Thermodynamic performance of R502 alternative refrigerant mixtures for low temperature and transport applications

2007 ◽  
Vol 48 (12) ◽  
pp. 3084-3089 ◽  
Author(s):  
Ki-Jung Park ◽  
Dongsoo Jung
Keyword(s):  
Low Temperature ◽  
Alternative Refrigerant ◽  
Refrigerant Mixtures ◽  
Thermodynamic Performance

Performance Investigation of Solar Organic Rankine Cycle Systems With and Without Regeneration and With Zeotropic Working Fluid Mixtures for Use in Micro-Cogeneration

2020 ◽  
Author(s):  
Wahiba Yaïci ◽  
Evgueniy Entchev ◽  
Pouyan Talebizadeh Sardari
Keyword(s):  
Low Temperature ◽  
Heat Source ◽  
High Efficiency ◽  
Organic Rankine Cycle ◽  
Rankine Cycle ◽  
Industrial Wastes ◽  
Working Fluid ◽  
Condensation Temperature ◽  
Thermodynamic Performance ◽  
Cycle Efficiency

Abstract Globally there are several viable sources of renewable, low-temperature heat (below 130°C) particularly solar energy, geothermal energy, and energy generated from industrial wastes. Increased exploitation of these low-temperature options has the definite potential of reducing fossil fuel consumption with its attendant very harmful greenhouse gas emissions. Researchers have universally identified the organic Rankine cycle (ORC) as a practicable and promising system to generate electrical power from renewable sources based on its beneficial use of volatile organic fluids as working fluids (WFs). In recent times, researchers have also shown a preference for/an inclination towards deployment of zeotropic mixtures as ORC WFs because of their capacity to improve thermodynamic performance of ORC systems, a feat enabled by better matches of the temperature profiles of the WF and the heat source/sink. This paper demonstrates both the technical feasibility and the notable advantages of using zeotropic mixtures as WFs through a simulation study of an ORC system. The study examines the thermodynamic performance of ORC systems using zeotropic WF mixtures to generate electricity driven by low-temperature solar heat source for building applications. A thermodynamic model is developed with an ORC system both with and excluding a regenerator. Five zeotropic mixtures with varying compositions of R245fa/propane, R245fa/hexane, R245fa/heptane, pentane/hexane and isopentane/hexane are evaluated and compared to identify the best combinations of WF mixtures that can yield high efficiency in their system cycles. The study also investigates the effects of the volumetric flow ratio, and evaporation and condensation temperature glides on the ORC’s thermodynamic performance. Following a detailed analysis of each mixture, R245fa/propane is selected for parametric study to examine the effects of operating parameters on the system’s efficiency and sustainability index. For zeotropic mixtures, results showed that there is an optimal composition range within which binary mixtures are inclined to perform more efficiently than the component pure fluids. In addition, a significant increase in cycle efficiency can be achieved with a regenerative ORC, with cycle efficiency ranging between 3.1–9.8% and 8.6–17.4% for ORC both without and with regeneration, respectively. Results also showed that exploiting zeotropic mixtures could enlarge the limitation experienced in selecting WFs for low-temperature solar organic Rankine cycles.

scholarly journals Advanced Thermodynamic Analysis of a Transcritical R744 Booster Refrigerating Unit with Dedicated Mechanical Subcooling

Energies ◽  
2018 ◽  
Vol 11 (11) ◽  
pp. 3058 ◽  
Author(s):  
Paride Gullo
Keyword(s):  
Low Temperature ◽  
Thermodynamic Analysis ◽  
Temperature Difference ◽  
Exergy Analysis ◽  
Refrigeration System ◽  
Outdoor Temperature ◽  
Medium Temperature ◽  
High Stage ◽  
Thermodynamic Performance ◽  
Priority Needs

In this work the thermodynamic performance of a transcritical R744 booster supermarket refrigeration system equipped with R290 dedicated mechanical subcooling (DMS) was exhaustively investigated with the aid of the advanced exergy analysis. The outcomes obtained suggested that improvement priority needs to be addressed to the manufacturing of more efficient high-stage (HS) compressors, followed by the enhancement of the gas cooler/condenser (GC), of the medium-temperature (MT) evaporators, of the R290 compressor, and of the low-temperature (LT) evaporators. These conclusions were different from those drawn by the application of the conventional exergy assessment. Additionally, it was found that GC can be enhanced mainly by reducing the irreversibilities owing to the simultaneous interaction among the components. The R290 compressor would also have significantly benefitted from the adoption of such measures, as half of its avoidable irreversibilities were exogenous. Unlike the aforementioned components, all the evaporators were improvable uniquely by decreasing their temperature difference. Finally, the approach temperature of GC and the outdoor temperature were found to have a noteworthy impact on the avoidable irreversibilities of the investigated solution.

