A new class of high-performance thermoset resins using dicyanoimidazole (DCI) as crosslinking group: A key demo of synthesis, curing behavior and thermal properties

Polymer ◽  
2021 ◽  
pp. 124264
Author(s):  
Zhengzhu Zhu ◽  
Xian He ◽  
Wei Tan ◽  
Jinlang Hong ◽  
Shenjun Liao ◽  
...  
2021 ◽  
pp. 095400832110130
Author(s):  
Hailong Li ◽  
Sipei Zhao ◽  
Li Pei ◽  
Zihe Qiao ◽  
Ding Han ◽  
...  

Polybenzoxazines are emerging as a class of high-performance thermoset polymers that can find their applications in various fields. However, its practical application is limited by its low toughness. The cyclic β-cyclodextrin and a newly synthesized derivative (β-cyclodextrin-MAH) were separately blended with benzoxazine to improve the toughness of polybenzoxazine. The results revealed that the maximum impact strength of the blend was 12.24 kJ·m−2 and 14.29 kJ·m−2 when 1 wt.% of β-Cyclodextrin and β-Cyclodextrin-MAH, respectively, were used. The strengths were 53% and 86% higher than that of pure polybenzoxazine. The curing reaction, possible chemical structures, and fractured surface were examined using differential scanning calorimetry, Fourier transform infrared spectroscopy, and scanning electron microscopy techniques to understand the mechanism of generation of toughness. The results revealed that the sea-island structure and the presence of hydrogen bonds between polybenzoxazine and β-cyclodextrin and β-cyclodextrin-MAH resulted in the generation of toughness. Furthermore, the curves generated during thermogravimetric analysis did not significantly change, revealing the good thermal properties of the system. The phase-separated structure and the hydrogen bonds present in the system can be exploited to prepare synergistically tough polybenzoxazine exhibiting excellent thermal properties. This can be a potential way of modifying the thermoset resins.


2014 ◽  
Vol 887-888 ◽  
pp. 49-52 ◽  
Author(s):  
Noureddine Ramdani ◽  
Jun Wang ◽  
Wen Bin Liu

In this work, typical polybenzoxazine, as new class of phenolic resin, has been used as a matrix for preparing a series of high performance hybrid materials using various amounts of titanium carbide (TiC) ranging between 0-10 wt% as fillers, via a solution blending technique. The thermal properties of bisphenol A-aniline base benzoxazine monomers (BA-a) and TiC mixtures have been studied by differential scanning calorimetry (DSC). The thermal stability of their cured hybrids has been tested by means of thermogravimetric analysis (TGA). The result showed that the glass transition temperature of the prepared composites increased with increasing the amount of TiC to reach a higher value at 194°C. Also, the incorporation of TiC nanoparticles has considerably improved the thermal stability of the hybrids including the char yield which increase by 50 % at 10 wt% TiC content.


2021 ◽  
Vol 35 ◽  
pp. 102249
Author(s):  
S. Thakur ◽  
S. Maiti ◽  
K. Sardar ◽  
N. Besra ◽  
P. Bairi ◽  
...  

Genetics ◽  
2003 ◽  
Vol 165 (4) ◽  
pp. 2269-2282
Author(s):  
D Mester ◽  
Y Ronin ◽  
D Minkov ◽  
E Nevo ◽  
A Korol

