Influence of nitrogen fertilization on physical and chemical properties of fatty acid methyl esters from Brassica napus oil

Fuel ◽  
2013 ◽  
Vol 111 ◽  
pp. 865-871 ◽  
Author(s):  
D.E. Leiva-Candia ◽  
M.F. Ruz-Ruiz ◽  
S. Pinzi ◽  
J.R. García-Ruiz ◽  
J. Domínguez ◽  
...  
2002 ◽  
Vol 67 (7) ◽  
pp. 473-480 ◽  
Author(s):  
Hulya Çelik

In this study, monoketo and monohydroxy eicosanoic acids and their methyl esters with the position of the substituent on odd numbered carbon atoms from 3 to 13 were synthesized with high purity. Furthermore, the semicarbazone and anilide derivatives of the obtained keto acids were prepared. They were characterized by TLC, IR and 1H-NMR spectroscopy and their physical and chemical properties were established.


1964 ◽  
Vol 47 (4) ◽  
pp. 776-780
Author(s):  
Walld Ibrahim ◽  
John Iverson ◽  
David Firestone

Abstract Some physical and chemical properties, including fatty acid composition by gas chromatography, of 15 commercially refined safflower oils and three crude oils extracted from safflower seed, were determined. The average and standard deviations found were: refractive index, 1.4748 ± 0.0003; specific gravity, 0.9210 ± 0.0005; iodine number, Wijs, 143.4 ± 1.4; squalene, 7.1 mg/100 g ± 1.1; and Bellier test, 7.4° ± 0.9. The major fatty acid components were; palmitic 6.7 ± 0.3, stearic 2.7 ± 0.4, oleic 12.9 ± 0.6, and linoleic 77.5 ± 1.1. Minor fatty acid components detected were myristic, arachidic, and eicosenoic acids.


2010 ◽  
Vol 1 (1) ◽  
pp. 157-161
Author(s):  
E. Sarkozi ◽  
L. Janosi

The rape is one of the suitable plant species for biofuel feedstock in Hungary. Currently there are over 100 admitted rape sorts recorded in Hungary and their oils’ application as biodiesel proposes new aspects of evaluation. From references it is noticeable that there are differences in the physical and chemical properties of the various rape sorts’ oils and rapeseed-methyl-esters. Our aim is to analyze the differences in the quality of the various rape sorts’ oils and to determine the most appropriate rape sort in the viewpoint of technical utilization. In the course of present research work we have measured the heating values of 21 various rapesorts’ oils -12 from open-pollinated varieties and 9 from hybrids- and examined the differences between them. The outcome values dispersed in the range of the heating values found in the references, but the differences between them are less then the predicted, the variance and the coefficient of variation are reasonably slight, so the examined rape sorts’ oils are similar in the viewpoint of the heating value. Furthermore, the energy content of the rapeseed oils is independent of the type (hybrid or open-pollinated variety) of the plant.


2019 ◽  
Vol 2019 ◽  
pp. 1-12 ◽  
Author(s):  
F. Anguebes-Franseschi ◽  
A. Bassam ◽  
M. Abatal ◽  
O. May Tzuc ◽  
C. Aguilar-Ucán ◽  
...  

Amazon sailfin catfish (Pterygoplichthys pardalis) is considered one of the greatest threats to the biodiversity of continental aquatic systems, causing serious economic and environmental problems in the regions. In this work, the production of biodiesel from Amazon sailfin catfish biomass oil is studied. The physical and chemical properties of biofuel produced were evaluated under the specifications of the European standard EN-14214 by using gas chromatography-mass spectrometry, infrared spectroscopy, and atomic absorption spectrometry analyses. The results show that the biodiesel complies with all the specifications of the standard, except the content of polyunsaturated methyl esters. The yields obtained from oil and biodiesel were 9.67 and 90.71% (m/m), respectively. The methyl ester concentrations study identified 17 components where 47.003% m/m corresponded to methyl esters with saturated chains, whereas 34.394% m/m was attributed to monosaturated methyl esters and the remaining (18.624% m/m) to polysaturated methyl esters. Finally, mineral analysis by atomic absorption showed the absence of heavy metals Cd, Ni, and Pb, as well as low concentrations of Ni, Fe, Cu, and Zn, demonstrating that the quality of the fuel is not compromised. The study indicates the feasibility of manufacturing biodiesel using Amazon sailfin catfish biomass oil as a low-cost raw material. It represents an environmental option to mitigate a global problem of atmospheric pollution, and at the same time, it shows a commercial alternative to reduce the ecological impact caused by this fish in the diverse ecosystems to which it has spread. In addition, the great adaptability of this fish provides the possibility of a profitable process to have very high rates of reproduction and growth, allowing the generation of large amounts of biomass for the production of biodiesel.


2012 ◽  
Vol 30 (1) ◽  
pp. 235-248
Author(s):  
Wojciech Dzięgielewski ◽  
Bartosz Gawron

The study outlines results from the studies on applicability of 1st generation biocomponent, namely long-chain fatty acid methyl esters (FAME) of vegetable origin, as an ingredient to fuels used to supply turbine aircraft engines. The presented analysis refers to both physical and chemical properties of developed fuel mixtures of Jet A-1 pure kerosene fuel with various amounts of the FAME additive and is based on own results obtained from tests of turbine engines on workbenches. The experiment results indicate that there are virtually no chances to apply the 1st generation biocomponents of the FAME type to aircrafts, however it is possible to seek for application opportunities of such biocomponents to other turbine engines, different from the aviation engineering.


2020 ◽  
Vol 39 (1) ◽  
pp. 140-147 ◽  
Author(s):  
E.O. Babatunde ◽  
H.B. Saka ◽  
M.A. Olutoye ◽  
U.G. Akpan ◽  
M. Auta

In this present study transesterification of used vegetable oil (UVO) using synthesized activated anthill as catalyst was investigated. The catalyst was prepared via calcination process, characterized by Brunauer-Emmett-Teller (BET), X-ray diffraction (XRD) and Fourier transform infrared (FTIR) techniques. From the BET analysis; calcination temperature has a positive impact on the textural properties. The XRD shows that the catalyst is crystalline in nature. Fatty acid methyl esters (FAME) was produced using thermally activated anthill as catalyst. The optimal FAME yield of 94.85 % was obtained at Methanol/Oil (M/O) 9:1, catalyst loading 1.5 wt%, reaction temperature of 65 ᵒ𝑪 and reaction time of 2 h. The physico-chemical properties of UVO – FAME produced was found to be within the American Society for Testing and Methods (ASTM). Hence, the study reveals that used vegetable oil catalyzed by novel activated anthill could be an effective feedstock to produce sustainable energy. Keywords: Anthills, FAME, Central composite design, Heterogeneous, used vegetable oil.


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