Liquid-liquid extraction of phenolic compounds from water using ionic liquids: Literature review and new experimental data using [C2mim]FSI

2018 ◽  
Vol 228 ◽  
pp. 475-482 ◽  
Author(s):  
Olalla G. Sas ◽  
Irene Domínguez ◽  
Begoña González ◽  
Ángeles Domínguez
Keyword(s):  
Experimental Data ◽  
Ionic Liquids ◽  
Phenolic Compounds ◽  
Literature Review ◽  
Liquid Extraction ◽  
Liquid Liquid Extraction

scholarly journals Recovery and Elimination of Phenolic Pollutants from Water Using [NTf2] and [Nf2]-Based Ionic Liquids

2019 ◽  
Vol 9 (20) ◽  
pp. 4321
Author(s):  
Sas ◽  
Domínguez ◽  
González
Keyword(s):  
Ionic Liquids ◽  
Phenolic Compounds ◽  
Extraction Yield ◽  
Liquid Extraction ◽  
Industrial Growth ◽  
Extraction Solvent ◽  
Phenolic Pollutants ◽  
Liquid Liquid Extraction ◽  
Volatile Organic ◽  
Extraction Solvents

At present, pollution is one of the most important problems worldwide. Industrial growth makes it necessary to develop techniques to remove pollutant substances from water, since water is an important natural source for life. One of these techniques is liquid–liquid extraction, which is used to remove phenolic compounds from wastewaters. Volatile organic compounds are used as common extraction solvents in liquid–liquid extractions; nevertheless, some of their properties, such as toxicity and volatility, make it necessary to replace them with other less toxic solvents. In this work, the capability of four ionic liquids, based on bis(trifluoromethylsulfonyl)imide [NTf2] and bis(fluorosulfonyl)imide [Nf2] anions and different cations to remove phenolic compounds from water was studied. The phenolic compounds used in this study were phenol, o-cresol, and 2-chlorophenol, and the effects of the extraction solvent and phenol structures were analyzed. For that, a liquid–liquid extraction was carried out, and the extraction yield was determined. In general, high extraction efficiencies were obtained for all studied systems, obtaining the highest extraction efficiencies using the pyrrolidinium cation-based ionic liquids.

Ethylsulphate-Based Ionic Liquids in the Liquid–Liquid Extraction of Pyrrole and Pyridine from Isododecane at 298.15 K

2015 ◽  
Vol 10 (3) ◽  
pp. 161-171 ◽  
Author(s):  
Nurshakirin Hazim Chan ◽  
Hanee Farzana Hizaddin ◽  
Ramalingam Anantharaj ◽  
Tamal Banerjee
Keyword(s):  
Experimental Data ◽  
Ionic Liquids ◽  
Distribution Coefficient ◽  
Significant Role ◽  
Entire Range ◽  
Liquid Extraction ◽  
Liquid Liquid Extraction ◽  
Lle Data ◽  
Denitrification Process ◽  
High Distribution Coefficient

Abstract Ternary liquid-liquid equilibria for four systems containing ionic liquids {1-ethyl-3-methylimidazolium ethylsulphate ([EMIM][EtSO4]) and 1-ethyl-3-methylpyridinium ethylsulphate ([EMPY][EtSO4])}(1)+pyrrole/pyridine(2)+isododecane (3) have been determined at 298.15 K. The solute distribution coefficient and selectivity were calculated from experimental LLE data. All systems showed high distribution coefficient and selectivity values at the entire range of pyrrole or pyridine in feed. The consistency of experimental data was ascertained by applying the Othmer-Tobias and hand equations. Furthermore, the experimental LLE data have been compared and correlated using COSMO-RS, NRTL and UNIQUAC models. The influence of aromatic structure without inside ring of cation has a significant role on denitrification process at 298.15 K.

scholarly journals Liquid-Liquid Extraction in Systems Containing Butanol and Ionic Liquids – A Review

2017 ◽  
Vol 38 (1) ◽  
pp. 97-110 ◽  
Author(s):  
Artur Kubiczek ◽  
Władysław Kamiński
Keyword(s):  
Ionic Liquids ◽  
Room Temperature ◽  
Liquid Extraction ◽  
Butanol Production ◽  
Model Liquid ◽  
New Class ◽  
Liquid Liquid Extraction ◽  
Liquid Systems ◽  
Nrtl Equation ◽  
Equilibrium Data

