Estimation of critical point, vapor pressure and heat of sublimation of pharmaceuticals and their solubility in supercritical carbon dioxide

2019 ◽  
Vol 488 ◽  
pp. 1-8 ◽  
Author(s):  
Samira Amini Jahromi ◽  
Aliakbar Roosta
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Vapor Pressure ◽  
Critical Point ◽  
Supercritical Carbon

Numerical Simulation of the Performance of an Axial Compressor Operating With Supercritical Carbon Dioxide

2018 ◽  
Author(s):  
Jinlan Gou ◽  
Wei Wang ◽  
Can Ma ◽  
Yong Li ◽  
Yuansheng Lin ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Numerical Simulation ◽  
Supercritical Carbon Dioxide ◽  
Critical Point ◽  
Mass Flow Rate ◽  
Mass Flow ◽  
Flow Rate ◽  
Axial Compressor ◽  
Brayton Cycle ◽  
Supercritical Carbon

Using supercritical carbon dioxide (SCO2) as the working fluid of a closed Brayton cycle gas turbine is widely recognized nowadays, because of its compact layout and high efficiency for modest turbine inlet temperature. It is an attractive option for geothermal, nuclear and solar energy conversion. Compressor is one of the key components for the supercritical carbon dioxide Brayton cycle. With established or developing small power supercritical carbon dioxide test loop, centrifugal compressor with small mass flow rate is mainly investigated and manufactured in the literature; however, nuclear energy conversion contains more power, and axial compressor is preferred to provide SCO2 compression with larger mass flow rate which is less studied in the literature. The performance of the axial supercritical carbon dioxide compressor is investigated in the current work. An axial supercritical carbon dioxide compressor with mass flow rate of 1000kg/s is designed. The thermodynamic region of the carbon dioxide is slightly above the vapor-liquid critical point with inlet total temperature 310K and total pressure 9MPa. Numerical simulation is then conducted to assess this axial compressor with look-up table adopted to handle the nonlinear variation property of supercritical carbon dioxide near the critical point. The results show that the performance of the design point of the designed axial compressor matches the primary target. Small corner separation occurs near the hub, and the flow motion of the tip leakage fluid is similar with the well-studied air compressor. Violent property variation near the critical point creates troubles for convergence near the stall condition, and the stall mechanism predictions are more difficult for the axial supercritical carbon dioxide compressor.

Visualization of Supercritical Carbon Dioxide Flow Through a Converging-Diverging Nozzle

2019 ◽  
Author(s):  
Chang Hyeon Lim ◽  
Gokul Pathikonda ◽  
Sandeep Pidaparti ◽  
Devesh Ranjan
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Critical Point ◽  
High Speed ◽  
Operating Conditions ◽  
Higher Plant ◽  
Two Phase ◽  
Pressure Profiles ◽  
Flow Through ◽  
Supercritical Carbon

Abstract Supercritical carbon dioxide (sCO2) power cycles have the potential to offer a higher plant efficiency than the traditional Rankine superheated/supercritical steam cycle or Helium Brayton cycles. The most attractive characteristic of sCO2 is that the fluid density is high near the critical point, allowing compressors to consume less power than conventional gas Brayton cycles and maintain a smaller turbomachinery size. Despite these advantages, there still exist unsolved challenges in design and operation of sCO2 compressors near the critical point. Drastic changes in fluid properties near the critical point and the high compressibility of the fluid pose several challenges. Operating a sCO2 compressor near the critical point has potential to produce two phase flow, which can be detrimental to turbomachinery performance. To mimic the expanding regions of compressor blades, flow through a converging-diverging nozzle is investigated. Pressure profiles along the nozzle are recorded and presented for operating conditions near the critical point. Using high speed shadowgraph images, onset and growth of condensation is captured along the nozzle. Pressure profiles were calculated using a one-dimensional homogeneous equilibrium model and compared with experimental data.

scholarly journals Characterization of Non-Equilibrium Condensation of Supercritical Carbon Dioxide in a de Laval Nozzle

2017 ◽  
Author(s):  
Claudio Lettieri ◽  
Derek Paxson ◽  
Zoltan Spakovszky ◽  
Peter Bryanston-Cross
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Critical Point ◽  
Laval Nozzle ◽  
Experimental Measurements ◽  
Fluid Properties ◽  
Inlet Conditions ◽  
Direct Extrapolation ◽  
Supercritical Carbon

