Thermodynamic properties of mixtures of benzene with pyridines 2. Excess volume and excess Gibbs function of benzene + pyridine

1973 ◽  
Vol 5 (4) ◽  
pp. 569-575 ◽  
Author(s):  
P.R. Garrett ◽  
J.M. Pollock ◽  
K.W. Morcom
1986 ◽  
Vol 90 (6) ◽  
pp. 1137-1143 ◽  
Author(s):  
Bernardo Celda ◽  
Agustin Campos ◽  
Juan E. Figueruelo ◽  
Arturo Horta
Keyword(s):  

Ocean Science ◽  
2011 ◽  
Vol 7 (1) ◽  
pp. 1-26 ◽  
Author(s):  
D. G. Wright ◽  
R. Pawlowicz ◽  
T. J. McDougall ◽  
R. Feistel ◽  
G. M. Marion

Abstract. Salinity plays a key role in the determination of the thermodynamic properties of seawater and the new TEOS-101 standard provides a consistent and effective approach to dealing with relationships between salinity and these thermodynamic properties. However, there are a number of practical issues that arise in the application of TEOS-10, both in terms of accuracy and scope, including its use in the reduction of field data and in numerical models. First, in the TEOS-10 formulation for IAPSO Standard Seawater, the Gibbs function takes the Reference Salinity as its salinity argument, denoted SR, which provides a measure of the mass fraction of dissolved material in solution based on the Reference Composition approximation for Standard Seawater. We discuss uncertainties in both the Reference Composition and the Reference-Composition Salinity Scale on which Reference Salinity is reported. The Reference Composition provides a much-needed fixed benchmark but modified reference states will inevitably be required to improve the representation of Standard Seawater for some studies. However, the Reference-Composition Salinity Scale should remain unaltered to provide a stable representation of salinity for use with the TEOS-10 Gibbs function and in climate change detection studies. Second, when composition anomalies are present in seawater, no single salinity variable can fully represent the influence of dissolved material on the thermodynamic properties of seawater. We consider three distinct representations of salinity that have been used in previous studies and discuss the connections and distinctions between them. One of these variables provides the most accurate representation of density possible as well as improvements over Reference Salinity for the determination of other thermodynamic properties. It is referred to as "Density Salinity" and is represented by the symbol SAdens; it stands out as the most appropriate representation of salinity for use in dynamical physical oceanography. The other two salinity variables provide alternative measures of the mass fraction of dissolved material in seawater. "Solution Salinity", denoted SAsoln, is the most obvious extension of Reference Salinity to allow for composition anomalies; it provides a direct estimate of the mass fraction of dissolved material in solution. "Added-Mass Salinity", denoted SAadd, is motivated by a method used to report laboratory experiments; it represents the component of dissolved material added to Standard Seawater in terms of the mass of material before it enters solution. We also discuss a constructed conservative variable referred to as "Preformed Salinity", denoted S∗, which will be useful in process-oriented numerical modelling studies. Finally, a conceptual framework for the incorporation of composition anomalies in numerical models is presented that builds from studies in which composition anomalies are simply ignored up to studies in which the influences of composition anomalies are accounted for using the results of biogeochemical models. 1TEOS-10: international Thermodynamic Equation of Seawater 2010, http://www.teos-10.org/.


2010 ◽  
Vol 7 (4) ◽  
pp. 1559-1625 ◽  
Author(s):  
D. G. Wright ◽  
R. Pawlowicz ◽  
T. J. McDougall ◽  
R. Feistel ◽  
G. M. Marion

