scholarly journals Synthesis of magnetic core-shell Fe3O4@SiO2@Mg(OH)2 composite using waste bischofite and its catalytic performance for ozonation of antibiotics

2020 ◽  
Vol 8 (5) ◽  
pp. 104318 ◽  
Author(s):  
Jun Wu ◽  
Qi Sun ◽  
Jian Lu
Nanomaterials ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 2111
Author(s):  
Inês A. S. Matias ◽  
Ana P. C. Ribeiro ◽  
Ana M. Ferraria ◽  
Ana M. Botelho do Rego ◽  
Luísa M. D. R. S. Martins

For the first time, herein is reported the use of a magnetic core-shell support for a C-scorpionate metallic complex. The prepared hybrid material, that consists on the C-scorpionate iron(II) complex [FeCl2{κ3-HC(pz)3}] (pz, pyrazolyl) immobilized at magnetic core-shell particles (Fe3O4/TiO2), was tested as catalyst for the oxidation of secondary alcohols using the model substrate 1-phenylethanol. Moreover, the application of alternative energy sources (e.g., ultrasounds, microwaves, mechanical or thermal) for the peroxidative alcohol oxidation using the magnetic heterogenized iron(II) scorpionate led to different/unusual outcomes that are presented and discussed.


2016 ◽  
Vol 18 (21) ◽  
pp. 5900-5914 ◽  
Author(s):  
Shuangtao Yin ◽  
Jin Li ◽  
Hui Zhang

Magnetically recyclable 3D hierarchical hollow nanostructured Au25 nanocluster catalysts, assembled by an Au25Capt18 precursor method, exhibit an extraordinary catalytic performance for the aerobic oxidation of alcohol by molecular oxygen upon strong Au25NCs–LDH–magnetic core synergy.


RSC Advances ◽  
2016 ◽  
Vol 6 (37) ◽  
pp. 31514-31525 ◽  
Author(s):  
J. Safari ◽  
S. Gandomi-Ravandi ◽  
Z. Haghighi

We exhibit the synthesis of magnetic core–shell nanocomposites as solid phase catalysts in the reduction of nitroaromatics.


2020 ◽  
Vol 01 ◽  
Author(s):  
Bonamali Pal ◽  
Anila Monga ◽  
Aadil Bathla

Background:: Bimetallic nanocomposites have currently gained significant importance for enhanced catalytic applications relative to monometallic analogues. The synergistic interactions modified electronic and optical properties in the bimetallic (M1@M2) structural morphology e.g., core-shell /alloy nanostructures resulted in a better co-catalytic performance for TiO2 photocatalysis. Objective:: Hence, this article discusses the preparation, characterization, and co-catalytic activity of different bimetallic nanostructures namely, Cu@Zn, Pd@Au, Au@Ag, and Ag@Cu, etc. Method:: These bimetallic co-catalysts deposited on TiO2 possess the ability to absorb visible light due to surface plasmonic absorption and are also expected to display the new properties due to synergy between two distinct metals. As a result, they reveal the highest level of activity than the monometal deposited TiO2. Result:: Their optical absorption, emission, charge carrier dynamics, and surface structural morphology are explained for the improved photocatalytic activity of M1@M2 loaded TiO2 for the hydrogenation of certain organic compounds e.g., quinoline, crotonaldehyde, and 1,3-dinitrobenzene, etc. under UV/ visible light irradiation. Conclusion:: It revealed that the use of bimetallic core@shell co-catalyst for hydrogenation of important industrial organics by M1@M2-TiO2 nanocomposite demonstrates beneficial reactivity in many instances relative to conventional transition metal catalysts.


Author(s):  
Yangyang Ren ◽  
Chuanliang Li ◽  
Baosong Li ◽  
Fan Gao ◽  
Xinghua Zhang ◽  
...  

PtPd nanoframes with excellent catalytic properties were obtained by etching Pd@PdPt core–shell RDs with Fe3+ in an acid environment.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
H. Rajabi-Moghaddam ◽  
M. R. Naimi-Jamal ◽  
M. Tajbakhsh

AbstractIn the present work, an attempt has been made to synthesize the 1,2,3-triazole derivatives resulting from the click reaction, in a mild and green environment using the new copper(II)-coated magnetic core–shell nanoparticles Fe3O4@SiO2 modified by isatoic anhydride. The structure of the catalyst has been determined by XRD, FE-SEM, TGA, VSM, EDS, and FT-IR analyzes. The high efficiency and the ability to be recovered and reused for at least up to 6 consecutive runs are some superior properties of the catalyst.


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