Modeling of chromium (VI) biosorption by immobilized Spirulina platensis in packed column

2009 ◽  
Vol 170 (2-3) ◽  
pp. 735-743 ◽  
Author(s):  
S.V. Gokhale ◽  
K.K. Jyoti ◽  
S.S. Lele
2010 ◽  
Vol 156 (2) ◽  
pp. 264-269 ◽  
Author(s):  
Elisabetta Finocchio ◽  
Alessandra Lodi ◽  
Carlo Solisio ◽  
Attilio Converti

2009 ◽  
Vol 60 (2) ◽  
pp. 381-388 ◽  
Author(s):  
Pulane E. Molokwane ◽  
Evans M. Nkhalambayausi-Chirwa

Microbial Cr(VI) reduction in groundwater aquifer media was investigated in microcosm reactors extracted from Cr(VI) contaminated sites in South Africa. The reactors were operated under an influent Cr(VI) concentration of 40 mg/L to simulate the current Cr(VI) level at the contaminated site. Near complete Cr(VI) removal was observed in microcosm reactors inoculated with Cr(VI) reducing bacteria from dried activated sludge collected from a treatment plant receiving periodic loadings of Cr(VI). The best performance was observed under low hydraulic loading (flow rate, Q=0.310 cm3/hr). Microbial culture characterisation results showed a change in culture composition after 17 days of reactor operation, indicating Bacillus and Lysinibacillus species as the most dominant organisms in reactors that reduced Cr(VI). The predominance of Bacillus and Lysinibacillus species was either due to resilience against toxicity or adaptation to the changing conditions in the reactor. This research was the initial step towards the development of an in situ bioremediation process to contain the spread of a Cr(VI) plume in a groundwater aquifer at contaminated site in Brits, South Africa. South Africa holds about 72% percent of the world’s chromium resources, the majority of which is mined in the North Eastern region of the country formally known as Transvaal.


2015 ◽  
Vol 7 ◽  
pp. 92-99 ◽  
Author(s):  
Hyo Won Kwak ◽  
Moo Kon Kim ◽  
Jeong Yun Lee ◽  
Haesung Yun ◽  
Min Hwa Kim ◽  
...  

2009 ◽  
Vol 2009 (16) ◽  
pp. 1542-1551
Author(s):  
Pulane E. Molokwane ◽  
Evans M. N. Chirwa
Keyword(s):  

2017 ◽  
Vol 12 (3) ◽  
pp. 553-566 ◽  
Author(s):  
A. Abu-Rizaiza ◽  
M.W. Kadi ◽  
M.S. El-Shahawi

Activated carbon (AC) prepared from residual fly (FA) was activated by combined CO2-steam gasification and physically modified with procaine hydrochloride (PQ+Cl-). Modified AC was used as low cost and effective solid phase extractor (SPE) for removal, total determination and chemical speciation of chromium(III&VI) in wastewater. Pseudo-second order rate equation is proposed for assigning the kinetics of chromium(VI) sorption in aqueous HCl (1.0 mol L-1) by PQ+Cl-- modified AC . The data were correlated with surface structure of the SPE. A dual separation mechanism of chromium(VI) as a binary complex ion associate [PQ+.CrO3Cl-] in/on the modified AC via "weak base anion exchanger" and an added component of “surface adsorption” is proposed. At 2 mL min-1 flow rate Sorption of spiked chromium(VI) at known concentrations (0.5-20 mg mL-1) from water onto modified AC packed columns at 2 mL min-1 was achieved. The sorbed chromium(VI) species were successfully recovered (106.0±2- 110 ±3%, n=3) from AC packed column with NaOH (10 mL, 1.0 mol L-1). Chromium(III) after oxidation to chromium(VI) was also enriched and eluted from the AC packed column and analyzed. Modified PQ+Cl- AC packed column was also used for total determination and speciation of chromium(III & VI) species at trace levels in environmental water samples. Good apparent recovery percentage (94.6±6.3-102.0± 8.5 %) of chromium species was achieved confirming the analytical utility of the modified AC-packed column for removal, total determination and speciation of chromium(III & VI) species in environmental water samples.


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