CoP/Co2P hollow spheres embedded in porous N-doped carbon as highly efficient multifunctional electrocatalyst for Zn–air battery driving water splitting device

2021 ◽  
pp. 139643
Author(s):  
Lili Bo ◽  
Wanlu Liu ◽  
Rongrong Liu ◽  
Yusen Hu ◽  
Lumei Pu ◽  
...  
Materials ◽  
2022 ◽  
Vol 15 (2) ◽  
pp. 458
Author(s):  
Tse-Wei Chen ◽  
Ganesan Anushya ◽  
Shen-Ming Chen ◽  
Palraj Kalimuthu ◽  
Vinitha Mariyappan ◽  
...  

Metal-air batteries and fuel cells are considered the most promising highly efficient energy storage systems because they possess long life cycles, high carbon monoxide (CO) tolerance, and low fuel crossover ability. The use of energy storage technology in the transport segment holds great promise for producing green and clean energy with lesser greenhouse gas (GHG) emissions. In recent years, nanoscale based electrocatalysts have shown remarkable electrocatalytic performance towards the construction of sustainable energy-related devices/applications, including fuel cells, metal-air battery and water-splitting processes. This review summarises the recent advancement in the development of nanoscale-based electrocatalysts and their energy-related electrocatalytic applications. Further, we focus on different synthetic approaches employed to fabricate the nanomaterial catalysts and also their size, shape and morphological related electrocatalytic performances. Following this, we discuss the catalytic reaction mechanism of the electrochemical energy generation process, which provides close insight to develop a more efficient catalyst. Moreover, we outline the future perspectives and challenges pertaining to the development of highly efficient nanoscale-based electrocatalysts for green energy storage technology.


2020 ◽  
Vol 4 (3) ◽  
pp. 996-1005 ◽  
Author(s):  
Lifeng Lin ◽  
Min Chen ◽  
Limin Wu

In this work, we report the facile synthesis of NixCuy@C hollow spheres as highly efficient bifunctional electrocatalysts for overall water splitting.


2021 ◽  
Vol 5 (1) ◽  
pp. 375-385
Author(s):  
Lifeng Lin ◽  
Min Chen ◽  
Limin Wu

Herein, we report a facile synthesis of novel hierarchical MoP/NiFeP hybrid hollow spheres (MoP/NiFeP HSs) as an electrocatalyst for the first time.


2021 ◽  
Author(s):  
Lei Gu ◽  
Xuan-Long Sun ◽  
Jiao Zhao ◽  
Bing-Quan Gong ◽  
Zheng-Lv Bao ◽  
...  

Electrocatalysts play an important role in fuel cells, metal-air battery and water-splitting devices. The development of low cost, high activity and high performance bifunctional electrocatalysts for ORR and OER is...


2019 ◽  
Author(s):  
Jiajia Tao ◽  
Hong-Ping Ma ◽  
Kaiping Yuan ◽  
Yang Gu ◽  
Jianwei Lian ◽  
...  

<div>As a promising oxygen evolution reaction semiconductor, TiO2 has been extensively investigated for solar photoelectrochemical water splitting. Here, a highly efficient and stable strategy for rationally preparing GaON cocatalysts on TiO2 by atomic layer deposition is demonstrated, which we show significantly enhances the</div><div>photoelectrochemical performance compared to TiO2-based photoanodes. For TiO2@20 nm-GaON core-shell nanowires a photocurrent density up to 1.10 mA cm-2 (1.23 V vs RHE) under AM 1.5 G irradiation (100 mW cm-2) has been achieved, which is 14 times higher than that of TiO2 NWs. Furthermore, the oxygen vacancy formation on GaON as well as the band gap matching with TiO2 not only provides more active sites for water oxidation but also enhances light absorption to promote interfacial charge separation and migration. Density functional theory studies of model systems of GaON-modified TiO2 confirm the band gap reduction, high reducibility and ability to activate water. The highly efficient and stable systems of TiO2@GaON core-shell nanowires provide a deeper understanding and universal strategy for enhancing photoelectrochemical performance of photoanodes now available. </div>


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