Abstract. Salinity plays a key role in the determination of the thermodynamic properties of seawater and the new TEOS-101 standard provides a consistent and effective approach to dealing with relationships between salinity and these thermodynamic properties. However, there are a number of practical issues that arise in the application of TEOS-10, both in terms of accuracy and scope, including its use in the reduction of field data and in numerical models. First, in the TEOS-10 formulation for IAPSO Standard Seawater, the Gibbs function takes the Reference Salinity as its salinity argument, denoted SR, which provides a measure of the mass fraction of dissolved material in solution based on the Reference Composition approximation for Standard Seawater. We discuss uncertainties in both the Reference Composition and the Reference-Composition Salinity Scale on which Reference Salinity is reported. The Reference Composition provides a much-needed fixed benchmark but modified reference states will inevitably be required to improve the representation of Standard Seawater for some studies. The Reference-Composition Salinity Scale should remain unaltered to provide a stable representation of salinity for use with the TEOS-10 Gibbs function and in climate change detection studies. Second, when composition anomalies are present in seawater, no single salinity variable can fully represent the influence of dissolved material on the thermodynamic properties of seawater. We consider three distinct representations of salinity that have been used in previous studies and discuss the connections and distinctions between them. One of these variables provides the most accurate representation of density possible as well as improvements over Reference Salinity for the determination of other thermodynamic properties. It is referred to as "Density Salinity" and is represented by the symbol SAdens; it stands out as the most appropriate representation of salinity for use in dynamical physical oceanography. The other two salinity variables provide alternative measures of the mass fraction of dissolved material in seawater. "Solution Salinity", denoted SAsoln, is the most obvious extension of Reference Salinity to allow for composition anomalies; it provides a direct estimate of the mass fraction of dissolved material in solution. "Added-Mass Salinity", denoted SAadd, is motivated by a method used to report laboratory experiments; it represents the component of dissolved material added to Standard Seawater in terms of the mass of material before it enters solution. We also discuss a constructed conservative variable referred to as "Preformed Salinity", denoted S*, which will be useful in process-oriented numerical modelling studies. Finally, a conceptual framework for the incorporation of composition anomalies in numerical models is presented that builds from studies in which composition anomalies are simply ignored up to studies in which the influences of composition anomalies are accounted for using the results of biogeochemical models. 1TEOS-10: international thermodynamic equation of seawater 2010, http://www.teos-10.org.


1972 ◽  
Vol 27 (1) ◽  
pp. 141-148 ◽  
Author(s):  
J. Richter ◽  
S. Sehm

Abstract EMF measurements were performed on a chemical cell containing a silver and a nitrate electrode. The systems NaNO3 + AgNO3 , LiNO3 + AgNO3, and pure AgNO3 were investigated in a temperature range of 240 °C to 310 °C and in the total concentration range permitted by the phase diagram. We found a linear dependence of the EMF on temperature. Six constants, characteristic for the investigated molten salts depending neither on composition nor on temperature, were determined by the analytical construction of the activity coefficients. Together with the analytically constructed excess molar Gibbs function, the excess molar entropy was calculated from calorimetric data in the literature.


Measurements have been made from which all the thermodynamic properties of fluid helium can be calculated in the temperature range from 3 to 20 °K and up to 100 atm pressure. The quantities measured were: (i) the specific heat at constant volume as a function of temperature and density, (ii) the pressure coefficient at constant volume ( also as a function of temperature and density, (iii) the pressure as a function of temperature at constant volume (isochores) for a range of densities. A particular feature of the experiments is that the important derivative ( )v, from which the changes of entropy and internal energy with volume at constant temperature are calculated, was measured directly by a differential method. Starting from the known entropy and internal energy of the liquid near its normal boiling point, these two quantities were calculated for all single phase states within the experimental range. From these, and using the equation of state data, the enthalpy, free energy, Gibbs function, and the specific heat at constant pressure have been deduced. The thermodynamic functions, together with some useful state properties, are tabulated as functions of temperature and either volume or pressure as relevant. The choice of the measured quantities was such that all the thermodynamic functions except the specific heat at constant pressure were obtained by integration of the experimental data; these functions therefore have the same accuracy as the measured quantities, about 1 %.


1979 ◽  
Vol 44 ◽  
pp. 349-355
Author(s):  
R.W. Milkey

The focus of discussion in Working Group 3 was on the Thermodynamic Properties as determined spectroscopically, including the observational techniques and the theoretical modeling of physical processes responsible for the emission spectrum. Recent advances in observational techniques and theoretical concepts make this discussion particularly timely. It is wise to remember that the determination of thermodynamic parameters is not an end in itself and that these are interesting chiefly for what they can tell us about the energetics and mass transport in prominences.


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