scholarly journals Prediction of N2O Solubility in Alkanolamine Solutions from the Excess Volume Property

2013 ◽  
Vol 37 ◽  
pp. 1744-1750 ◽  
Author(s):  
Ardi Hartono ◽  
Emmanuel O. Mba ◽  
Hallvard F. Svendsen
Keyword(s):  
Excess Volume ◽  
Volume Property

Measurements of the excess volume of benzene-methanol, benzene-acetonitrile and methanol-acetonitrile mixtures by a vibrating-tube densimeter

1979 ◽  
Vol 44 (2) ◽  
pp. 295-306 ◽  
Author(s):  
Ivan Cibulka ◽  
Vladimír Hynek ◽  
Robert Holub ◽  
Jiří Pick
Keyword(s):  
Excess Volume ◽  
Density Measurement ◽  
Indirect Measurement ◽  
Measuring System ◽  
Mean Error ◽  
Shaped Tube ◽  
Underlying Principle ◽  
The Mean ◽  
Vibrating Tube Densimeter

A digital vibrating-tube densimeter was constructed for measuring the density of liquids at several temperatures. The underlying principle of the apparatus is the measurement of the period of eigen-vibrations of a V-shaped tube; the second power of the period of the vibrations is proportional to the density of the liquid in the tube. The temperature of the measuring system is controlled by an electronic regulator. The mean error in the density measurement is approximately ±1 . 10-5 g cm-3 at 25 °C and ±2 . 10-5 g cm-3 at 40 °C. The apparatus was used for an indirect measurement of the excess volume, tested with the benzene-cyclohexane system and further used for determining the excess volume of the benzene-methanol, benzene-acetonitrile and methanol-acetonitrile systems at 25 and 40 °C.

scholarly journals Phase Diagram of Binary Alloy Nanoparticles under High Pressure

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2929
Author(s):  
Han Gyeol Kim ◽  
Joonho Lee ◽  
Guy Makov
Keyword(s):  
Phase Diagram ◽  
Phase Diagrams ◽  
Interaction Parameter ◽  
Excess Volume ◽  
Eutectic Temperature ◽  
Calphad Method ◽  
Alloy Nanoparticles ◽  
Thermodynamic Conditions ◽  
Nanoparticle System ◽  
Pressure Phase

CALPHAD (CALculation of PHAse Diagram) is a useful tool to construct phase diagrams of various materials under different thermodynamic conditions. Researchers have extended the use of the CALPHAD method to nanophase diagrams and pressure phase diagrams. In this study, the phase diagram of an arbitrary A–B nanoparticle system under pressure was investigated. The effects of the interaction parameter and excess volume were investigated with increasing pressure. The eutectic temperature was found to decrease in most cases, except when the interaction parameter in the liquid was zero and that in the solid was positive, while the excess volume parameter of the liquid was positive. Under these conditions, the eutectic temperature increased with increasing pressure.

On the excess volume in polymer blends

Polymer ◽  
1991 ◽  
Vol 32 (3) ◽  
pp. 501-504 ◽  
Author(s):  
Hans-Werner Kammer
Keyword(s):  
Polymer Blends ◽  
Excess Volume

Evaluation of the excess volume and density of liquid Al-Sr alloys

2002 ◽  
Vol 93 (9) ◽  
pp. 904-909 ◽  
Author(s):  
Zhonghua Zhang ◽  
Xiufang Bian ◽  
Yan Wang
Keyword(s):  
Excess Volume

Excess molar volumes and viscosities of binary mixtures of some polyethers with propylamine at 298.15 K

2002 ◽  
Vol 80 (5) ◽  
pp. 467-475 ◽  
Author(s):  
Amalendu Pal ◽  
Rakesh Kumar Bhardwaj
Keyword(s):  
Experimental Data ◽  
Viscous Flow ◽  
Binary Mixtures ◽  
Entire Range ◽  
Excess Volume ◽  
Excess Molar Volumes ◽  
Liquid Mixtures ◽  
Molar Volumes ◽  
Binary Liquid ◽  
Volume Viscosity

Excess molar volumes (VmE) and dynamic viscosities (η) have been measured as a function of composition for binary liquid mixtures of propylamine with 2,5-dioxahexane, 2,5,8-trioxanonane, 2,5,8,11-tetraoxadodecane, 3,6,9-trioxaundecane, and 5,8,11-trioxapentadecane at 298.15 K. The excess volumes are positive over the entire range of composition for the systems propylamine + 2,5-dioxahexane, and + 3,6,9-trioxaundecane, negative for the systems propylamine + 2,5,8,11-tetraoxadodecane, and + 5,8,11-trioxapentadecane, and change sign from positive to negative for the remaining system propylamine + 2,5,8-trioxanonane. From the experimental data, deviations in the viscosity (Δln η) and excess energies of activation for viscous flow (ΔG*E) have been derived. These values are positive for all mixtures with the exception of propylamine + 2,5-dioxahexane.Key words : excess volume, viscosity, binary mixtures.

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