Excess molar enthalpy measurement and modelling of (oxygenated compounds + hydrocarbon) mixtures: Binary and ternary mixtures containing 2-(2-methoxyethoxy)ethanol, 1-hexene and cyclohexane at (298.15 and 313.15) K

2020 ◽  
Vol 149 ◽  
pp. 106171 ◽  
Author(s):  
Mohamed Lifi ◽  
Natalia Muñoz-Rujas ◽  
Eduardo A. Montero ◽  
Latifa Negadi ◽  
Fernando Aguilar ◽  
...  
Keyword(s):  
Molar Enthalpy ◽  
Ternary Mixtures ◽  
Excess Molar Enthalpy ◽  
Hydrocarbon Mixtures ◽  
Oxygenated Compounds ◽  
Binary And Ternary Mixtures

scholarly journals Modelling of volumetric properties of binary and ternary mixtures by CEOS, CEOS/Ge and empirical models

2007 ◽  
Vol 72 (12) ◽  
pp. 1437-1463 ◽  
Author(s):  
Bojan Djordjevic ◽  
Slobodan Serbanovic ◽  
Ivona Radovic ◽  
Aleksandar Tasic ◽  
Mirjana Kijevcanin
Keyword(s):  
Molar Volume ◽  
Excess Molar Volume ◽  
Equations Of State ◽  
Ternary Systems ◽  
Empirical Models ◽  
Ternary Mixtures ◽  
Excess Properties ◽  
Volumetric Properties ◽  
Excess Molar Enthalpy ◽  
Binary And Ternary Mixtures

Although many cubic equations of state coupled with van der Waals-one fluid mixing rules including temperature dependent interaction parameters are sufficient for representing phase equilibria and excess properties (excess molar enthalpy HE, excess molar volume VE, etc.), difficulties appear in the correlation and prediction of thermodynamic properties of complex mixtures at various temperature and pressure ranges. Great progress has been made by a new approach based on CEOS/GE models. This paper reviews the last six-year of progress achieved in modelling of the volumetric properties for complex binary and ternary systems of non-electrolytes by the CEOS and CEOS/GE approaches. In addition, the vdW1 and TCBT models were used to estimate the excess molar volume VE of ternary systems methanol + chloroform + benzene and 1-propanol + chloroform + benzene, as well as the corresponding binaries methanol + chloroform, chloroform + benzene, 1-propanol + chloroform and 1-propanol + benzene at 288.15-313.15 K and atmospheric pressure. Also, prediction of VE for both ternaries by empirical models (Radojkovic, Kohler, Jackob-Fitzner, Colinet, Tsao-Smith, Toop, Scatchard, Rastogi) was performed.

Excess enthalpies of ether+alcohol+hydrocarbon mixtures: Binary and ternary mixtures containing dibutyl ether (DBE), 1-butanol and benzene at 298.15K and 313.15K

2009 ◽  
Vol 284 (2) ◽  
pp. 106-113 ◽  
Author(s):  
Fernando Aguilar ◽  
Fatima E.M. Alaoui ◽  
José J. Segovia ◽  
Miguel A. Villamañán ◽  
Eduardo A. Montero
Keyword(s):  
Ternary Mixtures ◽  
Excess Enthalpies ◽  
Hydrocarbon Mixtures ◽  
Dibutyl Ether ◽  
Binary And Ternary Mixtures ◽  
Ether Alcohol

Energy saving technology for sintering of black bricks from high-siliceous clay

MRS Advances ◽  
2020 ◽  
Vol 5 (61) ◽  
pp. 3123-3131
Author(s):  
Mario Flores Nicolas ◽  
Marina Vlasova ◽  
Pedro Antonio Márquez Aguilar ◽  
Mykola Kakazey ◽  
Marcos Mauricio Chávez Cano ◽  
...  
Keyword(s):  
Low Temperature ◽  
Oxygen Deficiency ◽  
Glass Ceramics ◽  
Total Content ◽  
Ceramic Materials ◽  
Ternary Mixtures ◽  
High Porosity ◽  
Reducing Conditions ◽  
Binary And Ternary Mixtures ◽  
Dark Color

