Ammonia decomposition reaction to produce COx-free hydrogen using carbon supported cobalt catalysts in microwave heated reactor system

2020 ◽  
Vol 45 (60) ◽  
pp. 34867-34878 ◽  
Author(s):  
Rukan Can Seyfeli ◽  
Dilek Varisli
Author(s):  
Dilek Varisli ◽  
Tugba Rona

Abstract Ammonia has become an important source for hydrogen especially for fuel cell applications that require COx free hydrogen. In this study, high surface area Pt incorporated mesoporous siliceous materials were prepared for ammonia decomposition reaction to produce clean hydrogen. The results of a fixed bed flow reactor tests, conducted using pure ammonia showed that Pt-SiO2 type catalysts which were prepared by a one-pot hydrothermal synthesis procedure were very active in ammonia decomposition, such as 72% conversion was reached at 500°C at a gas hourly space velocity of 5,100 ml/h.gcat over the catalyst prepared at Pt/Si mol ratio of 0.03. Activity of the synthesized catalysts increased with an increase in Pt loading. Platinum incorporated siliceous materials prepared by impregnation procedures were also tested in ammonia decomposition and highly promising results were obtained.


2018 ◽  
Vol 27 (2) ◽  
pp. 128-136 ◽  
Author(s):  
Ahmed E. Awadallah ◽  
Ateyya A. Aboul-Enein ◽  
Abdellatif H. Mahmoud ◽  
Sayed S. Abd El Rehim ◽  
Ahmed K. El-Ziaty ◽  
...  

2003 ◽  
Vol 43 (4) ◽  
pp. 355-369 ◽  
Author(s):  
Jordi Llorca ◽  
Pilar Ramı́rez de la Piscina ◽  
Jean-Alain Dalmon ◽  
Joaquim Sales ◽  
Narcı́s Homs

2018 ◽  
Vol 54 (49) ◽  
pp. 6364-6367 ◽  
Author(s):  
Yanping Li ◽  
Jie Wen ◽  
Arshid M. Ali ◽  
Ming Duan ◽  
Wei Zhu ◽  
...  

Size structure–catalytic performance correlation was investigated with supported Ni/MCF-17 catalysts over COx-free hydrogen production via the ammonia decomposition reaction.


2018 ◽  
Vol 15 (10) ◽  
pp. 568-576 ◽  
Author(s):  
Ahmed E. Awadallah ◽  
Ateyya A. Aboul-Enein ◽  
Abdellatif H. Mahmoud ◽  
Sayed S. Abd El Rehim ◽  
Ahmed K. El-Ziaty ◽  
...  

Author(s):  
Natalia Morlanés ◽  
Salvador Sayas ◽  
Genrikh Shterk ◽  
Sai P. Katikaneni ◽  
Aadesh Harale ◽  
...  

COx-free hydrogen production; cobalt-based catalysts for ammonia decomposition; cerium–barium promoter in cobalt catalysts.


2021 ◽  
Author(s):  
Yingqiu Gu ◽  
Di Xu ◽  
Yun Huang ◽  
Zhouyang Long ◽  
Guojian Chen

Transition metals have been considered as potential catalysts for ammonia decomposition to produce COx-free hydrogen for fuel cells. However, the facile synthesis of transition metal catalyst with small size active...


2013 ◽  
Vol 56 (9-10) ◽  
pp. 730-736 ◽  
Author(s):  
A. Lillebø ◽  
S. Håvik ◽  
E. A. Blekkan ◽  
A. Holmen

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