Effects of Calcium and Aluminum on Particle Settling in an Oil Sands End Pit Lake

Surface mining of oil sands ore in Alberta, Canada has generated fluid fine tailings (FFT) that must be reclaimed. End pit lakes (EPLs), which consist of thick deposits of FFT capped with water, have been proposed for FFT reclamation, and Base Mine Lake (BML) is the first full-scale demonstration EPL. However, FFT particle settling and resuspension contributes to high turbidity in the BML water cap, which may be detrimental to the development of an aquatic ecosystem. This study investigated the effect of Ca and Al treatments on turbidity mitigation. The initial turbidity was reduced from 20 NTU to less than 2 NTU in BML surface water treated with 54 mg/L of Ca or 1.1 mg/L of Al. At a concentration of 1.1 mg/L, Al reduced the initial turbidity to a greater extent, and in a shorter time, than 54 mg/L of Ca. Further, resuspended Al-treated FFT particles were 100–700 nm larger in diameter, and thus resettled faster than the resuspended untreated or Ca-treated FFT particles. The final turbidity values 21 days after resuspension of untreated and 1.7 mg/L Al-treated FFT particles in fresh BML surface water were 20.5 NTU and 2.5 NTU, respectively. Thus, Al treatment may be effective in mitigating turbidity in BML through both Al-induced coagulation and self-weight settling of the resuspended Al-treated FFT particles.

Biofilms for Turbidity Mitigation in Oil Sands End Pit Lakes

End pit lakes (EPLs) have been proposed as a method of reclaiming oil sands fluid fine tailings (FFT), which consist primarily of process-affected water and clay- and silt-sized particles. Base Mine Lake (BML) is the first full-scale demonstration EPL and contains thick deposits of FFT capped with water. Because of the fine-grained nature of FFT, turbidity generation and mitigation in BML are issues that may be detrimental to the development of an aquatic ecosystem in the water cap. Laboratory mixing experiments were conducted to investigate the effect of mudline biofilms made up of microbial communities indigenous to FFT on mitigating turbidity in EPLs. Four mixing speeds were tested (80, 120, 160, and 200 rpm), all of which are above the threshold velocity required to initiate erosion of FFT in BML. These mixing speeds were selected to evaluate (i) the effectiveness of biofilms in mitigating turbidity and (ii) the mixing speed required to ‘break’ the biofilms. The impact of biofilm age (10 weeks versus 20 weeks old) on turbidity mitigation was also evaluated. Diverse microbial communities in the biofilms included photoautotrophs, namely cyanobacteria and Chlorophyta (green algae), as well as a number of heterotrophs such as Gammaproteobacteria, Desulfobulbia, and Anaerolineae. Biofilms reduced surface water turbidity by up to 99%, depending on the biofilm age and mixing speed. Lifting and layering in the older biofilms resulted in weaker attachment to the FFT; as such, younger biofilms performed better than older biofilms. However, older biofilms still reduced turbidity by 69% to 95%, depending on the mixing speed. These results indicate that biostabilization is a promising mechanism for turbidity mitigation in EPLs.

Effects of seasonal weathering on dewatering and strength of an oil sands tailings deposit

Considerable research has been conducted over the past decade by oil sands mining companies to improve the dewatering and strength properties of fluid fine tailings deposits in an effort to meet the regulatory and closure requirements. Commercially employed dewatering treatment technologies (inline flocculation, thickening, and centrifugation) may not be sufficient to develop the strength for the creation of trafficable landscape without the use of soft soil capping technologies. These treated tailings are continuously deposited creating soft and saturated deep deposits. Seasonal weathering may be an additional promising technology to further dewater the treated tailings and promote the development of shear strength at the surface. The effects of seasonal weathering on dewatering and strength were investigated in this paper by performing multiple cycles of freeze-thaw and alternate drying-wetting cycles on two types of treated tailings deposit. The results indicate that multiple cycles of seasonal weathering significantly increased the dewatering and strength properties. However, different parameters such as freezing gradient, number of seasonal cycles, and pore water chemistry play an influential role in changing the magnitude of the strength. The results also suggest that a minimum threshold strength value is required where the effects of rainfall rewetting had a minimal impact on strength reduction (the strength corresponding to the moisture content approaching the plastic limit).

Using Specified Risk Materials-Based Peptides for Oil Sands Fluid Fine Tailings Management

Fluid fine tailings are produced in huge quantities by Canada’s mined oil sands industry. Due to the high colloidal stability of the contained fine solids, settling of fluid fine tailings can take hundreds of years, making the entrapped water unavailable and posing challenges to public health and the environment. This study focuses on developing value-added aggregation agents from specified risk materials (SRM), a waste protein stream from slaughterhouse industries, to achieve an improved separation of fluid fine tailings into free water and solids. Settling results using synthetic kaolinite slurries demonstrated that, though not as effective as hydrolyzed polyacrylamide, a commercial flocculant, the use of SRM-derived peptides enabled a 2-3-fold faster initial settling rate than the blank control. The pH of synthetic kaolinite tailings was observed to be slightly reduced with increasing peptides dosage in the test range (10–50 kg/ton). The experiments on diluted fluid fine tailings (as a representation of real oil sands tailings) demonstrated an optimum peptides dosage of 14 kg/ton, which resulted in a 4-fold faster initial settling rate compared to the untreated tailings. Overall, this study demonstrates the novelty and feasibility of using SRM-peptides to address intractable oil sands fluid tailings.

Capping dewatered oil sands fluid fine tailings with salvaged reclamation soils at varying depths to grow woody plants

Managing fluid fine tailings (FFT) present a major cause of industrial and environmental concerns in oil sands surface mining production. A potential management solution is to dewater and cap the FFT solids for use in land reclamation. A 16 wk greenhouse study was conducted to assess whether FFT centrifuge cake with caps of various reclamation soil mixes (forest floor mineral mix, peat mineral mix, and a mixture of both) and depths (0, 5, 10, and 20 cm) would support growth of trembling aspen (Populus tremuloides — native broadleaf tree) and beaked willow (Salix bebbiana — native broadleaf shrub). Beaked willow had a much greater survival rate (100%) when grown directly in FFT cake compared with trembling aspen (16.7%). Plants grown directly in FFT cake were negatively impacted by high water content, low nitrate supply rates, and high metal concentrations with beaked willow seedlings having 10 times higher foliar concentrations of Al, Cr, and Ti compared with any other treatments. Adding soil caps substantially increased aboveground biomass for both species, but differences among soil cap types and depths did not have as significant of an effect on plant growth. Results from this study show that capping FFT substantially improves woody plant growth, and S. bebbiana and P. tremuloides are potentially suitable species for tailings reclamation.

Effect of various treatments on consolidation of oil sands fluid fine tailings

Regulatory policy and regulations in Alberta require oil sands companies to reduce their production and storage of fluid fine tailings by creating deposits that can be reclaimed in a timely manner. To meet the regulatory requirements, some companies are adding flocculants to the fluid fine tailings and then using thickeners, inline flocculation or centrifuges to increase the solids content. Freeze–thaw and drying processes are then used to further dewater the tailings. The effects of flocculating, thickening, and freeze–thaw treatments were investigated by performing large-strain consolidation and shear strength tests on these treated fluid fine tailings. The consolidation and shear strength results were then compared with those of untreated fluid fine tailings. All of the treatments increased the hydraulic conductivity of the fluid fine tailings to some degree, but had little to no effect on the compressibility and shear strength. The effects of the treatment processes are discussed and evaluated.