Enhanced enzymatic performance of immobilized lipase on metal organic frameworks with superhydrophobic coating for biodiesel production

2021 ◽  
Author(s):  
Le Zhong ◽  
Yuxiao Feng ◽  
Hongtong Hu ◽  
Jiabao Xu ◽  
Ziyuan Wang ◽  
...  
Keyword(s):  
Immobilized Lipase ◽  
Metal Organic Frameworks ◽  
Biodiesel Production ◽  
Superhydrophobic Coating ◽  
Metal Organic

An Overview of Metal-organic Frameworks-based Acid/Base Catalysts for Biofuel Synthesis

2020 ◽  
Vol 24 (16) ◽  
pp. 1876-1891
Author(s):  
Qiuyun Zhang ◽  
Yutao Zhang ◽  
Jingsong Cheng ◽  
Hu Li ◽  
Peihua Ma
Keyword(s):  
Alternative Fuels ◽  
Heterogeneous Catalysts ◽  
Supported Catalysts ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Flexible Structures ◽  
Biodiesel Production ◽  
Biodiesel Synthesis ◽  
Metal Organic ◽  
Organic Framework

Biofuel synthesis is of great significance for producing alternative fuels. Among the developed catalytic materials, the metal-organic framework-based hybrids used as acidic, basic, or supported catalysts play major roles in the biodiesel production. This paper presents a timely and comprehensive review of recent developments on the design and preparation of metal-organic frameworks-based catalysts used for biodiesel synthesis from various oil feedstocks, including MILs-based catalysts, ZIFs-based catalysts, UiO-based catalysts, Cu-BTC-based catalysts, and MOFs-derived porous catalysts. Due to their unique and flexible structures, excellent thermal and hydrothermal stability, and tunable host-guest interactions, as compared with other heterogeneous catalysts, metal-organic framework-based catalysts have good opportunities for application in the production of biodiesel at industrial scale.

scholarly journals Metal-organic Frameworks as a Robust Biocatalysis Platform for Enzymatic Production of Biodiesel

2021 ◽  
Vol 245 ◽  
pp. 01023
Author(s):  
Xinlong Liu ◽  
Peng Liu ◽  
Na An ◽  
Chen Liu
Keyword(s):  
High Surface ◽  
Metal Organic Frameworks ◽  
High Surface Area ◽  
Biodiesel Production ◽  
Lipase Immobilization ◽  
Enzymatic Production ◽  
Metal Organic ◽  
Predicted Model ◽  
Immobilized Calb ◽  
Optimized Conditions

Metal–organic frameworks (MOFs) are an attractive class of hybrid materials with metal clusters and organic linkers. The unusual properties of MOFs, such as permanent nanoscale porosity, high surface area, uniformly structured cavities and the availability of in-pore functionality and outer-surface modification, are advantageous using as lipase immobilization platform. Herein, we covalent immobilized CALB onto MOFs and then evaluated the biocatalyst performance in the esterification of oleic acid with methanol for biodiesel production. Experimental data about the methanolysis process was evaluated by response surface methodology. The highest yield of 98.9 ± 0.4% was obtained under the optimized conditions: methanol/oil ratio of 3.65:1, a reaction temperature of 46.3 °C, a CALB@MOF loading of 117.77 mg and a reaction time of 11.55 h, which was closed to the predicted value (100.00%). Verification experiment confirmed the validity of the predicted model.

Crystal Facets Make a Profound Difference in Polyoxometalate-Containing Metal–Organic Frameworks as Catalysts for Biodiesel Production

2015 ◽  
Vol 137 (39) ◽  
pp. 12697-12703 ◽  
Author(s):  
Yiwei Liu ◽  
Shumei Liu ◽  
Danfeng He ◽  
Ning Li ◽  
Yujuan Ji ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Biodiesel Production ◽  
Metal Organic

Metal-Organic Frameworks

2021 ◽  
Author(s):  
Lars Öhrström ◽  
Francoise M. Amombo Noa
Keyword(s):  
Metal Organic Frameworks ◽  
Metal Organic
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