Development of mass and heat transfer coupled model of hollow fiber membrane for salt recovery from brine via osmotic membrane distillation

Background In this research work, a coupled heat and mass transfer model was developed for salt recovery from concentrated brine water through an osmotic membrane distillation (OMD) process in a hollow fiber membrane contactor (HFMC).The model was built based on the resistance-in-series concept for water transport across the hydrophobic membrane. The model was adopted to incorporate the effects of polarization layers such as temperature and concentration polarization, as well as viscosity changes during concentration. Results The modeling equations were numerically simulated in MATLAB® and were successfully validated with experimental data from literature with a deviation within the range of 1–5%. The model was then applied to study the effects of key process parameters like feed concentrations, osmotic solution concentration, feed, and osmotic solution flow rates and feed temperature on the overall heat and mass transfer coefficient as well as on water transport flux to improve the process efficiency. The mass balance modeling was applied to calculate the membrane area based on the simulated mass transfer coefficient. Finally, a scale-up for the MD process for salt recovery on an industrial scale was proposed. Conclusions This study highlights the effect of key parameters for salt recovery from wastewater using the membrane distillation process. Further, the applicability of the OMD process for salt recovery on large scale was investigated. Sensitivity analysis was performed to identify the key parameters. From the results of this study, it is concluded that the OMD process can be promising in salt recovery from wastewater.

Advances in seawater membrane distillation (SWMD) towards stand-alone zero liquid discharge (ZLD) desalination

Seawater membrane distillation (SWMD) is a promising separation technology due to its ability to operate as a stand-alone desalination unit operation. This paper reviews approaches to improve laboratory-to-pilot-scale MD performance, which comprise operational strategies, module design, and specifically tailored membranes. A detailed comparison of SWMD and sea water reverse osmosis is presented to further analyze the critical shortcomings of SWMD. The unique features of SWMD, namely the ability to operate with extremely high salt rejection and at extreme feed concentration, highlight the SWMD potential to be operated under zero liquid discharge (ZLD) conditions, which results in the production of high-purity water and simultaneous salt recovery, as well as the elimination of the brine disposal cost. However, technical challenges, such as thermal energy requirements, inefficient heat transfer and integration, low water recovery factors, and lack of studies on real-case valuable-salt recovery, are impeding the commercialization of ZLD SWMD. This review highlights the possibility of applying selected strategies to push forward ZLD SWMD commercialization. Suggestions are projected to include intermittent removal of valuable salts, in-depth study on the robustness of novel membranes, module and configuration, utilization of a low-cost heat exchanger, and capital cost reduction in a renewable-energy-integrated SWMD plant.

Brines from industrial water recycling: new ways to resource recovery

Stricter environmental regulation policies and freshwater as an increasingly valuable resource have led to global growth of zero liquid discharge (ZLD) processes in recent years. During this development, in addition to water, the recovery of recyclable materials, e.g. salts, from industrial wastewater and brines is considered more frequently. Within the framework of the HighCon research project, the subject of this study, a new ZLD process with the goal of pure single-salt recovery from industrial wastewater has been developed and investigated in a demonstrational setup at an industrial site. With regard to pure salts recovery, separating organic components is of great importance during the treatment of the concentrate arising from used water recycling. The removal of COD and of ions responsible for scaling worked very well using nanofiltration. The nanofiltration permeate containing the monovalent ions was pre-concentrated using electrodialysis and membrane distillation before selective crystallization for single-salt recovery was performed. An example economic case study for the newly developed ZLD process – based on demonstration results and considering optimization measures for a full-scale design – indicates that the costs are equal to those of a conventional ZLD process, which, however, does not provide inter alia the aforementioned benefit of single-salt recovery.

NUCLEAR ZIRCONIUM – THE BASIS OF ALLOYS WITH IMPROVED NEUTRON-PHYSICAL, RADIATION, AND CORROSION PROPERTIES

The paper provides a review of industrial technologies for the production of nuclear zirconium. Their advantages and disadvantages have been shown, a comparative analysis of the quality of zirconium and hafnium salts has been given. Zirconium with a purity of 99.95%, is on a par with the quality of the iodide metal, with a hafnium content of less than 0.005%, was obtained from zirconium tetrafluoride (TFZ) by electrolysis and method of salt recovery with calcium.