A conceptual comparison between potential configurations in the thermal coupling of naphtha reforming with propane ammoxidation

Author(s):  
Samira Ebrahimian ◽  
Davood Iranshahi
Author(s):  
R. L. Freed ◽  
M. J. Kelley

The commercial introduction of Pt-Re supported catalysts to replace Pt alone on Al2O3 has brought improvements to naphtha reforming. The bimetallic catalyst can be operated continuously under conditions which lead to deactivation of the single metal catalyst by coke formation. Much disagreement still exists as to the exact nature of the bimetallic catalyst at a microscopic level and how it functions in the process so successfully. The overall purpose of this study was to develop the materials characterization tools necessary to study supported catalysts. Specifically with the Pt-Re:Al2O3 catalyst, we sought to elucidate the elemental distribution on the catalyst.


2018 ◽  
Author(s):  
Nicolò Bontempi ◽  
Irene Vassalini ◽  
Stefano Danesi ◽  
Matteo Ferroni ◽  
Paolo Colombi ◽  
...  

<p>Here we investigate for the first time the opto-thermal behavior of SiO<sub>2</sub>/Si core/shell microbeads (Si-rex) irradiated with three common Raman laser sources (lambda=532, 633, 785 nm) under real working conditions. We obtained an experimental proof of the critical role played by bead size and aggregation in heat and light management, demonstrating that in the case of strong opto-thermal coupling the temperature can exceed that of the melting points of both core and shell components. In addition, we also show that weakly coupled beads can be utilized as stable substrates for plasmon-free SERS experiments.</p>


2020 ◽  
Vol 10 (8) ◽  
pp. 2790
Author(s):  
Wenzheng Zhuang ◽  
Chao Yang ◽  
Zhigang Wu

Hybrid corrugated sandwich (HCS) plates have become a promising candidate for novel thermal protection systems (TPS) due to their multi-functionality of load bearing and thermal protection. For hypersonic vehicles, the novel TPS that performs some structural functions is a potential method of saving weight, which is significant in reducing expensive design/manufacture cost. Considering the novel TPS exposed to severe thermal and aerodynamic environments, the mechanical stability of the HCS plates under fluid-structure-thermal coupling is crucial for preliminary design of the TPS. In this paper, an innovative layerwise finite element model of the HCS plates is presented, and coupled fluid-structure-thermal analysis is performed with a parameter study. The proposed method is validated to be accurate and efficient against commercial software simulation. Results have shown that the mechanical instability of the HCS plates can be induced by fluid-structure coupling and further accelerated by thermal effect. The influences of geometric parameters on thermal buckling and dynamic stability present opposite tendencies, indicating a tradeoff is required for the TPS design. The present analytical model and numerical results provide design guidance in the practical application of the novel TPS.


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