Formation and stabilization of colloidal ultra-small palladium nanoparticles on diamine-modified Cr-MIL-101: Synergic boost to hydrogen production from formic acid

2020 ◽  
Vol 567 ◽  
pp. 126-135 ◽  
Author(s):  
Hassan Alamgholiloo ◽  
Sadegh Rostamnia ◽  
Asadollah Hassankhani ◽  
Xiao Liu ◽  
Aziz Eftekhari ◽  
...  
Materials ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3258
Author(s):  
Hamed M. Alshammari ◽  
Mohammad Hayal Alotaibi ◽  
Obaid F. Aldosari ◽  
Abdulellah S. Alsolami ◽  
Nuha A. Alotaibi ◽  
...  

The present study investigates a process for the selective production of hydrogen from the catalytic decomposition of formic acid in the presence of iridium and iridium–palladium nanoparticles under various conditions. It was found that a loading of 1 wt.% of 2% palladium in the presence of 1% iridium over activated charcoal led to a 43% conversion of formic acid to hydrogen at room temperature after 4 h. Increasing the temperature to 60 °C led to further decomposition and an improvement in conversion yield to 63%. Dilution of formic acid from 0.5 to 0.2 M improved the decomposition, reaching conversion to 81%. The reported process could potentially be used in commercial applications.


2015 ◽  
Vol 5 (1) ◽  
pp. 364-371 ◽  
Author(s):  
M. Navlani-García ◽  
M. Martis ◽  
D. Lozano-Castelló ◽  
D. Cazorla-Amorós ◽  
K. Mori ◽  
...  

Palladium nanoparticles supported on different BETA zeolites are promising catalysts for H2production from formic acid dehydrogenation.


2019 ◽  
Vol 6 (3) ◽  
pp. 104-107
Author(s):  
Marina Vladimirovna Lebedeva ◽  
Alexey Petrovich Antropov ◽  
Alexander Victorovich Ragutkin ◽  
Nicolay Andreevich Yashtulov

In paper electrode materials with palladium nanoparticles on polymer matrix substrates for energy sources have been formed. Nanocomposites were investigated by atomic force and scanning electron microscopy. The catalytic activity of formed electrodes in the formic acid oxidation reaction was evaluated by voltammetry method.


2021 ◽  
Vol 45 ◽  
pp. 101078
Author(s):  
Samuel Eshorame Sanni ◽  
Peter Adeniyi Alaba ◽  
Emeka Okoro ◽  
Moses Emetere ◽  
Babalola Oni ◽  
...  

2021 ◽  
Author(s):  
Yusuke Minami ◽  
Yutaka Amao

Formate is attracting attention as a hydrogen carrier because of its low toxicity and easy handling in aqueous solution. In order to utilize formic acid as a hydrogen carrier, a...


2010 ◽  
Vol 132 (26) ◽  
pp. 8924-8934 ◽  
Author(s):  
Albert Boddien ◽  
Björn Loges ◽  
Felix Gärtner ◽  
Christian Torborg ◽  
Koichi Fumino ◽  
...  

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