scholarly journals The impact of oxalate ions on barium sulfate crystallization

2018 ◽  
Vol 498 ◽  
pp. 148-153 ◽  
Author(s):  
Franca Jones ◽  
Mark I. Ogden ◽  
Tomoko Radomirovic
Keyword(s):  
Barium Sulfate ◽  
Oxalate Ions ◽  
The Impact

Experimental Study of Natural Ions and Rock Interactions for Seawater Breakthrough Percentage Monitoring during Offshore Seawater Flooding

SPE Journal ◽  
2021 ◽  
pp. 1-21
Author(s):  
Yanqing Wang ◽  
Xiang Li ◽  
Jun Lu
Keyword(s):  
Porous Media ◽  
Fluid Flow ◽  
Barium Sulfate ◽  
Large Deviation ◽  
Exchange Process ◽  
Reaction Model ◽  
Sodium Content ◽  
Flow In Porous Media ◽  
Formation Water ◽  
The Impact

Summary Seawater breakthrough percentage monitoring is critical for offshore oil reservoirs because seawater fraction is an important parameter for estimating the severity of many flow assurance issues caused by seawater injection and further developing effective strategies to mitigate the impact of those issues on production. The validation of using natural ions as a tracer to calculate the seawater fraction was investigated systematically by studying the natural chemical composition evolution in porous media using coreflood tests and static bottle tests. The applicable range of ions was discussed based on the interaction between ion and rock. The barium sulfate reactive model was improved by integrating interaction between ions and rock as well as fluid flow effect. The results indicate that chloride and sodium interact with rock, but the influence of the interaction can be minimized to a negligible level because of the high concentrations of chloride and sodium. Thus, chloride and sodium can be used as conservative tracers during the seawater flooding process. However, adsorption/desorption may have a large influence on chloride and sodium concentrations under the scenario that both injection water and formation water have low chloride and sodium content. Bromide shows negligible interaction with rock even at low concentrations and can be regarded as being conservative. The application of a barium and sulfate reaction model in coreflood tests does not work as well as in bottle tests because fluid flow in porous media and ion interaction with rock is not taken into account. Although sulfate and barium adsorption on clay is small, it should not be neglected. The barium sulfate reaction model was improved based on the simulation of ion transport in porous media. Cations (magnesium, calcium, and potassium) are involved in the complicated cation-exchange process, which causes large deviation. Therefore, magnesium, calcium, and potassium are not recommended to calculate seawater fraction. Boron, which exists as anions in formation water and is used as a conservative tracer, has significant interactions with core matrix, and using boron in an ion tracking method directly can significantly underestimate the seawater fraction. The results give guidelines on selecting suitable ions as tracers to determine seawater breakthrough percentages under different production scenarios.

scholarly journals Using Molecular Modelling to Understand and Predict the Impact of Organic Additives as Crystal Growth Modifiers

2020 ◽  
Vol 73 (8) ◽  
pp. 724 ◽  
Author(s):  
Franca Jones ◽  
Andrew L. Rohl
Keyword(s):  
Crystal Growth ◽  
Molecular Modelling ◽  
Barium Sulfate ◽  
Organic Molecules ◽  
Adsorption Process ◽  
Organic Additives ◽  
Lattice Matching ◽  
Growth Modification ◽  
Matching Criteria ◽  
The Impact

Empirical molecular modelling was used to investigate the impact of organic additives on crystal morphology and inhibition. The replacement energy was found to correlate reasonably well with the degree of inhibition as determined from conductivity data. The replacement energy was also able to predict the barium sulfate face on which additive adsorption was most likely. While the ability of the organic functional groups to sit in the vacant sulfate lattice positions (the so-called ‘lattice matching’ criteria) appears intuitively sensible, it was found that this is not a sufficient criterion to predict real behaviour. A better criterion is the overall replacement energy as it takes into consideration the number of Ba–Oorganic interactions and whether the adsorption process overall is energetically favourable (by including the hydration energy of the ions). Thus, the replacement energy can successfully predict the effect of organic molecules on the crystal growth modification of barium sulfate.

