In this study, CASSs which were thermally aged at 275–400°C for up to 30000 hrs were investigated using atom probe tomography, Charpy impact test, hardness test, and fracture toughness test in order to evaluate the effects of chemical composition and ferrite content on thermal aging embrittlement. Test materials were 4 types of statically casted grade CF3M stainless steels which are used in Japanese BWR plants. As a result of the tests, Charpy absorbed energy at room temperature of all thermal aging conditions were obtained. We also obtained the microstructural evolution in ferrite phase, hardness of ferrite phase, and J–R curves of several aging conditions. The fracture toughness and the Charpy absorbed energy of all materials aged at 275°C for up to 15000 hrs were approximately same as those of unaged materials. On the other hand, reduction of the fracture toughness and the Charpy absorbed energy were observed in the materials aged at 300°C, 320°C, 350°C and 400°C. For the Charpy impact test in this study, the absorbed energy of the material with highest molybdenum was lower than that of the material with highest ferrite content. After the tests, the fracture toughness estimation model for grade CF8M in NUREG/CR-4513 and the method in PVP2005-71528 (H3T model) were discussed in order to confirm the applicability of the prediction methods to CF3M.