Three-dimensional ordered phosphotungstic acid/TiO2 with superior catalytic activity for oxidative desulfurization

Fuel ◽  
2018 ◽  
Vol 226 ◽  
pp. 148-155 ◽  
Author(s):  
Du Yue ◽  
Jiaheng Lei ◽  
Yang Peng ◽  
Junsheng Li ◽  
Xiaodi Du
Keyword(s):  
Catalytic Activity ◽  
Phosphotungstic Acid ◽  
Three Dimensional ◽  
Oxidative Desulfurization

Phosphotungstic acid encapsulated in the mesocages of amine-functionalized metal–organic frameworks for catalytic oxidative desulfurization

2014 ◽  
Vol 43 (31) ◽  
pp. 11950-11958 ◽  
Author(s):  
Xu-Sheng Wang ◽  
Yuan-Biao Huang ◽  
Zu-Jin Lin ◽  
Rong Cao
Keyword(s):  
Catalytic Activity ◽  
Phosphotungstic Acid ◽  
Metal Organic Frameworks ◽  
Oxidative Desulfurization ◽  
High Catalytic Activity ◽  
Exchange Method ◽  
Mild Conditions ◽  
Amine Functionalized ◽  
Catalytic Oxidative Desulfurization ◽  
Metal Organic

PTA@MIL-101(Cr)-NH2 has been prepared via an anion exchange method, and showed high catalytic activity for oxidative desulfurization under mild conditions.

Three-dimensionally ordered macroporous spinel-type MCr2O4 (M = Co, Ni, Zn, Mn) catalysts with highly enhanced catalytic performance for soot combustion

2015 ◽  
Vol 5 (9) ◽  
pp. 4594-4601 ◽  
Author(s):  
Jinguo Wang ◽  
Gaoyang Yang ◽  
Li Cheng ◽  
Eun Woo Shin ◽  
Yong Men
Keyword(s):  
Catalytic Activity ◽  
Three Dimensional ◽  
Catalytic Performance ◽  
Soot Combustion ◽  
Spinel Type ◽  
Ordered Macroporous

MCr2O4 catalysts with three-dimensional ordered macroporous structures displayed superior catalytic activity for soot combustion to their bulk counterparts.

scholarly journals Anchoring Water Soluble Phosphotungstic Acid by Hybrid Fillers to Construct Three-Dimensional Proton Transport Networks

Membranes ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 536
Author(s):  
Shaojian He ◽  
Zhongrui Lu ◽  
Wenxu Dai ◽  
Kangning Yang ◽  
Yang Xue ◽  
...  
Keyword(s):  
Relative Humidity ◽  
Composite Membrane ◽  
Proton Transport ◽  
Phosphotungstic Acid ◽  
Three Dimensional ◽  
Water Soluble ◽  
Hydroxyl Groups ◽  
Transport Networks ◽  
Hybrid Fillers ◽  
Speek Membrane

Phosphotungstic acid (HPW)-filled composite proton exchange membranes possess high proton conductivity under low relative humidity (RH). However, the leaching of HPW limits their wide application. Herein, we propose a novel approach for anchoring water soluble phosphotungstic acid (HPW) by polydopamine (PDA) coated graphene oxide and halloysite nanotubes (DGO and DHNTs) in order to construct hybrid three-dimensional proton transport networks in a sulfonated poly(ether ether ketone) (SPEEK) membrane. The introduction of PDA on the surfaces of the hybrid fillers could provide hydroxyl groups and secondary amine groups to anchor HPW, resulting in the uniform dispersion of HPW in the SPEEK matrix. The SPEEK/DGO/DHNTs/HPW (90/5/5/60) composite membrane exhibited higher water uptake and much better conductivity than the SPEEK membrane at low relative humidity. The best conductivity reached wass 0.062 S cm−1 for the composite membrane, which is quite stable during the water immersion test.

Effect of Preparation Methods of HPW/SiO2 Mesoporous Composites on its Catalytic Performance in Fuel Oils Desulfurization

2010 ◽  
Vol 148-149 ◽  
pp. 924-928
Author(s):  
Xue Min Yan ◽  
Yuan Zhu Mi
Keyword(s):  
Catalytic Activity ◽  
Self Assembly ◽  
Electrostatic Force ◽  
Oxidative Desulfurization ◽  
Strong Acid ◽  
Catalytic Performance ◽  
Synthesis Mechanism ◽  
Base Interaction ◽  
Preparation Methods ◽  
Oh Groups

Two kinds of mesoporous HPW/SiO2 composites, which have been synthesized respectively by the amino-functionalized (AF) method and evaporation-induced self-assembly (EISA) method, have been used as catalysts in the oxidative desulfurization process of dibenzothiophene(DBT). The catalytic performance results show that the catalyst synthesized by EISA method holds higher catalytic activity than that synthesized by the AF method. The difference of catalytic activity can be attributed to the different synthesis mechanism of two kinds of composites. In the AF method, the bonding force between HPW and SiO2 is strong acid-base interaction, which damages the Keggin structure. Whereas in the EISA process, electrostatic force and hydrogen bonds between W=O groups and Si-OH groups are main bonding forces. The hydrogen bond holds the electron-withdrawing effect, which increases the activity of nonbonding W=O groups in HPW and then results in the enhancement of the catalytic activity.

Facile synthesis of three-dimensional ordered macroporous Sr1−xKxTiO3 perovskites with enhanced catalytic activity for soot combustion

2018 ◽  
Vol 8 (21) ◽  
pp. 5462-5472 ◽  
Author(s):  
Peng Zhao ◽  
Nengjie Feng ◽  
Fan Fang ◽  
Geng Liu ◽  
Li Chen ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Three Dimensional ◽  
Catalytic Performance ◽  
Soot Combustion ◽  
Facile Synthesis ◽  
Ordered Macroporous

The appropriate incorporation of potassium into 3DOM SrTiO3 perovskites effectively improved the catalytic performance for soot combustion.

Nanoporous gold supported chromium-doped NiFe oxyhydroxides as high-performance catalysts for the oxygen evolution reaction

2019 ◽  
Vol 7 (16) ◽  
pp. 9690-9697 ◽  
Author(s):  
Jie-Song Sun ◽  
Yi-Tong Zhou ◽  
Rui-Qi Yao ◽  
Hang Shi ◽  
Zi Wen ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
High Performance ◽  
Three Dimensional ◽  
Nanoporous Gold

Chromium-doped NiFe oxyhydroxide nanosheets that are quasi-vertically oriented on three-dimensional nanoporous gold exhibit superior catalytic activity towards the oxygen evolution reaction.

Facile synthesis of mesoporous α-MnO2 nanorod with three-dimensional frameworks and its enhanced catalytic activity for VOCs removal

2013 ◽  
Vol 97 ◽  
pp. 1-3 ◽  
Author(s):  
Yinsu Wu ◽  
Sai Li ◽  
Yang Cao ◽  
Shengtao Xing ◽  
Zichuan Ma ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Three Dimensional ◽  
Facile Synthesis
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