The Congo red dye was decolourized by advanced oxidation process using solar/H2O2 method and the
effect of various parameters on decolourization like pH, H2O2 concentration, dye concentration, solar
light intensity, additives, COD and TOC removal studies and kinetic studies were investigated. The
photodegradation process was done by exposing dye solutions with the concentration of 100 mg/L treated
with 50% H2O2 to sunlight with the lux intensity range of 60,000-90,000 lux. The best possible pH 2
with an optimal H2O2 concentration of 1000 mM to achieve 100% decolourization within the period of
5 h. The kinetic studies done on H2O2 concentration also proved that the high solar light intensity leads
to higher decolourization and low solar light intensity leads to lesser decolourization. Addition of
additives like H2PO4
– and Cl– leads to a decrease in the rate of decolourization. The removal of COD
and TOC removal was found to be 83.26% and 5.18%, respectively.