Physicochemical structure characteristics and intrinsic reactivity of demineralized coal char rapidly pyrolyzed at elevated pressure

2020 ◽  
Vol 93 (3) ◽  
pp. 1064-1073 ◽  
Author(s):  
Dan Lin ◽  
Li Liu ◽  
Yi-Jun Zhao ◽  
Yan Zhao ◽  
Peng-Hua Qiu ◽  
...  
Author(s):  
Yufeng Duan ◽  
Yi Zhou ◽  
Xiaoping Chen ◽  
Changsui Zhao ◽  
Xin Wu

Pore structure is one of the most important factors that dominate the reactivity of post-combustion of coal-chars derived from partial gasification process of atmospheric and pressurized spouted fluidized bed gasifiers. The influential factors on pore structure of coal-chars were analyzed in terms of the coal size feed, operational conditions, coal-char size and its components. It concluded that pyrolysis and devolatilization play a leading role in forming the pore structure of coal-chars in the partial gasification process. It is the reaction of coal-char with CO2 and H2O (steam) that plays a dominant positive impact on promoting enlargement and development of the coal-char pores at the elevated pressure gasification. There may exist an optimal coal-char size range that possesses abundant porosity and bigger pore specific surface area, which contributes to enhancing the gasification reactions in the atmospheric gasifier.


2020 ◽  
Vol 93 (5) ◽  
pp. 1883-1891
Author(s):  
Yang Liu ◽  
Peifang Fu ◽  
Kang Bie ◽  
Yusen Gong ◽  
Tianyao Xu

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