Background:
Mn doped ZnS is selected as the right element which is prominent among
quantum dot for its high luminescent and quantum yield property and also non toxicity while comparing
with other organometallic quantum dot synthesized by using different capping agents.
Methods:
An interesting observation based on colorimetric sensing of dopamine using manganese
doped zinc sulfide quantum dot is discussed in this study. Mn doped ZnS quantum dot surface passivated
with capping agents such as L-histidine and also in polymers like chitosan, PVA and PVP
were studied and compared. The tunable fluorescence effect was also observed in different polymers
and amino acid as capping agents. Optical characterization studies like UV-Visible spectroscopy and
PL spectroscopy have been carried out. The functional group modification of Quantum dot has been
analyzed using FTIR and size and shape analysis was conducted by using HRTEM image.
Result:
The strong and broad peak of FTIR in the range of 3500-3300 cm-1 confirms the presence of
O-H bond. It is also observed that quenching phenomena in the luminescent peak are due to weaker
confinement effect. The average size of the particle is shown to be around 4-5 nm. Changes in color
of the quantum dot solution from transparent to dark brown has been due to the interaction with dopamine.
Conclusion:
Finally, L-Histidine amino acid capped Mn:ZnS shows better results in luminescence
and size confinement properties. Hence, it was chosen for dopamine sensing due to its colloidal nature
and inborn affinity towards dopamine, a neurotransmitter which is essential for early diagnosis
of neural diseases
Spectroscopic Characterization of a reactive [Cu2(µ‐OH)2] intermediate in Cu/TEMPO catalyzed aerobic alcohol oxidation reaction