On a ten-year timescale, Carbon Capture and Storage could significantly reduce carbon dioxide (CO2) emissions. One of the major limitations of this technology is the energy penalty for the compression of CO2 to supercritical conditions, which can require up to 15% of the plant’s gross power output. To reduce the power requirements supercritical carbon dioxide compressors must operate at reduced temperatures and near saturation where phase change effects are important. Non-equilibrium condensation can occur in the high-speed flow at the leading edge of the compressor, causing performance and stability issues. The characterization of the fluid at these conditions is vital to enable advanced compressor designs at enhanced efficiency levels but the analysis is challenging due to the lack of data on the metastable fluid properties. In this paper we assess the metastable behavior and nucleation characteristics of high-pressure subcooled carbon dioxide during the expansion in a Laval nozzle. The assessment is conducted with numerical calculations, supported and corroborated by experimental measurements. The Wilson line is determined via optical measurements in the range of 41 and 82 bar and near the critical point. The state of the metastable fluid is fully characterized through pressure and density measurements, with the latter obtained in a first of its kind laser interferometry set up. In a systematic analysis the inlet conditions of the nozzle are moved close to the critical point to allow for large gradients in fluid properties and reduced margin to condensation. The results of calculations using a direct extrapolation of the Span and Wagner equation of state model are compared with the experimental measurements. The analysis suggests that the direct extrapolation using the Span and Wagner model yields results within 2% of the experimental data, with improved accuracy at conditions away from the critical point. The results are applied in a pre-production supercritical carbon dioxide compressor and are used to define inlet conditions at reduced temperature but free of condensation. Full-scale compressor experiments demonstrate that the new inlet conditions can reduce the shaft power input by 16%.

Design and Real Fluid Modelling of Micro-Channel Recuperators for a Nominal 100 MW Class Recuperated Recompression Brayton Cycle Using Supercritical Carbon Dioxide

2015 ◽  
Author(s):  
Joshua Schmitt ◽  
David Amos ◽  
Jayanta Kapat
Keyword(s):  
Heat Transfer ◽  
Carbon Dioxide ◽  
Heat Exchanger ◽  
Supercritical Carbon Dioxide ◽  
Critical Point ◽  
Working Fluid ◽  
Brayton Cycle ◽  
Micro Channel ◽  
One Dimensional ◽  
Supercritical Carbon

The goal of this study is to design and assess the effectiveness of a micro-channel recuperator using supercritical carbon dioxide as a working fluid. A one-dimensional thermal analysis is performed for a micro-channel recuperator suitable for a Brayton cycle with a nominal 100 MW class turbomachine. The impact of supercritical carbon dioxide properties near the critical point on the thermal performance of the recuperator is studied in detail. The cycle parameters are first obtained from an overall cycle analysis. Two adjacent flow passages with square cross-section in counter-flow configuration are considered for this analysis along with appropriate symmetry. The high pressure of SCO2 is also addressed and the structural stresses on the micro-channel walls are analyzed. Only the axial temperature variations in the hot stream and the cold stream are considered in the one-dimensional analysis. Each channel is discretized in the axial direction. Axial conduction through the wall is included in the energy balance. Of particular interest in this analysis is the variation of transport properties of the CO2 working fluid as thermodynamic conditions approach the critical point. These property variations are provided to the computer code through the REFPROP database. Over the length of the heat exchanger local changes in Reynolds number, Nusselt number, and heat transfer coefficient are charted. From the results of the heat transfer calculations, the log mean temperature difference and heat exchange effectiveness of the heat exchanger is calculated. Using the code to produce multiple results, the optimum heat exchanger design is found. Recommendations on the manufacturing method of a micro-channel recuperator are made.

