Investigation of the Thermodynamic Characteristics of the Ester Oil and R152a, R125, R134a and R123 Refrigerant Mixtures

The presence of the lubricant POE 68 in the refrigeration system changes the thermophysical properties of the refrigerant, which significantly affects the heat transfer and the hydraulic processes. The purpose of this research is to investigate the thermodynamic properties of the R152a, R125, R134a and R123 refrigerant and POE 68 lubricant mixtures at different temperatures from 233,15 to 313,15 K. There have been investigated the values of the densities and kinematic viscosities of the mixtures at different concentrations (100%, 90%, 80%). Finally, it was found that, the density and kinematic viscosity of the R123/POE 68 mixture were most affected by the change of the concentration.

Temperature-entropy diagrams for calculating cycles of refrigerating machines using refrigerant mixtures

The article represents the advantages and disadvantages of refrigeration machines operating on non-azeotropic refrigerant mixtures. There has been illustrated their specific feature in comparison with pure substances: they are non-isothermal during phase transitions. It can be effective when cooling or heating flows that significantly change the temperature, and ineffective when working with volumes, where it is necessary to maintain a constant temperature. In the first case there takes place a decrease in the internal irreversibility of heat transfer processes in evaporators and condensers; in the second case - an increase. When using mixed refrigerants, it is possible to simultaneously obtain several temperature levels in a single-stage machine at the same pressure in the evaporators, they can obtain low boiling points of the refrigerant without vacuum in the evaporator and regulate the refrigeration capacity of the machine by changing the composition of the mixture. The prospects of using mixtures of working bodies of refrigerating machines have been proved. The diagrams T-S, T-ξ, i-ξ are presented allowing to calculate the cycle of the machine, to determine its operating parameters and to calculate the technical and energy characteristics. The developed thermal diagrams make it possible to accurately examine the dynamics of the boiling and condensation processes of a binary mixture, show the change in the concentration of the mixture in the vapor and liquid phases and make it possible to construct and calculate the cycle of a refrigeration machine operating on a mixed refrigerant. Examples of constructing cycles of two schemes of refrigeration machines operating on a mixed refrigerant are considered: with separation of the working substance flow and without separation. Methods for calculating the cycle are provided