Performance Investigation of Solar Organic Rankine Cycle System With Zeotropic Working Fluid Mixtures for Use in Micro-Cogeneration

2021 ◽  
Vol 143 (9) ◽  
Author(s):  
Wahiba Yaïci ◽  
Evgueniy Entchev ◽  
Pouyan Talebizadehsardari ◽  
Michela Longo
Keyword(s):  
Low Temperature ◽  
Power Output ◽  
Organic Rankine Cycle ◽  
Rankine Cycle ◽  
Working Fluid ◽  
Condensation Temperature ◽  
Source Temperature ◽  
Thermodynamic Performance ◽  
Net Power Output ◽  
Cycle Efficiency

Abstract Overall, there are numerous sustainable sources of renewable, low-temperature heat, principally solar energy, geothermal energy, and energy produced from industrial wastes. Extended utilization of these low-temperature alternatives has a certain capacity of decreasing fossil fuel use with its associated very hazardous greenhouse gas emissions. Researchers have commonly recognized the organic Rankine cycle (ORC) as a feasible and suitable system to produce electrical power from renewable sources based on its advantageous use of volatile organic fluids as working fluids (WFs). Researchers have similarly shown an affinity to the exploitation of zeotropic mixtures as ORC WFs due to their capability to enhance the thermodynamic performance of ORC systems, an achievement supported by improved fits of the temperature profiles of the WF and the heat source/sink. This paper determines both the technical feasibility and the benefits of using zeotropic mixtures as WFs by means of a simulation study of an ORC system. This study analyzes the thermodynamic performance of ORC systems using zeotropic WF mixtures to produce electricity driven by low-temperature solar heat sources for use in buildings. A thermodynamic model is created with an ORC system with and without a regenerator. Five zeotropic mixtures with diverse compositions between 0 and 1 in 0.2 increments of R245fa/propane, R245fa/hexane, R245fa/heptane, pentane/hexane, and isopentane/hexane are assessed and compared with identify the best blends of mixtures that are able to produce superior efficiency in their system cycles. Results disclosed that R245fa/propane (0.4/0.6) with regenerator produces the highest net power output of 7.9 kW and cycle efficiency of 9.4% at the operating condition with a hot source temperature of 85 °C. The study also investigates the effects of the volume flow ratio, and evaporation and condensation temperature glide on the ORC’s thermodynamic performance. Following a thorough analysis of each mixture, R245fa/propane is chosen for a parametric study to examine the effects of operating factors on the system’s efficiency and sustainability index. It was found that the highest cycle efficiency and highest second law cycle efficiency of around 10.5% and 84.0%, respectively, were attained with a mass composition of 0.6/0.4 at the hot source temperature of 95 °C and cold source temperature of 20 °C with a net power output of 9.6 kW. Moreover, results revealed that for zeotropic mixtures, there is an optimal composition range within which binary mixtures are tending to work more efficiently than the component pure fluids. In addition, a significant increase in cycle efficiency can be achieved with a regenerative ORC, with cycle efficiency in the range 3.1–9.8% versus 8.6–17.4% for ORC both without and with regeneration, respectively. In conclusion, utilizing zeotropic mixtures may well expand the restriction faced in choosing WFs for solar-powered ORC-based micro-combined heat and power (CHP) systems.

scholarly journals Thermodynamic, Economic and Sustainability Analysis of Solar Organic Rankine Cycle System with Zeotropic Working Fluid Mixtures for Micro-Cogeneration in Buildings

2020 ◽  
Vol 10 (21) ◽  
pp. 7925
Author(s):  
Wahiba Yaïci ◽  
Evgueniy Entchev ◽  
Pouyan Talebizadehsardari ◽  
Michela Longo
Keyword(s):  
Low Temperature ◽  
Heat Source ◽  
Organic Rankine Cycle ◽  
Rankine Cycle ◽  
Optimum Operating ◽  
Working Fluid ◽  
Condensation Temperature ◽  
Fluid Mixtures ◽  
Thermodynamic Performance ◽  
Cycle Efficiency

Globally there are several viable sources of renewable, low-temperature heat (below 130 °C), particularly solar energy, geothermal energy, and energy generated from industrial wastes. Increased exploitation of these low-temperature options has the definite potential of reducing fossil fuel consumption with its attendant very harmful greenhouse gas emissions. Researchers have universally identified the organic Rankine cycle (ORC) as a practicable and suitable system to generate electrical power from renewable sources based on its beneficial usage of volatile organic fluids as working fluids (WFs). In recent times, researchers have also shown a preference towards deployment of zeotropic mixtures as ORC WFs because of their capacity to improve thermodynamic performance of ORC systems, a feat enabled through the greater matching of the temperature profiles of the WF and the heat source/sink. This paper demonstrates the thermodynamic, economic and sustainability feasibility, and the notable advantages of using zeotropic mixtures as WFs through a simulation study of an ORC system. The study examines first the thermodynamic performance of ORC systems using zeotropic mixtures to generate electricity powered by a low-temperature solar heat source for building applications. A thermodynamic model is developed with a solar-driven ORC system both with and excluding a regenerator. Twelve zeotropic mixtures with varying compositions are evaluated and compared to identify the best combinations of mixtures that can yield high performance and high efficiency in their system cycles. The study also examines the effects of the volume flow ratio, and evaporation and condensation temperature glides on the ORC’s thermodynamic performance. Following a detailed analysis of each mixture, R245fa/propane and butane/propane are selected for parametric study to investigate the influence of operating parameters on the system’s efficiency and sustainability index. For zeotropic mixtures, results disclosed that there is an optimal composition range within which binary mixtures are inclined to perform more efficiently than the component pure fluids. In addition, a substantial enhancement in cycle efficiency can be obtained by a regenerative ORC, with cycle efficiency ranging between 3.1–9.8% and 8.6–17.4% for ORC both without and with regeneration, respectively. Results also revealed that exploiting zeotropic mixtures could enlarge the limitation experienced in selecting WFs for low-temperature solar ORCs. Moreover, a detailed economic with a sensitivity analysis of the solar ORC system was performed to evaluate the cost of the electricity and other economic criteria. The outcome of this investigation should be useful in the thermo-economic feasibility assessments of solar-driven ORC systems using working fluid mixtures to find the optimum operating range for maximum performance and minimum cost.

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