scholarly journals Ebullition enhances chemical mass transport across the tailings-water interface of oil sands pit lakes

Author(s):  
Daniel J. Francis ◽  
S. Lee Barbour ◽  
Matthew B.J. Lindsay
2019 ◽  
Author(s):  
Daniel Francis ◽  
◽  
Matthew B.J. Lindsay ◽  
Lee Barbour

Environments ◽  
2020 ◽  
Vol 7 (11) ◽  
pp. 100
Author(s):  
Kristina Åhlgren ◽  
Viktor Sjöberg ◽  
Mattias Bäckström

Alum shale was mined for oil and uranium production in Kvarntorp, Sweden, 1942–1966. Remnants such as pit lakes, exposed shale and a 100-meter-high waste deposit with a hot interior affect the surrounding environment, with elevated concentrations of, e.g., Mo, Ni and U in the recipient. Today most pit lakes are circumneutral while one of the lakes is still acidic. All pit lakes show signs of sulfide weathering with elevated sulfate concentrations. Mass transport calculations show that for elements such as uranium and molybdenum the western lake system (lake Söderhavet in particular) contributes the largest part. For sulfate, the two western lakes contribute with a quarter each, the eastern lake Norrtorpssjön about a third and a serpentine pond system receiving water from the waste deposit contributes around 17%. Except for a few elements (e.g., nickel 35%), the Serpentine system (including the waste deposit area) is not a very pronounced point source for metal release compared to the pit lakes. Estimates about future water runoff when the deposit has cooled down suggest only a slight increase in downstream water flow. There could possibly be first flush effects when previous hot areas have been reached by water.


Atmosphere ◽  
2020 ◽  
Vol 11 (10) ◽  
pp. 1057
Author(s):  
Marc L. Mansfield

When they dissolve in water, aldehydes become hydrated to gem-diols: R−COH+H2O↔RCH(OH)2. Such reactions can complicate air–water transport models. Because of a persistent belief that the gem-diols do not exist in the vapor phase, typical models do not allow them to pass through the air–water interface, but in fact, they do. Therefore, transport models that allow both molecular forms to exist in both phases and to pass through the interface are needed. Such a model is presented here as a generalization of Whitman’s two-film model. Since Whitman’s model has fallen into disuse, justification of its use is also given. There are hypothetical instances for which the flux predicted by the current model is significantly larger than the flux predicted when models forbid the diol form from passing through the interface. However, for formaldehyde and acetaldehyde, the difference is about 6% and 2%, respectively.


2018 ◽  
Vol 54 (4) ◽  
pp. 2799-2812 ◽  
Author(s):  
Joey J. Voermans ◽  
Marco Ghisalberti ◽  
Gregory N. Ivey

Author(s):  
Kai Wei ◽  
Heidi L. Cossey ◽  
Ania C. Ulrich

AbstractSurface mining of oil sands ore in Alberta, Canada has generated fluid fine tailings (FFT) that must be reclaimed. End pit lakes (EPLs), which consist of thick deposits of FFT capped with water, have been proposed for FFT reclamation, and Base Mine Lake (BML) is the first full-scale demonstration EPL. However, FFT particle settling and resuspension contributes to high turbidity in the BML water cap, which may be detrimental to the development of an aquatic ecosystem. This study investigated the effect of Ca and Al treatments on turbidity mitigation. The initial turbidity was reduced from 20 NTU to less than 2 NTU in BML surface water treated with 54 mg/L of Ca or 1.1 mg/L of Al. At a concentration of 1.1 mg/L, Al reduced the initial turbidity to a greater extent, and in a shorter time, than 54 mg/L of Ca. Further, resuspended Al-treated FFT particles were 100–700 nm larger in diameter, and thus resettled faster than the resuspended untreated or Ca-treated FFT particles. The final turbidity values 21 days after resuspension of untreated and 1.7 mg/L Al-treated FFT particles in fresh BML surface water were 20.5 NTU and 2.5 NTU, respectively. Thus, Al treatment may be effective in mitigating turbidity in BML through both Al-induced coagulation and self-weight settling of the resuspended Al-treated FFT particles.


2017 ◽  
Vol 53 (6) ◽  
pp. 4725-4740 ◽  
Author(s):  
Kathryn A. Dompierre ◽  
S. Lee Barbour ◽  
Rebecca L. North ◽  
Sean K. Carey ◽  
Matthew B. J. Lindsay

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