Selection of universal peptide biomarkers for the detection of the allergen hazelnut in food trough a comprehensive, high resolution mass spectrometric (HRMS) based approach

2020 ◽  
Vol 309 ◽  
pp. 125679 ◽  
Author(s):  
Kaatje Van Vlierberghe ◽  
Maxime Gavage ◽  
Marc Dieu ◽  
Patsy Renard ◽  
Thierry Arnould ◽  
...  
1973 ◽  
Vol 135 (1) ◽  
pp. 133-143 ◽  
Author(s):  
Hans J. Förster ◽  
Klaus Biemann ◽  
W. Geoffrey Haigh ◽  
Neil H. Tattrie ◽  
J. Ross Colvin

A novel C35 terpene and its monounsaturated analogue were isolated from cultures of Acetobacter xylinum, together with traces of their C36 homologues. These substances were found to be hopane derivatives substituted by a five-carbon chain bearing four vicinal hydroxyl groups. For the parent hydrocarbon the term bacteriohopane is proposed. The elucidation of the structures utilized high-resolution mass spectrometry of the terpenes, degradation to C32 hydrocarbons and detailed mass-spectrometric comparison of these with C32 hydrocarbons synthesized from known pentacyclic triterpenes. High-resolution mass-spectral data of the terpenes are presented. N.m.r. data are in agreement with the proposed structures, which are further supported by the isolation from the same organism of 22-hydroxyhopane and derivative hopene(s).


2011 ◽  
Vol 83 (23) ◽  
pp. 8937-8944 ◽  
Author(s):  
Qian Ruan ◽  
Qin C. Ji ◽  
Mark E. Arnold ◽  
W. Griffith Humphreys ◽  
Mingshe Zhu

1967 ◽  
Vol 20 (1) ◽  
pp. 103 ◽  
Author(s):  
QN Porter

The high-resolution mass spectra of benzo[b]thiophen, some alkyl and aryl derivatives, and the sulphone and 2,3-dihydrosulphone have been obtained; compositions of all significant ions in the spectra have been determined. Fragmentations of the unoxidized compounds are dominated by losses of C2H2 and CS units, while the sulphones undergo initial isomerization to cyclic sulphinates followed by expulsion of SO and fragments containing a C-O bond. Structures have been suggested for most of the ions observed.


2020 ◽  
Vol 304 ◽  
pp. 125428 ◽  
Author(s):  
Maxime Gavage ◽  
Kaatje Van Vlierberghe ◽  
Christof Van Poucke ◽  
Marc De Loose ◽  
Kris Gevaert ◽  
...  

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