Impact of Relaxation of Low-Sulfate Seawater Parameters on Scaling Risk

2021 ◽  
pp. 1-20
Author(s):  
Mandhr Al Kalbani ◽  
Hatem Al Shabibi ◽  
Oleg Ishkov ◽  
Duarte Silva ◽  
Eric Mackay ◽  
...  
Keyword(s):  
Barium Sulfate ◽  
Produced Water ◽  
Switching Time ◽  
Water Drop ◽  
Sensitivity Study ◽  
Sulfate Concentration ◽  
Full Field ◽  
Switching Strategy ◽  
Field Case ◽  
The Impact

Summary Injection of low-sulfate seawater (LSSW) instead of untreated full-sulfate seawater (FSSW) is widely used to mitigate barium sulfate scaling risk at the production wells. LSSW injection may no longer be required when the barium concentrations in the produced water drop below a certain threshold. Such a trigger value could be estimated from the barium sulfate precipitation tendency. Relaxation of requirements for the sulfate reduction plant (SRP) can significantly reduce operational costs. This study investigates the impact of several parameters on the timing and degree of relaxation of the output sulfate concentration by the SRP. Finally, the optimal switching strategy is proposed for a field case. The strategy for switching from LSSW to FSSW (e.g., time and method; direct or gradual increase in the sulfate concentration) was initially investigated using generic 2D areal and vertical models. The sensitivity study included the impact of reservoir heterogeneity and the initial barium and sulfate ion concentrations. Findings were later applied on a full-field reservoir simulation model followed by a mineral scale prediction software to investigate the specific switching strategy for a field that has multiple wells and significantly more complex heterogeneity. The results show that barium concentrations in the formation brine affect the choice of switching time more than the output sulfate concentration produced by the SRP. The degree of heterogeneity around the producers also has a significant impact on the switching time. Another parameter is the contrast in the permeability between layers; higher contrast allows a longer period of coproduction of the scaling ions and thus delays the switching time. In the field case, switching to FSSW at early times allows higher consumption of barium ions because of its in-situ precipitation. Barium is no longer a limiting ion, and so a higher degree of deep reservoir precipitation reduces the requirement for prolonged LSSW injection. Another strategy is a gradual relaxation of LSSW output, which allows even earlier buildup of the injected sulfate concentration compared with the direct FSSW switch. The study investigates the reservoir parameters that affect sulfate relaxation of LSSW injection for a field. After the proposed workflow, the optimal relaxation strategy can be designed for other field cases.

scholarly journals The impact of sulfite ions on barium sulfate crystallization

2019 ◽  
Vol 507 ◽  
pp. 213-219
Author(s):  
Franca Jones ◽  
Mark I. Ogden ◽  
Tomoko Radomirovic
Keyword(s):  
Barium Sulfate ◽  
Sulfite Ions ◽  
The Impact

Formation of Lunar Craters and Bright Rays as a Result of Meteorite Impacts

1962 ◽  
Vol 14 ◽  
pp. 415-418
Author(s):  
K. P. Stanyukovich ◽  
V. A. Bronshten
Keyword(s):  
Explosive Charge ◽  
The Moon ◽  
Meteorite Impacts ◽  
The Earth ◽  
Lunar Craters ◽  
The Impact

The phenomena accompanying the impact of large meteorites on the surface of the Moon or of the Earth can be examined on the basis of the theory of explosive phenomena if we assume that, instead of an exploding meteorite moving inside the rock, we have an explosive charge (equivalent in energy), situated at a certain distance under the surface.

The Geosciences Applied to Lunar Exploration

1962 ◽  
Vol 14 ◽  
pp. 169-257 ◽  
Author(s):  
J. Green
Keyword(s):  
Lunar Surface ◽  
Probable Mechanism ◽  
Point Of View ◽  
Lunar Exploration ◽  
Geological Model ◽  
Apply Geophysics ◽  
Surface Features ◽  
The Impact

The term geo-sciences has been used here to include the disciplines geology, geophysics and geochemistry. However, in order to apply geophysics and geochemistry effectively one must begin with a geological model. Therefore, the science of geology should be used as the basis for lunar exploration. From an astronomical point of view, a lunar terrain heavily impacted with meteors appears the more reasonable; although from a geological standpoint, volcanism seems the more probable mechanism. A surface liberally marked with volcanic features has been advocated by such geologists as Bülow, Dana, Suess, von Wolff, Shaler, Spurr, and Kuno. In this paper, both the impact and volcanic hypotheses are considered in the application of the geo-sciences to manned lunar exploration. However, more emphasis is placed on the volcanic, or more correctly the defluidization, hypothesis to account for lunar surface features.