Abstract This article is devoted to the problem of ordering in linkage groups with many dozens or even hundreds of markers. The ordering problem belongs to the field of discrete optimization on a set of all possible orders, amounting to n!/2 for n loci; hence it is considered an NP-hard problem. Several authors attempted to employ the methods developed in the well-known traveling salesman problem (TSP) for multilocus ordering, using the assumption that for a set of linked loci the true order will be the one that minimizes the total length of the linkage group. A novel, fast, and reliable algorithm developed for the TSP and based on evolution-strategy discrete optimization was applied in this study for multilocus ordering on the basis of pairwise recombination frequencies. The quality of derived maps under various complications (dominant vs. codominant markers, marker misclassification, negative and positive interference, and missing data) was analyzed using simulated data with ∼50-400 markers. High performance of the employed algorithm allows systematic treatment of the problem of verification of the obtained multilocus orders on the basis of computing-intensive bootstrap and/or jackknife approaches for detecting and removing questionable marker scores, thereby stabilizing the resulting maps. Parallel calculation technology can easily be adopted for further acceleration of the proposed algorithm. Real data analysis (on maize chromosome 1 with 230 markers) is provided to illustrate the proposed methodology.


Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2400
Author(s):  
Leandra P. Santos ◽  
Douglas S. da Silva ◽  
Thais H. Morari ◽  
Fernando Galembeck

Many materials and additives perform well as fire retardants and suppressants, but there is an ever-growing list of unfulfilled demands requiring new developments. This work explores the outstanding dispersant and adhesive performances of cellulose to create a new effective fire-retardant: exfoliated and reassembled graphite (ERG). This is a new 2D polyfunctional material formed by drying aqueous dispersions of graphite and cellulose on wood, canvas, and other lignocellulosic materials, thus producing adherent layers that reduce the damage caused by a flame to the substrates. Visual observation, thermal images and surface temperature measurements reveal fast heat transfer away from the flamed spots, suppressing flare formation. Pinewood coated with ERG underwent standard flame resistance tests in an accredited laboratory, reaching the highest possible class for combustible substrates. The fire-retardant performance of ERG derives from its thermal stability in air and from its ability to transfer heat to the environment, by conduction and radiation. This new material may thus lead a new class of flame-retardant coatings based on a hitherto unexplored mechanism for fire retardation and showing several technical advantages: the precursor dispersions are water-based, the raw materials used are commodities, and the production process can be performed on commonly used equipment with minimal waste.


Metabolites ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 412
Author(s):  
Martin Malý ◽  
Martin Hajšl ◽  
Kamila Bechyňská ◽  
Ondřej Kučerka ◽  
Martin Šrámek ◽  
...  

Alterations in lipid metabolism mediated by oxidative stress play a key role in the process of atherosclerosis and superimposed thrombosis; these can lead to acute coronary syndrome (ACS) and acute ischemic stroke (AIS). Multiple studies have shown that the formation of atheromatous lesions is initiated by oxidation of low-density lipoproteins incorporated into the intima of the vessel wall. Here, we studied lipids in plasma samples from three cohorts: 61 patients with ACS (group A), 49 patients with AIS (group D), and 82 controls (group K). Untargeted lipidomics based on high-performance liquid chromatography coupled to mass spectrometry (UHPLC-HRMS) was employed to obtain comprehensive information on whether relationships exist between these patient categories based on lipid patterns. In addition, malondialdehyde (MDA) as a standard marker of oxidative stress was monitored. The most characteristic lipids in group K were fatty acyls of hydroxyfatty acids (FAHFAs). As expected, MDA concentrations were the lowest in group K. Our findings can better explain ongoing pathologies, both acute and chronic, with the potential for future diagnosis and treatment.


Nanoscale ◽  
2013 ◽  
Vol 5 (17) ◽  
pp. 7906 ◽  
Author(s):  
Qin-qin Xiong ◽  
Jiang-ping Tu ◽  
Xin-hui Xia ◽  
Xu-yang Zhao ◽  
Chang-dong Gu ◽  
...  