Comparison of Compressor Performance Map Predictions to Test Data for a Supercritical Carbon Dioxide Brayton Power System

2021 ◽  
Author(s):  
Eric Clementoni
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Critical Point ◽  
Power Cycles ◽  
Real Gas ◽  
Performance Map ◽  
Compressor Inlet ◽  
Compressor Performance ◽  
Inlet Conditions ◽  
Supercritical Carbon

Abstract Supercritical carbon dioxide (sCO2) Brayton power cycles are typically designed to operate with compressor inlet conditions near the critical point to take advantage of the high density of the fluid at these conditions. While designing the cycle to operate here improves cycle efficiency, it also creates challenges for designing the compressor and predicting off-design compressor performance due to real gas fluid properties near the critical point. Multiple compressor performance map evaluation methodologies which incorporate real gas corrections have been proposed in literature with only limited evaluation of the accuracy of these methods compared to operational data from compressors designed for sCO2 power cycles. This paper evaluates compressor performance from the 100 kWe Integrated System Test (IST), which was operated at the Naval Nuclear Laboratory, over a range of compressor inlet conditions and rotational speeds relative to one real gas performance map correction methodology and assesses the impact of additional terms proposed in literature for improving the accuracy of off-design performance predictions.

Effect of Experimental Method on the Heat Transfer Performance of Supercritical Carbon Dioxide in Microchannel

2017 ◽  
Vol 139 (11) ◽  
Author(s):  
Chien-Yuh Yang ◽  
Kun-Chieh Liao
Keyword(s):  
Heat Transfer ◽  
Carbon Dioxide ◽  
Pressure Drop ◽  
Supercritical Carbon Dioxide ◽  
Critical Point ◽  
Test Section ◽  
Heat Transfer Performance ◽  
Test Results ◽  
Test Conditions ◽  
Supercritical Carbon

This paper provides an experimental investigation of heat transfer and pressure drop of supercritical carbon dioxide cooling in a microchannel heat exchanger. An extruded flat aluminum tube with 37 parallel channels and each channel of 0.5 mm × 0.5 mm cross section was used as the test section. The temperature drops of supercritical CO2 cooled inside the test section were controlled at 2 °C, 4 °C, and 8 °C separately for each test to investigate the effect of property change on the friction and heat transfer performance at various temperature cooling ranges near the critical point. The test results showed that while the test conditions were away from the critical point, both heat transfer and pressure drop performance agreed very well with those predicted by conventional correlations. However, for the test conditions near the critical point, the difference between those of the test results and the predicted values is very high. Both heat transfer and pressure drop were strongly affected by the ranges of temperature cooling in the test section while they were near the critical conditions. Since there is a drastic peak of the property change near the critical point, if we use the properties integrated but not averaged from inlet to the exit temperatures, we obtain the results that agree well with the values predicted by conventional correlations. The heat transfer and pressure drop performance of supercritical carbon dioxide in microchannels with size near 0.5 mm are indeed similar to these at normal conditions if its properties are appropriately evaluated.

Effect of Mixtures on Compressor and Cooler in Supercritical Carbon Dioxide Cycles

2018 ◽  
Author(s):  
Ladislav Vesely ◽  
K. R. V. Manikantachari ◽  
Subith Vasu ◽  
Jayanta Kapat ◽  
Vaclav Dostal ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Critical Point ◽  
Carbon Capture ◽  
Power Plants ◽  
High Efficiency ◽  
Waste Heat ◽  
Operating Conditions ◽  
Working Fluid ◽  
Supercritical Carbon

With the increasing demand for electric power, the development of new power generation technologies is gaining increased attention. The supercritical carbon dioxide (S-CO2) cycle is one such technology, which has relatively high efficiency, compactness, and potentially could provide complete carbon capture. The S-CO2 cycle technology is adaptable for almost all of the existing heat sources such as solar, geothermal, fossil, nuclear power plants, and waste heat recovery systems. However, it is known that, optimal combinations of: operating conditions, equipment, working fluid, and cycle layout determine the maximum achievable efficiency of a cycle. Within an S-CO2 cycle the compression device is of critical importance as it is operating near the critical point of CO2. However, near the critical point, the thermo-physical properties of CO2 are highly sensitive to changes of pressure and temperature. Therefore, the conditions of CO2 at the compressor inlet are critical in the design of such cycles. Also, the impurity species diluted within the S-CO2 will cause deviation from an ideal S-CO2 cycle as these impurities will change the thermodynamic properties of the working fluid. Accordingly the current work examines the effects of different impurity compositions, considering binary mixtures of CO2 and: He, CO, O2, N2, H2, CH4, or H2S; on various S-CO2 cycle components. The second part of the study focuses on the calculation of the basic cycles and component efficiencies. The results of this study will provide guidance and defines the optimal composition of mixtures for compressors and coolers.

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