Asteroid and Comet Impact Speeds upon Mars: Significance for Panspermia and the Supply of Organics

1997 ◽  
Vol 161 ◽  
pp. 197-201 ◽  
Author(s):  
Duncan Steel
Keyword(s):  
Probability Distributions ◽  
Regions Of Interest ◽  
Significant Fraction ◽  
Organic Chemicals ◽  
Impact Speed ◽  
The Mean ◽  
The Impact

AbstractWhilst lithopanspermia depends upon massive impacts occurring at a speed above some limit, the intact delivery of organic chemicals or other volatiles to a planet requires the impact speed to be below some other limit such that a significant fraction of that material escapes destruction. Thus the two opposite ends of the impact speed distributions are the regions of interest in the bioastronomical context, whereas much modelling work on impacts delivers, or makes use of, only the mean speed. Here the probability distributions of impact speeds upon Mars are calculated for (i) the orbital distribution of known asteroids; and (ii) the expected distribution of near-parabolic cometary orbits. It is found that cometary impacts are far more likely to eject rocks from Mars (over 99 percent of the cometary impacts are at speeds above 20 km/sec, but at most 5 percent of the asteroidal impacts); paradoxically, the objects impacting at speeds low enough to make organic/volatile survival possible (the asteroids) are those which are depleted in such species.

Organic Syntheses During the Impact of a Comet with a Gaseous Planet

1997 ◽  
Vol 161 ◽  
pp. 189-195
Author(s):  
Cesare Guaita ◽  
Roberto Crippa ◽  
Federico Manzini
Keyword(s):  
Polymeric Material ◽  
Molecular Form ◽  
Parent Compound ◽  
Blue Filter ◽  
Organic Syntheses ◽  
The Impact

AbstractA large amount of CO has been detected above many SL9/Jupiter impacts. This gas was never detected before the collision. So, in our opinion, CO was released from a parent compound during the collision. We identify this compound as POM (polyoxymethylene), a formaldehyde (HCHO) polymer that, when suddenly heated, reformes monomeric HCHO. At temperatures higher than 1200°K HCHO cannot exist in molecular form and the most probable result of its decomposition is the formation of CO. At lower temperatures, HCHO can react with NH3 and/or HCN to form high UV-absorbing polymeric material. In our opinion, this kind of material has also to be taken in to account to explain the complex evolution of some SL9 impacts that we observed in CCD images taken with a blue filter.

Hydrogen Cyanide Polymers from the Impact of Comet P/Shoemaker-Levy 9 on Jupiter

1997 ◽  
Vol 161 ◽  
pp. 179-187
Author(s):  
Clifford N. Matthews ◽  
Rose A. Pesce-Rodriguez ◽  
Shirley A. Liebman
Keyword(s):  
Amino Acids ◽  
Solar System ◽  
Hydrogen Cyanide ◽  
Nitrogen Heterocycles ◽  
Laboratory Studies ◽  
Heterogeneous Solids ◽  
The Many ◽  
Comet Halley ◽  
The Impact ◽  
By Products

AbstractHydrogen cyanide polymers – heterogeneous solids ranging in color from yellow to orange to brown to black – may be among the organic macromolecules most readily formed within the Solar System. The non-volatile black crust of comet Halley, for example, as well as the extensive orangebrown streaks in the atmosphere of Jupiter, might consist largely of such polymers synthesized from HCN formed by photolysis of methane and ammonia, the color observed depending on the concentration of HCN involved. Laboratory studies of these ubiquitous compounds point to the presence of polyamidine structures synthesized directly from hydrogen cyanide. These would be converted by water to polypeptides which can be further hydrolyzed to α-amino acids. Black polymers and multimers with conjugated ladder structures derived from HCN could also be formed and might well be the source of the many nitrogen heterocycles, adenine included, observed after pyrolysis. The dark brown color arising from the impacts of comet P/Shoemaker-Levy 9 on Jupiter might therefore be mainly caused by the presence of HCN polymers, whether originally present, deposited by the impactor or synthesized directly from HCN. Spectroscopic detection of these predicted macromolecules and their hydrolytic and pyrolytic by-products would strengthen significantly the hypothesis that cyanide polymerization is a preferred pathway for prebiotic and extraterrestrial chemistry.

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