Hybrid polymer aerogels containing porphyrins as catalysts for efficient photodegradation of pharmaceuticals in water

Author(s):  
Rafael F. N. Quadrado ◽  
Henrique F. V. Vitoria ◽  
Daniele C. Ferreira ◽  
Klaus Krambrock ◽  
Kelly S. Moreira ◽  
...  
Keyword(s):  
2003 ◽  
Vol 780 ◽  
Author(s):  
R. Houbertz ◽  
J. Schulz ◽  
L. Fröhlich ◽  
G. Domann ◽  
M. Popall ◽  
...  

AbstractReal 3-D sub-νm lithography was performed with two-photon polymerization (2PP) using inorganic-organic hybrid polymer (ORMOCER®) resins. The hybrid polymers were synthesized by hydrolysis/polycondensation reactions (modified sol-gel synthesis) which allows one to tailor their material properties towards the respective applications, i.e., dielectrics, optics or passivation. Due to their photosensitive organic functionalities, ORMOCER®s can be patterned by conventional photo-lithography as well as by femtosecond laser pulses at 780 nm. This results in polymerized (solid) structures where the non-polymerized parts can be removed by conventional developers.ORMOCER® structures as small as 200 nm or even below were generated by 2PP of the resins using femtosecond laser pulses. It is demonstrated that ORMOCER®s have the potential to be used in components or devices built up by nm-scale structures such as, e.g., photonic crystals. Aspects of the materials in conjunction to the applied technology are discussed.


The main methods (pressing and winding) of the processing of hybrid polymer composites to obtain items were examined. Advantages and disadvantages of the methods were noted. Good combinations of different-module fibers (carbon, glass, boron, organic) in hybrid polymer materials are described, which allow one to prepare materials with high compression strength on the one hand, and to increase fracture energy of samples and impact toughness on the other hand.


Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1282
Author(s):  
M.J. Suriani ◽  
Fathin Sakinah Mohd Radzi ◽  
R.A. Ilyas ◽  
Michal Petrů ◽  
S.M. Sapuan ◽  
...  

Oil palm empty fruit bunches (OPEFB) fiber is a natural fiber that possesses many advantages, such as biodegradability, eco-friendly, and renewable nature. The effect of the OPEFB fiber loading reinforced fire retardant epoxy composites on flammability and tensile properties of the polymer biocomposites were investigated. The tests were carried out with four parameters, which were specimen A (constant), specimen B (20% of fiber), specimen C (35% of fiber), and specimen D (50% of fiber). The PET yarn and magnesium hydroxide were used as the reinforcement material and fire retardant agent, respectively. The results were obtained from several tests, which were the horizontal burning test, tensile test, and scanning electron microscopy (SEM). The result for the burning test showed that specimen B exhibited better flammability properties, which had the lowest average burning rate (11.47 mm/min). From the tensile strength, specimen A revealed the highest value of 10.79 N/mm2. For the SEM morphological test, increasing defects on the surface ruptured were observed that resulted in decreased tensile properties of the composites. It can be summarized that the flammability and tensile properties of OPEFB fiber reinforced fire retardant epoxy composites were reduced when the fiber volume contents were increased at the optimal loading of 20%, with the values of 11.47 mm/min and 4.29 KPa, respectively.


Author(s):  
Monisha Baby ◽  
Vijayalakshmi K. Periya ◽  
Bhuvaneshwari Soundiraraju ◽  
Nisha Balachandran ◽  
Suchithra Cheriyan ◽  
...  

Author(s):  
R. Raja ◽  
G. Sabari Narayanan ◽  
K. Senthil Kumar ◽  
S. Rajesh Babu ◽  
M. Manikandan ◽  
...  

Author(s):  
Pankaj Sonia ◽  
Jinesh Kumar Jain ◽  
Piyush Singhal ◽  
Kuldeep K. Saxena

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