Solvothermal synthesis of porphyrin-ferrocenyl conjugated microporous polymer nanospheres for shape-stable phase change materials with improved latent heat and cyclability

2021 ◽  
Vol 595 ◽  
pp. 178-186
Author(s):  
Huimin Li ◽  
Nan Meng ◽  
Wei Lyu ◽  
Zhonghua Cheng ◽  
Sijie Chen ◽  
...  
2020 ◽  
Vol 396 ◽  
pp. 125265 ◽  
Author(s):  
Yunzhi Tan ◽  
Yu Xiao ◽  
Rui Chen ◽  
Changlin Zhou ◽  
Lei Wang ◽  
...  

Energies ◽  
2021 ◽  
Vol 14 (22) ◽  
pp. 7761
Author(s):  
Xiaohui Lu ◽  
Xiaoxue Luo ◽  
Shibo Cao ◽  
Changzhen Zou

Benefitting from the characteristics of a high latent heat capacity and stable phase change behavior, phase change materials have widely received concerns in the field of thermodynamic management. Ba(OH)2·8H2O is an ideal phase change material (PCM) in the mid-to-low temperature range, but its large-scale application is still limited by severe supercooling during the nucleation process. In this paper, the experimental analysis and comparison are performed via an Edisonian approach, where Ba(OH)2·8H2O is adopted as an original substrate; BaCO3, CaCl2, NaCl, KH2PO4, and NaOH are selected as nucleating agents; and graphite is used as a heat-conducting agent. The results show that Ba(OH)2·8H2O containing 1.2% BaCO3 and 0.2% graphite powder has the best performance. Compared with pure Ba(OH)2·8H2O, the supercooling degree is reduced to less than 1 °C, the phase change latent heat duration is extended, and the thermal conductivity is significantly improved. Therefore, this study not only provides a reference for the application of Ba(OH)2·8H2O, but can also be used as a guidance for other material modifications.


2011 ◽  
Vol 197-198 ◽  
pp. 584-588 ◽  
Author(s):  
Jing Guo ◽  
Heng Xue Xiang ◽  
Qian Qian Wang

With stearic acid (SA) as phase change material, waste polyacrylonitrile fiber (PAN) as framework material, N,N-dimethylformamide (DMF) as solvent, form-stable PAN/SA blends phase change materials (PCM) are prepared by solution blending process. Phase change temperature and latent heat and the thermal stability of the PAN/SA PCM are characterized using Differential Scanning Calorimetry (DSC). The structure, crystalline morphology, and thermal insulation properties of the PAN/SA PCMs are investigated using Fourier transformation infrared spectroscope (FTIR), polarizing optical microscopy (POM), and temperature-recording instrument. The FTIR and POM results show that PAN and SA are combined by intermolecular forces, and SA is homogeneous distribution in the PAN matrix. The DSC results indicate that PAN/SA PCMs have high latent heat storage capacity of more than 115J/g, the phase transition temperature and phase transition enthalpy of the PCMs increase with increasing the mass percent of SA. Cooling curve of PAN/SA PCMs show that the PCMs have good insulation properties, the soaking time is continued for about six minutes, and the thermal insulation properties remain unchanged after five and ten times of thermal cycling. The best process condition is obtained by the soaking time and orthogonal experiment.


2020 ◽  
Vol 8 (42) ◽  
pp. 22315-22326
Author(s):  
Jiahao Ma ◽  
Tian Ma ◽  
Wenpeng Duan ◽  
Weihan Wang ◽  
Jue Cheng ◽  
...  

Sprayable form-stable phase change materials show excellent latent heat, photonic/thermal/electrical responses, superhydrophobicity, shape variation ability, thermal recycling properties and stability.


Author(s):  
J. Martínez-Gómez ◽  
E. Urresta ◽  
D. Gaona ◽  
G. Guerrón

Esta investigación tiene como objetivo seleccionar un material de cambio de fase (PCM) que cumplen mejor la solución del almacenamiento de energía térmica entre 200-400 ° C y reducir el costo de producción. El uso de métodos multicriterios de toma de decisiones (MCMD) para la evaluación fueron proporcionales implementados como COPRAS-G, TOPSIS y VIKOR. La ponderación de los criterios se realizó por el método AHP (proceso analítico jerárquico) y los métodos de entropía. La correlación de los resultados entre los tres métodos de clasificación ha sido desarrollada por el coeficiente de correlación de Spearman. Los resultados ilustran el mejor y la segundo mejor opción para los tres MCDM fueron NaOH y KNO3. Además, tenía valores de correlación de Spearman entre los métodos excede de 0.714.


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