Electrochemical behaviors and passive film properties of Fe-based bulk metallic glass in Cl−-containing acetic acid solutions under high temperature

2018 ◽  
Vol 766 ◽  
pp. 964-972 ◽  
Author(s):  
D.D. Liang ◽  
X.S. Wei ◽  
Y. Wang ◽  
H.R. Jiang ◽  
J. Shen
2021 ◽  
Vol 6 (3(62)) ◽  
pp. 11-14
Author(s):  
Oleh Zimin

The object of research in this work is the intensification of hydrocarbon production. The most problematic task of the study is the efficiency of intensification of compacted high-temperature carbonate reservoirs. Despite the gradual transition to renewable energy sources, natural gas and oil will play a dominant role in the world's energy balance in the next 20–30 years. Carbonate rocks have significant mining potential, but low filtration properties require intensification to improve reservoir permeability. High temperatures and pressures at great depths require the improvement of existing hydrocarbon production technologies. The most popular method for treating reservoirs containing carbonates is acid treatments in different variations, but for effective treatment it is necessary to achieve deep penetration of the solution into the formation. The study solves the problem of selection of effective carrier liquids for the preparation of acid solutions for the treatment of compacted high-temperature reservoirs with high carbonate content. To ensure quality treatment, acid solutions must have low viscosity and surface tension coefficient, low reaction rate, their chemical properties must ensure the absence of insoluble precipitates in the process of reactions with fluids and rocks, as well as be environmentally friendly. To select the most optimal carrier liquid, experiments were conducted to determine which candidate liquids provide the minimum reaction rate of acidic solutions with carbonates. Based on the analysis of industrial application data and literature sources, water, nephras, methanol, ethyl acetate, and methyl acetate were selected for further research. Widely studied acetic acid was chosen as the basic acid. Studies have shown that methyl acetate has a number of advantages, namely low reaction rate, low viscosity and surface tension coefficient. As well as the possibility of hydrolysis in the formation with the release of acetic acid, which significantly prolongs the reaction time of the solution with the rock and the depth of penetration of the active solution into the formation.


2012 ◽  
Vol 521 ◽  
pp. 225-253
Author(s):  
Mustafa Bakkal

This chapter covers the series of machinability evaluation test result and discussions of Zr52.5Ti5Cu17.9Ni14.6Al10bulk metallic glass (BMG). These tests are lathe turning, drilling, milling and preliminary level grinding tests. In the continuous machining methods such as turning, drilling and grinding of BMG, above a threshold cutting speed, the low thermal conductivity of BMG leads to chip temperatures high enough to cause the chip oxidation and associated light emission. The high temperature produced by this exothermic chemical reaction causes crystallization within the chips. Chips morphology suggests that increasing amounts of viscous flow control the chip-removal process. Moreover, viscous flow and crystallization can occur during the machining of the bulk metallic glass, even under the high temperature gradient and strain rate. High cutting speed significantly reduced the forces for BMG machining due to thermal softening. However, in intermittent cutting process which is milling, there is no high temperature problem, special burr formations the rollover and the top burr were observed along the slot and achieved good surface roughness, Ra= 0.113 μm, using conventional WC-Co cutting tool. In each method, tests repeated for the conventional materials for comparison purpose. This study concludes the precision machining of BMG is possible with the selection of feasible tools and process parameters for each method.


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