Adsorption pore structure and its fractal characteristics of coals by N2 adsorption/desorption and FESEM image analyses

Fuel ◽  
2019 ◽  
Vol 257 ◽  
pp. 116031 ◽  
Author(s):  
Zhentao Li ◽  
Dameng Liu ◽  
Yidong Cai ◽  
Yunpeng Wang ◽  
Juan Teng
2013 ◽  
Vol 868 ◽  
pp. 276-281
Author(s):  
Li Mei Zhao ◽  
Jie Liang ◽  
Lu Xin Qian

In order to find the change rule of porous structure of oil shale during pyrolysis, the Huadian oil shale samples were heated to final temperature of 300°C400°C500°C600°C700°C. The pore structure and pore size distribution of oil shale and produced semi-cokes were measured by N2 isothermal adsorption/desorption method. The fractal characteristics and other parameters of porous structures were then analyzed in detail. The results indicate that the pores in oil shale were open at one direction while the pores in semi-cokes could be observed from two or even four directions. The pore sizes of semi-cokes were mostly between 3-5 nm; and the pore volume increased at a quickest rate when pyrolysis temperature increased from 400 to 600 °C. Oil shale and its semi-cokes all showed obvious fractal characteristics, whereas oil shale and the semi-coke from 600 °C gave the lowest fractal dimensions; this means that the matrix of oil shale tended to keep its original skeleton structure and the pore structure of semi-cokes from high temperatures became regular after devolatilization during the pyrolysis.


Minerals ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 377
Author(s):  
Zhelin Wang ◽  
Xuewei Jiang ◽  
Mao Pan ◽  
Yongmin Shi

Fractal dimension is a critical parameter to evaluate the heterogeneity of complex pore structure in tight sandstone gas and other low permeability reservoirs. To quantify the fractal dimension of tight sandstone at various pore size classes and evaluate their implications on mineral composition and nano pore structure parameters, we conducted an integrated approach of N2 adsorption/desorption experiment (N2-GA), X-ray diffraction (X-RD), and field emission scanning electron microscopy (FE-SEM) on Sulige tight sandstone reservoirs. By comparing the nine types of fractal dimensions calculated from N2 adsorption data, we put forward the concept of “concentrated” fractal dimensions and “scattered” fractal dimensions (DN2, DN3, DN5, DN7 and DN8) for the first time according to its concentration extent of distribute in different samples. Result shows that mineral composition has a significant influence of a different level on specific surface area (SSA), pore volume (PV), and fractal dimensions (DN), respectively, where the “scattered” fractal dimension is more sensitive to certain specific property of the reservoir, including mineral content and the specific surface area contribution rate (Sr) of type II mesopores (Mesopore-II: 10~50nm). In addition, three type of hysteresis loops were distinguished corresponding to different pore shape combination of N2-GA isotherm curve, which reveals that pore structure heterogeneity is mainly controlled by inkbottle-shaped pores and the volume contribution rate (Vr) of mesopores in this study area. These findings could contribute to a better understanding of the controlling effect of pore heterogeneity on natural gas storage and adsorption.


2011 ◽  
Vol 194-196 ◽  
pp. 385-388
Author(s):  
Hong Juan Wang ◽  
Feng Qiang Sun ◽  
Ming Zhong Ren ◽  
Qing Wei Guo

Nanoporous SnO2with high photocatalytic activity has been successfully prepared by a photochemical method, using SnCl2aqueous solution as a precursor. The as-synthesized sample was characterized by XRD, N2 adsorption-desorption and UV-vis. The photocatalytic activity of the sample was evaluated by degrading methylene blue (MB) aqueous solution under the UV light source and was compared with that of the commercial titania (Degussa P25). The results showed that the produced SnO2can degrade MB solution quickly and has comparative photocatalytic performance with P25 for degrading MB. This facile method supplies an effective way to prepare SnO2photocatalyst.


2019 ◽  
Vol 41 (1) ◽  
pp. 72-72
Author(s):  
Jilei Liang Jilei Liang ◽  
Mengmeng Wu Mengmeng Wu ◽  
Hongmei Cai Hongmei Cai ◽  
Hao Wang Hao Wang ◽  
Hua Huang Hua Huang ◽  
...  

Carbon microspheres (CMs) with a diameter of 5-10 μm have been synthesized by hydrothermal carbonization of starch and L-arginine. The surface property and structure of CMs were examined by FT-IR spectra, N2 adsorption-desorption isotherms and SEM images. These characterizations indicated that the L-arginine does not connect into the CMs but it promotes the starch hydrolysis and polymerization-condensation reaction of intermediate, which accelerates the formation of CMs and improves the yield in shorter time. The surface property of CMs determines adsorption capacity for acetic acid. By contrast, the porosity resulted from the carbonization at 500 and#176;C dominates the adsorption capacity for acetic acid.


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