2021 ◽  
Vol 28 (2) ◽  
pp. 54-72
Author(s):  
Abd-al-Salam Al-Hazragi ◽  
Assim Lateef

This article investigates the behaviour of strengthened concrete columns using jacketing ultra-high-performance fiber reinforced concrete (UHPFRC) and carbon fiber-reinforced polymer (CFRP) under uniaxial loaded. The jacket was connected to the column core using shear connectors and (CFRP) fixed as a strip on the tension zone between the column cores and the jacketing. Seven column samples of square cross-section (120 x120) mm at the midsection with overall length of 1250 mm were cast using normal strength concrete (NSC) and having similar longitudinal and transverse reinforcement. The samples were made and tested under axial load at eccentricity equal to 120 mm up to failure. Test parameters were the thickness of jackets (25 and 35) mm and the width of CFRP (0,8, and 12) cm. Column specimens were tested, one of them was reference without any strengthening, and the other specimens divided into two groups (A, and B), and each group included three specimens based on the parameters. Group (A) has UHPFRC jacket thickness 25 mm and CFRP width (0,8, and 12) cm respectively, and group (B) has UHPFRC jacket thickness 35 mm and CFRP width (0,8, and 12) cm respectively. The outcomes of the article show that increasing the thickness of jacket, and width of CFRP lead to increase in the load carrying capacity about (110.5%,168.4%, and 184.2%) for group A, and (157.9%,226.3%, and 263.2%) for group B compared with the reference column due to delay in the appearance of cracks and their distribution. The mid-height lateral displacement of columns was decreased about (66.6%,42.3%, and 35.9%) for group A, and (46.15%,38.46%, and 32.3%) for group B, also the axial deformation of specimens decreased about (71.7%,60.86%, and 55.86%) for group A, and (65.5%,60.5%, and 53.4) for group B compared with the reference column. The ductility of columns that were strengthened with UHPFRC jacket only was increased about (13.67%,19.66%) for thickness(25,35) mm respectively, because of that UHPFRC jacket was contented on steel fibers, and the percentage decrease of ductility was about (5.1%,and 12%) for group (A), (1%,and 9.4%) for group (B) when bonded CFRP in the tension zone with width (8 ,and 12) cm respectively. The results show improvement in the initial and secant stiffness when, increased the thickness of jacket, and width of CFRP because of increase in the size of columns and improvement in the modulus of elasticity. The toughness increase was about (273.97%,301.55%, and 304.5%) for group A, and (453.69%,511.93%, and 524.28%) for group B compared with the reference column because of increase in the size of specimens and delay the appearance of cracks.


RSC Advances ◽  
2017 ◽  
Vol 7 (69) ◽  
pp. 43978-43986 ◽  
Author(s):  
Jianghuai Hu ◽  
Rui Sun ◽  
Yihao Wu ◽  
Jiangbo Lv ◽  
Zhiping Wang ◽  
...  

A novel self-promoted benzimidazole-containing phthalonitrile/E51 binary blends system with unique curing behaviors and outstanding thermal properties.


1988 ◽  
Vol 134 ◽  
Author(s):  
W. J. Welsh ◽  
J. E. Mark ◽  
Y. Yang ◽  
G. P. Das

ABSTRACTThis review focuses on a new type of para-catenated aromatic polymer being used in the preparation of high-performance films and fibers of exceptional strength, thermal stability, and environmental resistance, including inertness to essentially all common solvents. Polymers of this type include the cis- and trans-poly(p-phenylene benzobisoxazole) (PBO), the cis- and trans-forms of the corresponding poly(pphenylene benzobisthiazole) (PBT), and the structurally similar poly(5,5ʹ-bibenzoxazole-2.2ʹ-diyl-l,3-phenylene) (AAPBO) and poly(2,5-benzoxazole) (ABPBO) and their sulfurcontaining analogues. Because of their rigidity, these polymers become highly oriented in solution and some display liquid crystalline behavior. The purpose of this paper is to summarize the authorsʹ theoretical work on the structures, conformational energies, intermolecular interactions, electronic properties, electrical conductivity, and electrooptical properties of these chains, including, in some cases, the so-called articulated forms and the protonated forms known to exist in strong acids. The emphasis is on how such studies provide a molecular understanding of the unusual properties and processing characteristics of this new class of materials.


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