good combustion performance after some trimming of the air flows to reduce swirl. Lignin dried to 10% moisture content was easy to feed smoothly and had less bridging tendencies in the feeding system than did wood/bark powder. In the CFB boiler, lignin was easily handled and cofired together with bark. Although the filter cake was broken into smaller pieces and fines, the combustion was not disturbed. When cofiring lignin with bark, the sulfur emission increased compared with bark firing only, but most of the sulfur was captured by calcium in the bark ash. Conventional sulfur capture also occurred with addition of limestone to the bed. The sulfur content in the lignin had a significantly positive effect on reducing the alkali chloride content in the deposits, thus reducing the high temperature corrosion risk.

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