AbstractRoom-temperature ionic liquids (RTILs) are a moderately new class of liquid substances that are characterized by a great variety of possible anion-cation combinations giving each of them different properties. For this reason, they have been termed as designer solvents and, as such, they are particularly promising for liquid-liquid extraction, which has been quite intensely studied over the last decade. This paper concentrates on the recent liquid-liquid extraction studies involving ionic liquids, yet focusing strictly on the separation of n-butanol from model aqueous solutions. Such research is undertaken mainly with the intention of facilitating biological butanol production, which is usually carried out through the ABE fermentation process. So far, various sorts of RTILs have been tested for this purpose while mostly ternary liquid-liquid systems have been investigated. The industrial design of liquid-liquid extraction requires prior knowledge of the state of thermodynamic equilibrium and its relation to the process parameters. Such knowledge can be obtained by performing a series of extraction experiments and employing a certain mathematical model to approximate the equilibrium. There are at least a few models available but this paper concentrates primarily on the NRTL equation, which has proven to be one of the most accurate tools for correlating experimental equilibrium data. Thus, all the presented studies have been selected based on the accepted modeling method. The reader is also shown how the NRTL equation can be used to model liquid-liquid systems containing more than three components as it has been the authors’ recent area of expertise.

Experimental and numerical investigation of electrostatic spray liquid-liquid extraction with ionic liquids

2012 ◽  
Vol 33 (1) ◽  
pp. 167-183 ◽  
Author(s):  
Marek Krawczyk ◽  
Kamil Kamiński ◽  
Jerzy Petera
Keyword(s):  
Ionic Liquids ◽  
Numerical Investigation ◽  
High Viscosity ◽  
Liquid Extraction ◽  
Separation Processes ◽  
Organic Mixture ◽  
Liquid Liquid Extraction ◽  
Key Factor ◽  
A New Technique ◽  
Electrostatic Spray

Experimental and numerical investigation of electrostatic spray liquid-liquid extraction with ionic liquids A new concept of an electrostatic spray column for liquid-liquid extraction was investigated. An important problem for separation processes is the presence of azeotropic or close-boiling mixtures in their production, for example heptane with ethanol, since the separation is impossible by ordinary distillation. The use of ionic liquids (IL) as a dispersed solvent specially engineered for any specific organic mixture in terms of selectivity is a key factor to successful separation. As IL present particularly attractive combination of favorable characteristics for the separation of heptane and ethanol, in this work we use 1-butyl-3-methylimidazolium methyl sulfate [BMIM][MeSO4]. Because of high viscosity and relatively high cost of IL a new technique was introduced, consisting in the electrostatically spray generation to enhance the mass transport between the phases. In order to optimally design the geometry of the contactor a series of numerical simulation was performed. Especially multi-nozzle variants for better exploitation of contactor volume were investigated. Experiments showed excellent possibility of control of the dispersion characteristics by applied voltage and thus control of the rate of extraction. The preliminary simulations based on our mathematical model for a three nozzle variant exhibited visual agreement with the theory of electrostatics.

ZIF-8-porous ionic liquids for the extraction of 2,2,3,3-tetrafluoro-1-propanol and water mixture

2021 ◽  
Author(s):  
Zenghui Wang ◽  
Pingping Zhao ◽  
Jimin Wu ◽  
Jun Gao ◽  
Lianzheng Zhang ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Special Class ◽  
Liquid Extraction ◽  
Water Mixture ◽  
Liquid Liquid Extraction

The design of stable ionic liquids (ILs) has become crucial for efficient liquid-liquid extraction (LLE) of alcohol and water. Porous ionic liquids (PILs), as a special class of ILs, have...

Development of a rotatory and continuous liquid–liquid extraction technique for phenolic compounds in wine

The Analyst ◽  
1996 ◽  
Vol 121 (3) ◽  
pp. 297-302 ◽  
Author(s):  
E. R. Brú ◽  
C. G. Barroso ◽  
R. Cela ◽  
J. A. Pérez-Bustamante
Keyword(s):  
Phenolic Compounds ◽  
Liquid Extraction ◽  
Extraction Technique ◽  
Liquid Liquid Extraction
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