Nickel acetylacetonate as decomposition catalyst for HTPB-based fuels: Regression rate enhancement effects

Fuel ◽  
2021 ◽  
Vol 305 ◽  
pp. 121539
Author(s):  
Hongsheng Yu ◽  
Suhang Chen ◽  
Xiaodong Yu ◽  
Wei Zhang ◽  
Christian Paravan ◽  
...  
Aerospace ◽  
2019 ◽  
Vol 6 (12) ◽  
pp. 127 ◽  
Author(s):  
Paravan

This work provides a lab-scale investigation of the ballistics of solid fuel formulations based on hydroxyl-terminated polybutadiene and loaded with Al-based energetic additives. Tested metal-based fillers span from micron- to nano-sized powders and include oxidizer-containing fuel-rich composites. The latter are obtained by chemical and mechanical processes providing reduced diffusion distance between Al and the oxidizing species source. A thorough pre-burning characterization of the additives is performed. The combustion behaviors of the tested formulations are analyzed considering the solid fuel regression rate and the mass burning rate as the main parameters of interest. A non-metallized formulation is taken as baseline for the relative grading of the tested fuels. Instantaneous and time-average regression rate data are determined by an optical time-resolved technique. The ballistic responses of the fuels are analyzed together with high-speed visualizations of the regressing surface. The fuel formulation loaded with 10 wt.% nano-sized aluminum (ALEX-100) shows a mass burning rate enhancement over the baseline of 55% ± 11% for an oxygen mass flux of 325 ± 20 kg/(m2∙s), but this performance increase nearly disappears as combustion proceeds. Captured high-speed images of the regressing surface show the critical issue of aggregation affecting the ALEX-100-loaded formulation and hindering the metal combustion. The oxidizer-containing composite additives promote metal ignition and (partial) burning in the oxidizer-lean region of the reacting boundary layer. Fuels loaded with 10 wt.% fluoropolymer-coated nano-Al show mass burning rate enhancement over the baseline >40% for oxygen mass flux in the range 325 to 155 kg/(m2∙s). The regression rate data of the fuel composition loaded with nano-sized Al-ammonium perchlorate composite show similar results. In these formulations, the oxidizer content in the fuel grain is <2 wt.%, but it plays a key role in performance enhancement thanks to the reduced metal–oxidizer diffusion distance. Formulations loaded with mechanically activated ALEX-100–polytetrafluoroethylene composites show mass burning rate increases up to 140% ± 20% with metal mass fractions of 30%. This performance is achieved with the fluoropolymer mass fraction in the additive of 45%.


1998 ◽  
Author(s):  
Philmon George ◽  
S. Krishnan ◽  
P. Varkey ◽  
M. Ravindran ◽  
Lalitha Ramachandran

Author(s):  
Luciano Galfetti ◽  
Matteo Boiocchi ◽  
Christian Paravan ◽  
Elena Toson ◽  
Andrea Sossi ◽  
...  

1983 ◽  
Vol 48 (8) ◽  
pp. 2423-2435 ◽  
Author(s):  
Vladimír Pouzar ◽  
Soňa Vašíčková ◽  
Pavel Drašar ◽  
Ivan Černý ◽  
Miroslav Havel

Reaction of 5α-pregnan-21-al (V), obtained from ester of the corresponding acid III via the alcohol IV, with lithium salt of 1-methoxymethoxy-2-propyne afforded both the isomeric 25-methoxymethoxy-21,26,27-trinor-5α-cholest-23-yn-22-ols (VI and VIII) which were converted into two 21,26,27-trinor-5α-cholestane-22,25-diols (XI, XV). Absolute configuration of the alcohols X and XIV was assigned by chemical correlation with derivatives XXVI and XXVII of known absolute configuration at C(20). The correlation was based on reduction of thiocarbonates derived from the diols XXII and XXIV for which also Cotton effects of their complexes with nickel acetylacetonate were studied. Both diols were prepared from 5α-pregnan-20-one (XVIII) via 5α-pregn-20-yne (XIX) and the 21,26,27-trinor-5α-cholest-20-ene derivative XXI.


Author(s):  
Elizabeth T. Jens ◽  
Victor A. Miller ◽  
Flora S. Mechentel ◽  
Brian J. Cantwell ◽  
Scott Hubbard

Aerospace ◽  
2021 ◽  
Vol 8 (7) ◽  
pp. 190
Author(s):  
Francesco Barato

Ablative-cooled hybrid rockets could potentially combine a similar versatility of a liquid propulsion system with a much simplified architecture. These characteristics make this kind of propulsion attractive, among others, for applications such as satellites and upper stages. In this paper, the use of hybrid rockets for those situations is reviewed. It is shown that, for a competitive implementation, several challenges need to be addressed, which are not the general ones often discussed in the hybrid literature. In particular, the optimal thrust to burning time ratio, which is often relatively low in liquid engines, has a deep impact on the grain geometry, that, in turn, must comply some constrains. The regression rate sometime needs to be tailored in order to avoid unreasonable grain shapes, with the consequence that the dimensional trends start to follow some sort of counter-intuitive behavior. The length to diameter ratio of the hybrid combustion chamber imposes some packaging issues in order to compact the whole propulsion system. Finally, the heat soak-back during long off phases between multiple burns could compromise the integrity of the case and of the solid fuel. Therefore, if the advantages of hybrid propulsion are to be exploited, the aspects mentioned in this paper shall be carefully considered and properly faced.


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