AbstractThe low-temperature synthesis of bricks prepared from high-siliceous clays by the method of plastic molding of blanks was used. For the preparation of brick blanks, binary and ternary mixtures of high-siliceous clays, black sand, and bottle glass cullet were used. Gray-black low-porosity and high-porosity ceramics was obtained by sintering under conditions of oxygen deficiency. It has been established that to initiate plastic in mixtures containing high-siliceous clay, it is necessary to add montmorillonite/bentonite additives, carry out low-temperature sintering, and introduce low-melting glass additives with a melting point ranging from 750 to 800 °C. The performed investigations have shown that the sintering of mixtures with a total content of iron oxide of about 5 wt% under reducing conditions at Tsint. = 800°C for 8 h leads to the formation of glass ceramics consisting of quartz, feldspars, and a phase. The main sources of the appearance of a dark color is the formation of [Fe3+O4]4- and [Fe3+O6]9- anions in the composition of the glass phase and feldspars. By changing the contents of clay, sand, and glass in sintering, it is possible to obtain two types of ceramic materials: (a) in the form of building bricks and (b) in the form of porous fillers.

Properties of Refrigerants from Cubic Equations of State

2008 ◽  
Vol 59 (5) ◽  
Author(s):  
Viorel Feroiu ◽  
Dan Geana ◽  
Catinca Secuianu
Keyword(s):  
Experimental Data ◽  
Vapor Pressure ◽  
Equations Of State ◽  
Ternary Mixtures ◽  
Volumetric Properties ◽  
Mixing Rules ◽  
Saturation Curve ◽  
Equilibrium Thermodynamic ◽  
Liquid Equilibrium ◽  
Binary And Ternary Mixtures

Vapour � liquid equilibrium, thermodynamic and volumetric properties were predicted for three pure hydrofluorocarbons: difluoromethane (R32), pentafluoroethane (R125) and 1,1,1,2 � tetrafluoroethane (R134a) as well as for binary and ternary mixtures of these refrigerants. Three cubic equations of state GEOS3C, SRK (Soave � Redlich � Kwong) and PR (Peng � Robinson) were used. A wide comparison with literature experimental data was made. For the refrigerant mixtures, classical van der Waals mixing rules without interaction parameters were used. The GEOS3C equation, with three parameters estimated by matching several points on the saturation curve (vapor pressure and corresponding liquid volumes), compares favorably to other equations in literature, being simple enough for applications.

Catalytic hydrogenation of binary and ternary mixtures of unsaturated substances in the liquid phase on platinum

1979 ◽  
Vol 44 (8) ◽  
pp. 2378-2383 ◽  
Author(s):  
Libor Červený ◽  
Radka Junová ◽  
Vlastimil Růžička
Keyword(s):  
Liquid Phase ◽  
Binary Mixtures ◽  
Silica Gel ◽  
Catalytic Hydrogenation ◽  
Ternary Systems ◽  
Ternary Mixtures ◽  
Unsaturated Alcohol ◽  
Solvent Concentration ◽  
Binary And Ternary Mixtures ◽  
Hydrogenation Selectivity

Hydrogenation of olefinic substrates in binary and ternary mixtures using 5% Pt on silica gel as the catalyst was studied in normal conditions in the liquid phase with methanol or cyclohexane or in solvent-free systems. The effect of the solvent concentration on the selectivity of hydrogenation of the unsaturated alcohol-olefin binary mixtures was investigated. In ternary systems of unsaturated substrates, the effect of each of the substrates on the selectivity of hydrogenation of the remaining two substances was examined. Another system was found in which a jump change of the hydrogenation selectivity occurred on the vanishing of the fastest reacting substance.

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