Inspiration from a new lignin-derived phthalonitrile resin: Unique curing behavior, and thermal properties

2019 ◽  
Vol 121 ◽  
pp. 109351 ◽  
Author(s):  
Yang Liu ◽  
Zheng-zhou Liu ◽  
Wei-feng Peng ◽  
Zheng Lu ◽  
Jiang-huai Hu ◽  
...  
RSC Advances ◽  
2017 ◽  
Vol 7 (69) ◽  
pp. 43978-43986 ◽  
Author(s):  
Jianghuai Hu ◽  
Rui Sun ◽  
Yihao Wu ◽  
Jiangbo Lv ◽  
Zhiping Wang ◽  
...  

A novel self-promoted benzimidazole-containing phthalonitrile/E51 binary blends system with unique curing behaviors and outstanding thermal properties.


2014 ◽  
Vol 575 ◽  
pp. 21-28 ◽  
Author(s):  
Muhammad F. Mustafa ◽  
Wayne D. Cook ◽  
Tara L. Schiller ◽  
Humaira M. Siddiqi

2010 ◽  
Vol 46 (5) ◽  
pp. 1024-1031 ◽  
Author(s):  
Jun Wang ◽  
Ming-qing Wu ◽  
Wen-bin Liu ◽  
Shi-wei Yang ◽  
Jian-wei Bai ◽  
...  

2020 ◽  
Vol 44 (43) ◽  
pp. 18917-18928
Author(s):  
Ting Wang ◽  
Zhi-cheng Wang ◽  
Zhong-cheng Pan ◽  
Abdul Qadeer Dayo ◽  
Wen-bin Liu ◽  
...  

Poly(t-BF-sa-a) showed much better thermal properties and glass transition temperatures than traditional fluorene-based benzoxazine monomers.


2017 ◽  
Vol 144 ◽  
pp. 114-124 ◽  
Author(s):  
Abdul Qadeer Dayo ◽  
Bao-chang Gao ◽  
Jun Wang ◽  
Wen-bin Liu ◽  
Mehdi Derradji ◽  
...  

Polymers ◽  
2019 ◽  
Vol 11 (10) ◽  
pp. 1545 ◽  
Author(s):  
Tossapol Boonlert-uthai ◽  
Chavakorn Samthong ◽  
Anongnat Somwangthanaroj

The hyperbranched epoxy resins (HBE) composed of bisphenol A (BPA) and polyethylene glycol (PEG) as reactants and pentaerythritol as branching point were successfully synthesized via A2 + B4 polycondensation reaction at various BPA/PEG ratios. The 13C NMR spectra revealed that the synthesized HBE mainly had a dendritic structure as confirmed by the high degree of branching (DB). The addition of PEG in the resin enhanced degree of branching (DB) (from 0.82 to 0.90), epoxy equivalent weight (EEW) (from 697 g eq−1 to 468 g eq−1) as well as curing reaction. Adding 5–10 wt.% PEG in the resin decreased the onset and peak curing temperatures and glass transition temperature; however, adding 15 wt.% PEG in the resin have increased these thermal properties due to the lowest EEW. The curing kinetics were evaluated by fitting the experimental data of the curing behavior of all resins with the Šesták–Berggren equation. The activation energy increased with the increase of PEG in the resins due to HBE’s steric hindrance, whereas the activation energy of HBE15P decreased due to a large amount of equivalent active epoxy group per mass sample. The curing behavior and thermal properties of obtained hyperbranched BPA/PEG epoxy resin would be suitable for using in electronics application.


2012 ◽  
Vol 49 (1) ◽  
pp. 81-84 ◽  
Author(s):  
Songqi Ma ◽  
Weiqu Liu ◽  
Yuan Zhao ◽  
Zhenlong Yan ◽  
Nan Gao

2011 ◽  
Vol 228-229 ◽  
pp. 83-87
Author(s):  
Zeng Ping Zhang ◽  
Shuan Fa Chen ◽  
Jian Zhong Pei

A kind of nonfunctional silsesquioxane (SSQ), methylsilsesquioxane (Me-SSQ), was used to modify cyanate ester resin (CE) in this paper. First, methylsilsesquioxane (Me-SSQ) was synthesized by the hydrolysis and condensation of methyltriethoxysilane. Then a series of Me-SSQ/CE hybrids containing 0wt%, 1wt%, 5wt%, 10wt% and 20wt% of Me-SSQ were prepared. The effect of Me-SSQ content on the curing behavior and thermal properties of materials was investigated by using Fourier transforms infrared (FT-IR) spectroscopy and thermogravimetry (TG), respectively. FT-IR results indicate that the addition of Me-SSQ does not show significant effect on the conversion of CE. However, TG data show that Me-SSQ improved the thermal properties of CE greatly.


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